Molybdenum monoxide layers, and production thereof using PVD

Patent metadata

Field	Value
Publication number	US-9822322-B2
Application number	US-201113881855-A
Country	US
Kind code	B2
Filing date	Oct 6, 2011
Priority date	Oct 28, 2010
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

The invention relates to a coating comprising at least one molybdenum-containing layer having molybdenum oxide, said molybdenum being essentially molybdenum monoxide. The invention further relates to a PVD process for producing the disclosed coating, in which the layer comprising the molybdenum monoxide is produced using arc evaporation. The invention also relates to a component that has said coating.

First claim

What is claimed is:

1. Coating comprising:
at least one layer containing molybdenum oxide, characterized in that the molybdenum oxide consists essentially of a molybdenum monoxide,
at least one molybdenum nitride layer, and
at least one Mo—N—O layer including molybdenum-nitrogen compounds and molybdenum-oxide compounds.

2. Coating according to claim 1 , characterized in that the XRD spectrum of the molybdenum monoxide layer essentially exhibits neither MoO 2 peaks nor MoO 3 peaks.

3. Coating according to claim 1 , characterized in that the Mo—N—O layer lies between a molybdenum nitride layer and a molybdenum monoxide layer.

4. Coating according to claim 1 , characterized in that the atomic concentration ratio in the Mo—N—O layer is described by the following formula, Mo z (N d O e ), wherein:
e: is the atomic oxygen concentration in the Mo—N—O layer
d: is the atomic nitrogen concentration in the Mo—N—O layer
z: is the atomic molybdenum concentration in the Mo—N—O layer and z≧e.

5. Coating according to claim 1 , characterized in that the Mo—N—O layer is a graded layer, wherein the nitrogen concentration decreases from the boundary surface close to the substrate towards the boundary surface close to the surface of the Mo—N—O layer whilst the oxygen concentration increases.

6. Coating according to claim 1 , characterized in that the Mo—N—O layer is a graded layer, wherein the oxygen concentration decreases from the boundary surface close to the substrate towards the boundary surface close to the surface of the Mo—N—O layer whilst the nitrogen concentration increases.

7. Coating according to claim 5 or 6 , characterized in that the coating comprises at least one coating according to claim 5 and at least one coating according to claim 6 .

8. Coating according to claim 1 , characterized in that the coating has a cover layer with MoO 3 .

9. Coating according to claim 1 , characterized in that at least one bonding layer and/or at least one functional layer is deposited between a base body and the layer containing Mo.

10. Coating according claim 1 , characterized in that at least one layer containing Mo comprising (Mo 1-x , Me x ) A a B b C c , wherein 0≦x≦0.99 and Me is a metal from the group of W, Ti, Al, Cr, Si, Zr, Ta, Nb, Ag, Cu and V or the combination of two or more metals of this group and
A is nitrogen (N) with 0.5≦a≦1
B is carbon (C) with 0≦b≦0.5
C is oxygen (O) with 0≦c≦0.5

and wherein a, b and c indicate in at % between the elements N, C and O with a+b+c=1, and x≧c.

11. Coating according to claim 1 , characterized in that at least one layer containing Mo comprising (Mo 1-y , Me y ) A u B v C w , wherein 0≦y≦0.99 and Me is a metal from the group of W, Ti, Al, Cr, Si, Zr, Ta, Nb, Ag, Cu and V or the combination of two or more metals of this group and
A is nitrogen (N) with 0.5≦u≦1
B is carbon (C) with 0≦v≦0.5
C is oxygen (O) with 0.5≦w≦1

and wherein u, v and w indicate in at % between the elements N, C and O with u+v+w=1, and y≧w.

12. Coating according to claims 10 and 11 , characterized in that the coating comprises at least one first layer according to claim 10 and a second layer according to claim 11 .

13. Component with a coating, characterized in that the coating is a coating according to claim 1 .

14. Coating according to claim 1 , wherein the molybdenum monoxide is contained in the coating.

15. Coating according to claim 10 , wherein 0≦x≦0.5.

16. Coating according to claim 11 , wherein 0≦y≦0.5.

17. Coating comprising:
at least one molybdenum nitride layer,
at least one Mo—N—O layer formed on the at least one molybdenum nitride layer, the at least one Mo—N—O layer including molybdenum-nitrogen compounds and molybdenum-oxide compounds, and
at least one molybdenum oxide formed on the at least one Mo—N—O layer, wherein the molybdenum oxide consists essentially of a molybdenum monoxide.

Assignees

• Ramm Jurgen
• Widrig Beno
• Glantz Kerstin
• Seibert Florian
• Oerlikon Surface Solutions Ag Pfaffikon

Inventors

• Ramm Jurgen
• Widrig Beno
• Glantz Kerstin
• Seibert Florian

Classifications

• C23C28/42

  characterized by the composition of the alternating layers · CPC title

• C23C14/08 Primary

  Oxides (C23C14/10 takes precedence) · CPC title

• C23C28/044

  coatings specially adapted for cutting tools or wear applications · CPC title

• C23C14/024

  Deposition of sublayers, e.g. to promote adhesion of the coating (C23C14/027 takes precedence) · CPC title

• C23C14/548

  Controlling the composition · CPC title