Photocatalyst injection method and photocatalyst injection system

Patent metadata

Field	Value
Publication number	US-9824782-B2
Application number	US-201314432547-A
Country	US
Kind code	B2
Filing date	Oct 1, 2013
Priority date	Oct 3, 2012
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A photocatalyst injection system including: a reactor primary system coolant collection section collecting a reactor primary system coolant containing a noble metal or noble metal ion from a reactor primary system; a photocatalyst addition section adding a photocatalyst to the collected reactor primary system coolant; an ultraviolet irradiation section irradiating, with ultraviolet rays, the coolant to which the photocatalyst has been added for producing, in the coolant, a noble metal-carrying photocatalyst in which the noble metal is carried on a surface of the photocatalyst; and a noble metal-carrying photocatalyst injection section injecting the coolant containing the noble metal-carrying photocatalyst into the reactor primary system.

First claim

The invention claimed is:

1. A photocatalyst injection method comprising:
a reactor primary system coolant collecting step of removing a reactor primary system coolant containing a noble metal or noble metal ion from a reactor primary system;
a photocatalyst adding step of adding a photocatalyst to the removed reactor primary system coolant;
an ultraviolet irradiating step of irradiating, outside of the reactor primary system, the coolant resulting from the photocatalyst adding step with ultraviolet rays and producing, in the irradiated coolant, a noble metal-carrying photocatalyst in which the noble metal is carried on a surface of the photocatalyst; and
a noble metal-carrying photocatalyst injecting step of injecting the coolant resulting from the ultraviolet irradiating step into the reactor primary system.

2. The photocatalyst injection method according to claim 1 , wherein a temperature of the coolant resulting from the ultraviolet irradiating step at a time of injection into the reactor primary system is controlled to be 10° C. or more and 288° C. or less.

3. The photocatalyst injection method according to claim 1 , wherein an amount of the noble metal carried on the noble metal-carrying photocatalyst is 0.001% by mass to 10% by mass based on 100% by mass of the photocatalyst.

4. The photocatalyst injection method according to claim 1 , wherein an ultraviolet irradiation intensity employed in the ultraviolet irradiating step is 0.01 mW/cm′ or more and 20 mW/cm 2 or less.

5. The photocatalyst injection method according to claim 1 , wherein an ultraviolet irradiation intensity and an irradiation time are controlled in irradiation with the ultraviolet rays.

6. The photocatalyst injection method according to claim 1 , wherein the noble metal is one or more selected from Pt, Pd, Rh, Ru, Os and Ir.

7. The photocatalyst injection method according to claim 1 , wherein the photocatalyst is one or more selected from titanium oxide, iron oxide and zinc oxide.

8. The photocatalyst injection method according to claim 7 , wherein the photocatalyst is Fe 2 O 3 .

9. A photocatalyst injection system for a nuclear reactor primary system comprising:
means for removing a reactor primary system coolant containing a noble metal or noble metal ion from the reactor primary system the means for removing being fluidly coupled to the reactor primary system;
means for adding a photocatalyst to the collected reactor primary system coolant;
means for irradiating, with ultraviolet rays, the coolant to which the photocatalyst has been added for producing, in the coolant, a noble metal-carrying photocatalyst in which the noble metal is carried on a surface of the photocatalyst, the means for irradiating being arranged outside of the reactor primary system; and
means for injecting the coolant containing the noble metal-carrying photocatalyst into the reactor primary system.

10. The photocatalyst injection system according to claim 9 , wherein an inside of the means for adding holds the photocatalyst and the collected reactor primary system coolant and stirs the photocatalyst and the collected reactor primary system coolant together for mixing.

11. The photocatalyst injection system according to claim 9 , wherein the means for adding drops the photocatalyst into the collected reactor primary system coolant.

12. The photocatalyst injection system according to claim 9 , wherein the means for adding includes an ultraviolet irradiation tank and an ultraviolet irradiation source arranged outside of the ultraviolet irradiation tank.

13. A photocatalyst injection system for a nuclear reactor primary system comprising:
an ultraviolet irradiation tank arranged outside of the reactor primary system;
an outlet pipe configured to connect the reactor primary system to the ultraviolet irradiation tank and transfer a reactor primary system coolant from the reactor primary system to the ultraviolet irradiation tank, the reactor primary system coolant including a noble metal or noble metal ion;
an inlet pipe configured to connect a photocatalyst source to the ultraviolet irradiation tank and add a photocatalyst from the photocatalyst source to the reactor primary system coolant in the ultraviolet irradiation tank to create a combined coolant;
an ultraviolet irradiation source arranged outside of the reactor primary system and configured to irradiate, with ultraviolet rays, the combined coolant to produce, in the combined coolant, a noble metal-carrying photocatalyst in which the noble metal is carried on a surface of the photocatalyst; and
an injection pipe configured to connect the ultraviolet irradiation tank to the reactor primary system and inject the combined coolant containing the noble metal-carrying photocatalyst into the reactor primary system.

14. The photocatalyst injection system according to claim 13 , further comprising: a stirrer arranged inside of the ultraviolet irradiation tank and configured to mix together the photocatalyst and the collected reactor primary system coolant inside the ultraviolet irradiation tank.

15. The photocatalyst injection system according to claim 13 , wherein the inlet pipe is configured to drop the photocatalyst into the collected reactor primary system coolant in the ultraviolet irradiation tank.

16. The photocatalyst injection system according to claim 13 , wherein the ultraviolet irradiation source is arranged outside of the ultraviolet irradiation tank and configured to irradiate the irradiation tank.

Assignees

• Toshiba Kk

Inventors

• Okamura Masato
• Shibasaki Osamu
• Negishi Koji
• Yamamoto Seiji
• Arai Hiroyuki
• Uruma Yutaka

Classifications

• B01J23/8906

  Iron and noble metals · CPC title

• B01J2219/0877

  Liquid · CPC title

• G21C19/28

  Arrangements for introducing fluent material into the reactor core; Arrangements for removing fluent material from the reactor core (pumping coolant G21D) · CPC title

• B01J19/123

  Ultraviolet light · CPC title

• B01J37/345

  of ultraviolet wave energy · CPC title