Process for friction reduction during ethanol transport

Patent metadata

Field	Value
Publication number	US-9822325-B2
Application number	US-201514713532-A
Country	US
Kind code	B2
Filing date	May 15, 2015
Priority date	May 21, 2014
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

This invention involves a process for reducing friction in ethanol during its transport through pipelines. This process involves combining ethanol with a polymer-based composition, characterized in that the polymer is obtained from at least 50 mol % of at least one monomer selected from the group comprising N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, N,N-substituted methacrylamides, substituted acrylates and substituted methacrylates.

First claim

The invention claimed is:

1. A process for reducing friction during ethanol transport through pipelines, the process comprising combining ethanol with a polymer-based composition comprising a polymer obtained from at least 50 mol % of at least one non-ionic monomer selected from the group consisting of N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, N,N-substituted methacrylamides, substituted acrylates and substituted methacrylates, wherein the quantity of polymer combined with ethanol ranges between 5 and 5,000 ppm in weight as regards the weight of ethanol.

2. The process according to claim 1 , wherein the polymer has a molecular weight ranging between 0.5 and 25 million g/mol.

3. The process according to claim 1 , wherein the at least one monomer has a substituted chain containing less than 30 carbon atoms.

4. The process according to claim 1 , wherein the N-substituted acrylamide monomers, N-substituted methacrylamide monomers, N,N-substituted acrylamide monomers and N,N-substituted methacrylamide monomers are selected from the group consisting of N-ethylacrylamide, N-isopropylacrylamide, N-tert-Butylacrylamide, Diacetoneacrylamide, N-hydroxyethylacrylamide, N-hydroxymethylacrylamide, N-alkyl acrylamide, N-[Tris(hydroxymethyl)methyl]acrylamide, N-acryloylmorpholine, N,N-Dimethylacrylamide, N,N-diethylacrylamide and N,N-dialkylacrylamide; alkyl representing an alkyl group comprising 3 to 22 carbon atoms.

5. The process according to claim 1 , wherein the substituted acrylate monomers and substituted methacrylate monomers are selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, other alkyl acrylate, alkyl methacrylate, isobornyl acrylate, isobornyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, Hydroxyethyl acrylate, Hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, furfuryl acrylate, furfuryl methacrylate, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, glyceryl acrylate, glyceryl methacrylate, glycidyl acrylate, and glycidyle methacrylate; alkyl representing an alkyl group comprising 5 to 22 carbon atoms.

6. The process according to claim 1 , wherein the polymer additionally includes 5 mol % to less than 40 mol % of at least one ionic monomer.

7. The process according to claim 6 , wherein the ionic monomer is an anionic monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid, and 2-Acrylamido-2-methylpropane sulfonic acid (ATBS), the said anionic monomer being in its acid form, salified either partially or completely.

8. The process according to claim 1 , wherein the polymer includes at least 80 mol % of the at least one monomer selected from the group consisting of N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, N,N-substituted methacrylamides, substituted acrylates and substituted methacrylates.

9. The process according to claim 1 , wherein the polymer is a polymer selected from the group consisting of N,N-dimethylacrylamide homopolymer, N,N-diethylacrylamide homopolymer, N,N-dimethylacrylamide copolymer and acrylic acid copolymer, N,N-diethylacrylamide copolymer and acrylic acid copolymer, N,N-dimethylacrylamide copolymer and 2-Acrylamido-2-methylpropane sulfonic acid copolymer and N,N-diethylacrylamide copolymer and 2-Acrylamido-2-methylpropane sulfonic acid copolymer.

10. The process according to claim 1 , wherein the polymer is obtained by a gel synthesis process.

11. The process according to claim 1 , wherein the composition additionally comprises water and/or ethanol.

12. The process according to claim 1 , wherein the polymer is obtained from at least 50 mol % of at least one non-ionic monomer selected from the group consisting of N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, and N,N-substituted methacrylamides.

13. The process according to claim 1 , wherein the ethanol is bioethanol.

14. The process according to claim 2 , wherein the at least one monomer has a substituted chain containing at least 30 carbon atoms.

15. The process according to claim 2 , wherein the N-substituted acrylamide monomers, N-substituted methacrylamide monomers, N,N-substituted acrylamide monomers and N,N-substituted methacrylamide monomers are selected from the group consisting of N-ethylacrylamide, N-isopropylacrylamide, N-tert-Butylacrylamide, Diacetoneacrylamide, N-hydroxyethylacrylamide, N-hydroxymethylacrylamide, N-alkyl acrylamide, N-[Tris(hydroxymethyl)methyl]acrylamide, N-acryloylmorpholine, N,N-Dimethylacrylamide, N,N-diethylacrylamide and N,N-dialkylacrylamide; alkyl representing an alkyl group comprising 3 to 22 carbon atoms.

16. The process according to claim 2 , wherein the substituted acrylate monomers and substituted methacrylate monomers are selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, other alkyl acrylate, alkyl methacrylate, isobornyl acrylate, isobornyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, Hydroxyethyl acrylate, Hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, furfuryl acrylate, furfuryl methacrylate, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, glyceryl acrylate, glyceryl methacrylate, glycidyl acrylate, and glycidyle methacrylate; alkyl representing an alkyl group comprising 5 to 22 carbon atoms.

17. The process according to claim 2 , wherein the polymer additionally includes at least 40 mol % of at least one ionic monomer.

18. The process according to claim 17 , wherein the ionic monomer is an anionic monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid, and 2-Acrylamido-2-methylpropane sulfonic acid (ATBS), the said anionic monomer being in its acid form, salified either partially or completely.

19. The process according to claim 18 , wherein the polymer includes at least 80 mol % of the at least one monomer selected from the group consisting of N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, N,N-substituted methacrylamides, substituted acrylates and substituted methacrylates.

20. The process according to claim 19 , wherein the polymer is a polymer selected from the group consisting of N,N-dimethylacrylamide homopolymer, N,N-diethylacrylamide homopolymer, N,N-dimethylacrylamide copolymer and acrylic acid copolymer, N,N-diethylacrylamide copolymer and acrylic acid copolymer, N,N-dimethylacrylamide copolymer and 2-Acrylamido-2-methylpropane sulfonic acid copolymer and N,N-diethylacrylamide copolymer and 2-Acrylamido-2-methylpropane sulfonic acid copolymer.

Assignees

• Spcm Sa

Inventors

• Favero Cédrick
• Braun Olivier
• Cheucle Pierrick
• Quillien Bernard

Classifications

• C10L1/1963

  mono-carboxylic · CPC title

• C10L1/2364

  homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups (C10L1/221 takes precedence) · CPC title

• C10L2230/14

  for improving storage or transport of the fuel · CPC title

• C10M151/02 Primary

  Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds · CPC title

• C10L2250/04

  Additive or component is a polymer · CPC title