Underlayer composition and method of manufacturing a semiconductor device
US-2024369932-A1 · Nov 7, 2024 · US
US9823565B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9823565-B2 |
| Application number | US-201615042220-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 12, 2016 |
| Priority date | Feb 18, 2015 |
| Publication date | Nov 21, 2017 |
| Grant date | Nov 21, 2017 |
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Embodiments in accordance with the present invention encompass negative-tone, solvent developable, self-imageable polymer compositions containing photobase generators which are useful for forming films that can be patterned to create structures for microelectronic devices, microelectronic packaging, microelectromechanical systems, optoelectronic devices and displays.
Opening claim text (preview).
What is claimed is: 1. A photoimageable solvent developable negative tone composition comprising: a) a polymer selected from the group consisting of: a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(6-(bicyclo[2.2.1]hept-5-en-2-yl)hexyl)oxirane (EONB); a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butyl)oxirane (EHNB); a copolymer containing repeating units derived from 5-benzylbicyclo[2.2.1]hept-2-ene (BenNB) and 2-(6-(bicyclo[2.2.1]hept-5-en-2-yl)hexyl)oxirane (EONB); and a copolymer containing repeating units derived from 5-benzylbicyclo[2.2.1]hept-2-ene (BenNB) and 2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butyl)oxirane (EHNB); b) a photobase generator of formula (II): where R 3 is (C 6 -C 10 )aryl(C 1 -C 6 )alkyl; and c) a carrier solvent. 2. The composition of claim 1 , wherein the polymer is selected from the group consisting of: a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(6-(bicyclo[2.2.1]hept-5-en-2-yl)hexyl)oxirane (EONB); and a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butyl)oxirane (EHNB). 3. The composition of claim 1 , wherein the polymer is selected from the group consisting of: a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(6-(bicyclo[2.2.1]hept-5-en-2-yl)hexyl)oxirane (EONB); a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butyl)oxirane (EHNB); and a copolymer containing repeating units derived from 5-benzylbicyclo[2.2.1]hept-2-ene (BenNB) and 2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butyl)oxirane (EHNB). 4. The composition of claim 1 , wherein the photobase generator is 1-(1-phenylethyl)octahydropyrrolo[1,2-a]pyrimidine. 5. A photoimageable solvent developable negative tone composition comprising: a) a copolymer containing repeating units derived from 5-phenethylbicyclo[2.2.1]hept-2-ene (PENB) and 2-(6-(bicyclo[2.2.1]hept-5-en-2-yl)hexyl)oxirane (EONB); b)1-(1-phenylethyl)octahydropyrrolo[1,2-a]pyrimidine; and c) a carrier solvent.
with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors · CPC title
with perfluoro compounds, e.g. for dry lithography (G03F7/0048 takes precedence) · CPC title
the macromolecular compound being present in a chemically amplified negative photoresist composition · CPC title
Macromolecular compounds which are rendered insoluble or differentially wettable (G03F7/075 takes precedence; macromolecular azides G03F7/012; macromolecular diazonium compounds G03F7/021) · CPC title
used as adhesion-promoting additives or as means to improve adhesion · CPC title
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