Method for preparing synthetic fuel from natural gas of stranded gas field and associated gas from oil and gas fields by GTL-FPSO process

Patent metadata

Field	Value
Publication number	US-9822311-B2
Application number	US-201514951857-A
Country	US
Kind code	B2
Filing date	Nov 25, 2015
Priority date	Dec 24, 2014
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

The present invention relates to a method for preparing a synthetic fuel on a vessel above a stranded gas field or an oil & gas field by a GTL-FPSO process, more particularly to a method for preparing a synthetic fuel with superior economic feasibility, productivity and efficiency using a compact GTL (gas to liquid) apparatus that can be used for a stranded gas field or an oil & gas field and an FPSO (floating production, storage and offloading) process under a condition optimized for the ratio of carbon dioxide in the stranded gas field or the oil & gas field and an apparatus for the same.

First claim

What is claimed is:

1. A method for preparing a synthesis gas from a natural gas of a stranded gas field and associated gas from oil & gas fields through a GTL-FPSO process on a vessel above the stranded gas field and oil and gas fields, comprising:
separating gas phase hydrocarbons and an oil with hydrocarbons containing 5 or more carbons from a natural gas supplied from the stranded gas field;
removing a sulfur component from a separated C 1 -C 4 gas to form a desulfurized gas;
converting a C 2 + higher hydrocarbon in the desulfurized gas to a pre-reformed methane;
producing a synthesis gas comprising carbon monoxide and hydrogen by steam carbon dioxide reforming (SCR) of the pre-reformed methane and carbon dioxide included in the stranded gas field with steam;
preparing a reaction catalyst based on the compositional ratio of hydrogen and carbon monoxide included in the synthesis gas and the volume of unreacted carbon dioxide in the natural gas supplied from the stranded gas field; and
performing a Fischer-Tropsch reaction of the synthesis gas using the reaction catalyst,
wherein the method further comprises separating and purifying a crude GTL fuel from a liquid hydrocarbon compound or a wax with low fluidity after the Fischer-Tropsch reaction process to separately recover gasoline and diesel.

2. The method according to claim 1 , wherein the stranded gas field and associated gas comprises 5-55 vol % of carbon dioxide in the natural gas.

3. The method according to claim 1 , wherein the Fischer-Tropsch reaction is selected from one or more of a reaction using a cobalt-based catalyst, a reaction using an iron-based catalyst and a reaction using a cobalt- and iron-based catalyst.

4. The method according to claim 1 , wherein the reaction catalyst is selected depending on the initial carbon dioxide content in the stranded gas field and associated gas or the content of carbon monoxide and hydrogen in the synthesis gas after the reforming reaction.

5. The method according to claim 1 , wherein a Fischer-Tropsch reactor is configured such that the Fischer-Tropsch reaction can be performed in a reactor selected from a cobalt (Co)-based catalytic reactor, an iron (Fe)-based catalytic reactor and a cobalt- and iron-based (Co—Fe) catalytic reactor using the catalyst selected based on the compositional ratio of the synthesis gas supplied to the Fischer-Tropsch reactor.

6. The method according to claim 5 , wherein the Fischer-Tropsch reactor further comprises a cobalt- and iron-based catalytic reactor as a preliminary reactor.

7. The method according to claim 1 , wherein, in the reaction catalyst selection process, a cobalt-based catalyst is used if the compositional ratio of hydrogen and carbon monoxide (H 2 /CO) of the synthesis gas is 1.8-2.2 and an iron-based catalyst is used if the molar ratio is outside the range.

8. The method according to claim 1 , wherein, in the separation/purification process, all or part of the separated C 1 -C 4 gas is recycled to one or more process selected from the pre-reforming process, the reforming process and the Fischer-Tropsch reaction process.

9. The method according to claim 1 , wherein the carbon compound or wax with low fluidity separated in the separation/purification process is collected and separated as gasoline, kerosene or diesel through an upgrading process.

Assignees

• Korea Inst Sci & Tech

Inventors

• Moon Dong Ju
• Jung Jae Sun
• Yang Eun Hyeok
• Lee Jae Suk
• Noh Young Su
• Hong Gi Hoon
• Lee Sang Yong
• Lim Sung Soo
• Kim Na Young

Classifications

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title

• C01B3/382

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title