Fluid for electrowetting device and electrowetting device including same

Patent metadata

Field	Value
Publication number	US-9823461-B2
Application number	US-201514694187-A
Country	US
Kind code	B2
Filing date	Apr 23, 2015
Priority date	Oct 29, 2014
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

Provided are a fluid for an electrowetting device including a first fluid as a polar liquid, and a second fluid, as a non-polar solution, which is separated from the first fluid by an interface, wherein the first fluid includes an organic acid having an acid dissociation constant (pKa) of about 4 or less, a polar solvent, and a quaternary ammonium hydroxide compound, and an electrowetting device including the fluid.

First claim

What is claimed is:

1. A fluid for an electrowetting device, the fluid comprising:
a first fluid; and
a second fluid immiscible with the first fluid,
wherein the first fluid is a polar liquid and comprises an organic acid having an acid dissociation constant of about 4 or less, a polar solvent, and a quaternary ammonium hydroxide compound, and
the second fluid is a non-polar solution, wherein the organic acid having an acid dissociation constant of about 4 or less comprises at least one selected from the group consisting of a compound of Formula 1, polyvinylphosphonic acid, polymethacrylic acid, and polystyrene sulfonic acid:

wherein, R 1 to R 7 are each independently a hydrogen atom, an unsubstituted or substituted C1-C20 alkyl group, or an unsubstituted or substituted C6-C20 aryl group, and
n1 is selected from 1 to 1,000, and n2 is selected from 1 to 4.

2. The fluid of claim 1 , wherein the compound of Formula 1 comprises at least one selected from the group consisting of poly(2-acrylamido-2-methyl-1-propane sulfonic acid) of Formula 1a, a compound of Formula 1 b, and a compound of Formula 1c:

wherein n is selected from 1 to 1,000,

wherein n1 is selected from 1 to 1,000, and

wherein n1 is selected from 1 to 1,000,
n2 is selected from 1 to 4, and
R 3 , R 4 , and R 6 are each independently H, CH 3 , or C 2 H 5 .

3. The fluid of claim 1 , wherein the quaternary ammonium hydroxide compound is a compound of Formula 2:

wherein at least one of R 8 to R 11 is an unsubstituted or substituted C1-C20 alkyl group, or an unsubstituted or substituted C6-C20 aryl group, and remaining R 8 to R 11 are each independently a hydrogen atom, an unsubstituted or substituted C1-C20 alkyl group, or an unsubstituted or substituted C6-C20 aryl group.

4. The fluid of claim 1 , wherein the quaternary ammonium hydroxide compound comprises at least one selected from the group consisting of tetramethylammonium hydroxide, tetraethylammonium hydroxide, choline hydroxide, tetrabutylammonium hydroxide, tetrabutylammonium hydroxide 30-hydrate, diethyl dimethyl ammonium hydroxide, ethyltrimethylammonium hydroxide, and trimethylphenylammonium hydroxide.

5. The fluid of claim 1 , wherein an amount of the quaternary ammonium hydroxide compound is in a range of about 1 mol to about 1.5 mol based on 1 mol of the organic acid having an acid dissociation constant of about 4 or less.

6. The fluid of claim 1 , wherein the polar solvent is selected from the group consisting of a polyhydric alcohol, a carbonate-based solvent, γ-butyrolactone, dimethylformamide, N-methylpyrrolidone, and a mixture thereof.

7. The fluid of claim 6 , wherein the polyhydric alcohol is selected from the group consisting of ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, diethylene glycol, triethylene glycol, 1,2,3-propanetriol, and a mixture thereof.

8. The fluid of claim 1 , wherein an amount of the polar solvent is in a range of about 100 parts by weight to about 100,000 parts by weight based on 100 parts by weight of the organic acid having an acid dissociation constant of about 4 or less.

9. The fluid of claim 1 , further comprising a nonionic surfactant.

10. The fluid of claim 1 , wherein the second fluid comprises oil.

11. The fluid of claim 1 , wherein an amount of the organic acid having an acid dissociation constant of about 4 or less is in a range of about 0.0001 part by weight to about 20 parts by weight based on 100 parts by weight of a total weight of the first fluid.

12. The fluid of claim 1 , wherein an amount of the quaternary ammonium hydroxide compound is in a range of about 0.0001 part by weight to about 20 parts by weight based on 100 parts by weight of a total weight of the first fluid.

13. The fluid of claim 1 , wherein the first fluid has an electrical conductivity of about 10 μS/cm to about 10,000 μS/cm.

14. The fluid of claim 1 , wherein a freezing point of the first fluid is in a range of about −5° C. to about −100° C.

15. The fluid of claim 1 , wherein the first fluid and the second fluid each have a light transmittance of about 90% to about 100%.

16. The fluid of claim 1 , which does not contain water.

17. An electrowetting device comprising:
a first electrode and a second electrode facing to each other;
a dielectric layer on the first electrode and the second electrode; and
a fluid disposed between the first electrode and the second electrode and is separated from the first electrode and the second electrode by the dielectric layer,
wherein the fluid is the fluid of claim 1 and the first fluid and the second fluid are separated from each other by an interface.

Assignees

• Samsung Electronics Co Ltd
• Snu R&Db Foundation

Inventors

• Choi Chilsung
• Jang Woohyuk
• Chung Taekdong

Classifications

• H01B1/124

  Intrinsically conductive polymers · CPC title

• G02B26/005 Primary

  based on electrowetting · CPC title

• G02F2201/50

  Protective arrangements · CPC title

• G02F1/1343

  Electrodes {(reflective electrodes G02F1/133553)} · CPC title