Hot melt adhesive

Patent metadata

Field	Value
Publication number	US-9822283-B2
Application number	US-201414211481-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Sep 16, 2011
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

The present invention provides hot melt adhesives for disposable products. The hot melt adhesives may be applied at high-speed and at low temperature ranges. The hot melt adhesives also provide excellent adhesion to polyethylene and a nonwoven fabric. The hot melt adhesive comprises (A) a thermoplastic block copolymer, which is a copolymer of a vinyl-based aromatic hydrocarbon with a conjugated diene compound; and (B) a propylene homopolymer having a melting point of 100° C. or lower, which is obtainable by polymerizing propylene using a metallocene catalyst. The disposable products are produced at high-speeds and low temperature with the inventive hot melt, and therefore, the disposal products are produced efficiently and safely, and a nonwoven fabric and a polyethylene film of the disposable products are less likely to peel.

First claim

The invention claimed is:

1. A hot melt adhesive comprising:
a polymer component consisting of: (A) 3 to 30 parts by weight of a thermoplastic styrene block copolymer having a styrene content of less than 20 wt %; and (B) greater than 20 to 35 parts by weight of a propylene homopolymer having a melting point of 80° C. or lower that is prepared by polymerizing propylene with a metallocene catalyst;
(C) a tackifier resin;
(D) a plasticizer; and
an additive, the additive comprising a stabilizing agent, filler, or mixtures thereof,
wherein all parts by weight are based on 100 parts by weight of the total weight of components (A) to (D).

2. The hot melt adhesive according to claim 1 , wherein the adhesive has a melt viscosity of 2,000 to 7,000 mPa·s at 140° C.

3. The hot melt adhesive according to claim 1 , wherein the thermoplastic styrene block copolymer (A) is selected from the group consisting of (A1) a hydrogenated styrene-butadiene block copolymer (SEBS), (A2) a hydrogenated styrene-isoprene block copolymer (SEPS), and mixtures thereof.

4. The hot melt adhesive according to claim 3 , wherein the styrene content is from 10 to 15% by weight of the thermoplastic styrene block copolymer.

5. The hot melt adhesive according to claim 1 , wherein the propylene homopolymer is selected from the group consisting of (B1) a propylene homopolymer having a weight average molecular weight of 60,000 or less, (B2) a propylene homopolymer having a weight average molecular weight of more than 60,000, and mixtures thereof.

6. The hot melt adhesive according to claim 5 , wherein the propylene homopolymer has a polydispersity (Mw/Mn) of 1 to 3.

7. The hot melt adhesive according to claim 1 , wherein the plasticizer is (D1) a naphthene oil or (D2) a paraffin oil.

8. The hot melt adhesive according to claim 7 , wherein the tackifier resin is a hydrogenated dicyclopentadiene-based resin.

9. The hot melt adhesive according to claim 7 , further comprising an olefin wax that has been modified with carboxylic acid or carboxylic anhydride.

10. The hot melt adhesive according to claim 9 , wherein the carboxylic acid or carboxylic anhydride is selected from the group consisting of maleic acid, maleic anhydride, fumaric acid, fumaric anhydride, itaconic acid, acrylic acid, methacrylic acid, and mixtures thereof.

11. An article comprising the hot melt adhesive of claim 1 , which is a disposable product.

12. The article of claim 11 comprising a substrate selected from the group consisting of woven fabric, a nonwoven fabric, a rubber, a resin, papers and polyolefin film.

13. The article of claim 12 , wherein the substrate is polyolefin film.

14. The article of claim 11 which is a paper diaper, a sanitary napkin, a pet sheet, a hospital gown or surgical garment.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Inoue Kentarou

Classifications

• C09J7/22

  Plastics; Metallised plastics · CPC title

• C09J2453/00

  Presence of block copolymer · CPC title

• C09J7/21

  Paper; Textile fabrics · CPC title

• C08L23/12

  Polypropene · CPC title

• C09J153/02 Primary

  Vinyl aromatic monomers and conjugated dienes · CPC title