Assembly for producing alkylene oxides and glycol ethers

Patent metadata

Field	Value
Publication number	US-9822087-B2
Application number	US-201615043368-A
Country	US
Kind code	B2
Filing date	Feb 12, 2016
Priority date	Jul 14, 2010
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

There is provided a manufacturing assembly for the production of an alkylene oxide and a stream of glycol ethers. The manufacturing assembly produces the alkylene oxide and stream of glycol without the use of equipment for separating substantially all of the alkyl alcohol from the alkylene oxide product stream. Thus, the use of additional pieces of equipment can be avoided, or the equipment required to effectuate any required further separation and/or purification may be smaller and/or cheaper to purchase and/or operate.

First claim

The invention claimed is:

1. A manufacturing assembly for the production of an alkylene oxide and one or more glycol ethers, the assembly comprising: a reactor appropriate for housing a reaction to produce an alkylene oxide product stream; an exit stream of the reactor being the alkylene oxide product stream comprising from about 5 to about 15 weight percent alkylene oxide, about 50 to about 85 weight percent alkyl alcohol, and about 10 to about 25 weight percent water; a first distillation column that is operatively disposed relative to the reactor and that receives the alkylene oxide product stream from the reactor, the first distillation column comprising fewer than 80 theoretical stages; an exit stream of the first distillation column being a refined stream comprising from about 70 to about 95 weight percent alkylene oxide, about 1 to about 30 weight percent alkyl alcohol, and about 0.1 to about 4.9 weight percent water; a vessel operatively that is disposed relative to the first distillation column and that receives the refined stream from the first distillation column and housing a catalyst capable of reacting with the refined stream; an exit stream of the vessel being a reacted stream comprising reacted stream comprising less than 1 wt % alkyl alcohol, from about 0.01 to about 98 weight percent alkylene oxide, and from about 2 to about 99 weight percent glycol ethers; and a second distillation column that is operatively disposed relative to the vessel and that receives the reacted stream from the vessel; and an exist stream of the second distillation being a stream of alkylene oxide and a stream of glycol ethers.

2. The manufacturing assembly of claim 1 , wherein the alkylene oxide comprises ethylene oxide, propylene oxide, butylene oxide, pentylene oxide, hexylene oxide, and combinations thereof.

3. The manufacturing assembly of claim 1 , wherein said alkylene oxide is propylene oxide.

4. The manufacturing assembly of claim 1 , wherein the alcohol comprises methanol, ethanol, propanol, butanol, pentanol, hexanol, 2-ethylhexyl alcohol, and combinations thereof.

5. The manufacturing assembly of claim 1 , wherein the alcohol comprises methanol.

6. The manufacturing assembly of claim 1 , wherein the catalyst comprises a metal-ligand complex, an acid, a base, or a combination of any number of these to produce a reacted stream comprising less than 1 wt % alkyl alcohol from about 0.01 to about 98 weight percent alkylene oxide and from about 2 to about 99 weight percent glycol ethers; wherein the metal ligand complex comprises a monomer defined by the formula:

wherein R 1 , R 2 , R 3 , R 4 , Y 1 , Y 2 , X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , and X 8 comprise, independently of one other, substituents selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydrocarbyl, hydroxyl, alkoxyl, amino, nitro, amide, phosphoryl, phosphonate, phosphine, carbonyl, carboxyl, silyl, ether, thioether, sulfonyl, selenoether, ketone, aldehyde, and ester;
or wherein two or more of R 1 , R 2 , R 3 , R 4 , Y 1 , Y 2 , X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , and X 8 together form a ring selected from the group consisting of a carbocyclic ring and a heterocyclic ring, said ring having from 4 to 10 atoms in the ring;
wherein R 5 group is selected from the group comprising a carbon-carbon bond, a methylene group, an ethylene group, an amine, an oxygen atom, and a sulfur atom;
wherein M t+ is a Group 2-15 metal capable of complexing with a ligand to affect catalysis, wherein t is an integer between 2 and 4;
wherein group A is selected from the group consisting of neutral group, bound anionic group, unbound anionic group, and combinations thereof, wherein s is the number of A groups associated with the metal and is an integer between 0 and 2.

Assignees

• Dow Global Technologies Llc

Inventors

• Arrowood Tina L
• Flick Derrick W
• Ackford John F

Classifications

• B01J19/245

  placed in series · CPC title

• C07D301/12

  with hydrogen peroxide or inorganic peroxides or peracids · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07D301/36

  Use of additives, e.g. for stabilisation · CPC title

• C07D301/32 Primary

  Separation; Purification · CPC title