System and method for on stream catalyst replacement

Patent metadata

Field	Value
Publication number	US-9822316-B2
Application number	US-201514737349-A
Country	US
Kind code	B2
Filing date	Jun 11, 2015
Priority date	Oct 26, 2011
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A system of reforming reactors comprises a plurality of reactors coupled by flow lines, a feed header coupled to the plurality of reactors by a plurality of feed lines, an effluent header coupled to the plurality of reactors by a plurality of effluent lines, and a plurality of valves disposed in the flow lines, the feed lines, and the effluent lines. Each reactor comprises a reforming catalyst, and the plurality of valves is configured to dynamically connect the plurality of reactors to create a first serial flow path and reconnect the plurality of reactors to create a second serial flow path through the plurality of reactors. A first reactor of the plurality of reactors is adjacent to a second reactor of the plurality of reactors in the first serial flow path, and the first reactor is not adjacent to the second reactor in the second serial flow path.

First claim

We claim:

1. A system comprising:
a plurality of reactors coupled by flow lines, wherein each reactor comprises a reforming catalyst;
a feed header coupled to the plurality of reactors by a plurality of feed lines;
an effluent header coupled to the plurality of reactors by a plurality of effluent lines; and
a plurality of valves disposed in the flow lines, the feed lines, and the effluent lines,
wherein the plurality of valves are capable of being dynamically operated to create a first serial flow path through the plurality of reactors, wherein a first reactor of the plurality of reactors is adjacent to a second reactor of the plurality of reactors in the first serial flow path,
wherein the plurality of valves are further configured to dynamically reconnect the plurality of reactors to create a second serial flow path through the plurality of reactors, wherein the first reactor is not adjacent to the second reactor in the second serial flow path; and
wherein the first reactor in the first serial flow path is configured to absorb sulfur present in a hydrocarbon stream passing there through.

2. The system of claim 1 , wherein the plurality of valves are further configured to bypass at least one reactor of the plurality of reactors from the remaining reactors of the plurality of reactors.

3. The system of claim 1 , wherein the reforming catalyst comprising a zeolite, and wherein the reforming catalyst is capable of converting at least a portion of a hydrocarbon stream to aromatic hydrocarbons.

4. The system of claim 1 , further comprising a sulfur removal system upstream of the plurality of reactors.

5. The system of claim 1 , wherein the first reactor is upstream of the second reactor in the first serial flow path, and wherein the first reactor is downstream of the second reactor in the second serial flow path.

6. The system of claim 5 , wherein the reforming catalyst in the first reactor has a lower activity than an activity of the reforming catalyst in the second reactor when the plurality of reactors are configured in the first serial flow path.

7. The system of claim 1 , wherein the first reactor is a first upstream reactor in the first serial flow path, and wherein the first reactor is a last downstream reactor in the second serial flow path.

8. The system of claim 1 , wherein the reforming catalyst comprises at least one Group VIII metal and a zeolitic support.

9. The system of claim 8 , wherein the least one Group VIII metal comprises platinum and the zeolitic support comprises silica bound L-zeolite.

10. The system of claim 1 , wherein the reforming catalyst comprises one or more halogens.

11. The system of claim 1 , wherein the reforming catalyst comprises a zeolite, and wherein the reforming catalyst is capable of converting at least a portion of a hydrocarbon stream to aromatic hydrocarbons in one or more of the plurality of reactors.

12. A system comprising:
a plurality of reactor-furnace pairs coupled by flow lines, wherein each reactor-furnace pair comprises a furnace coupled to a reactor, wherein each reactor comprises a reforming catalyst;
a feed header coupled to the plurality of reactor-furnace pairs by a plurality of feed lines;
an effluent header coupled to the plurality of reactor-furnace pairs by a plurality of effluent lines; and
a plurality of valves disposed in the flow lines, the feed lines, and the effluent lines, wherein the plurality of valves are capable of being dynamically operated to create a serial flow path through the plurality of reactor-furnace pairs, and wherein the plurality of valves are further configured to route the serial flow path to bypass at least one reactor-furnace pair;
wherein a first reactor-furnace pair of the plurality of reactor-furnace pairs in the serial flow path is configured to absorb sulfur present in a hydrocarbon stream passing there through.

13. The system of claim 12 , wherein the plurality of valves are further configured to reconnect the bypassed at least one reactor-furnace pair in a second serial flow path through the plurality of reactor-furnace pairs, wherein the second serial flow path is different than the serial flow path.

14. The system of claim 13 , wherein the plurality of reactor-furnace pairs comprises at least three reactor-furnace pairs, wherein the first reactor-furnace pair of the plurality of reactor-furnace pairs is adjacent to a second reactor-furnace pair of the plurality of reactor-furnace pairs in the serial flow path, wherein the first reactor-furnace pair is not adjacent to the second reactor-furnace pair in the second serial flow path.

15. The system of claim 14 , wherein the first reactor-furnace pair is upstream of the second reactor-furnace pair in the serial flow path, and wherein the first reactor-furnace pair is downstream of the second reactor-furnace pair in the second serial flow path.

16. The system of claim 15 , wherein the reforming catalyst in the first reactor-furnace pair has a lower activity than an activity of the reforming catalyst in the second reactor-furnace pair when the plurality of reactor-furnace pairs are configured in the first serial flow path.

17. The system of claim 12 , further comprising:
a supply header coupled to the plurality of reactor-furnace pairs by a plurality of supply lines;
a return header coupled to the plurality of reactor-furnace pair by a plurality of return lines; a flow system coupled to the supply header and the return header for providing a fluid to at least one of the plurality of reactor-furnace pairs; and
a plurality of flow system valves disposed in the supply lines and the return lines, wherein the plurality of flow system valves are capable of being dynamically operated to couple one or more of the plurality of reactor-furnace pairs to the flow system.

18. The system of claim 12 , wherein the reforming catalyst comprises a zeolite, and wherein the reforming catalyst is capable of converting at least a portion of a hydrocarbon stream to aromatic hydrocarbons in one or more of the plurality of reactors.

19. The system of claim 12 , wherein the reforming catalyst comprises at least one Group VIII metal and a zeolitic support.

20. The system of claim 19 , wherein the at least one Group VIII metal comprises one of platinum, platinum and gold, platinum and rhenium, or any combination thereof.

Assignees

• Chevron Phillips Chemical Co Lp
• Chevron Phillips Chemical Co Lp

Inventors

• Morrison Scott G
• Cheung Tin-Tack Peter
• Bergmeister Iii Joe
• Mcgahee Vincent D
• Murray Bruce D
• Hasenberg Daniel M

Classifications

• C10G2300/701

  Use of spent catalysts · CPC title

• C10G35/095 Primary

  containing crystalline alumino-silicates, e.g. molecular sieves {(C10G35/065 takes precedence)} · CPC title

• B01J2208/02

  with stationary particles · CPC title

• B01J2208/00548

  Flow · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title