Pressureless sintering-based method for making a two-phase ceramic composite body

Patent metadata

Field	Value
Publication number	US-9822040-B1
Application number	US-28716108-A
Country	US
Kind code	B1
Filing date	Oct 6, 2008
Priority date	Oct 5, 2007
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

Inventive manufacture of CrB 2 —Al 2 O 3 composites is based on pressureless sintering. According to typical inventive practice, CrB 2 powder and Al 2 O 3 powder are mixed together in selected volumetric proportions so that the volume of the CrB 2 does not exceed 50% of the overall volume of the CrB 2 —Al 2 O 3 mixture. The CrB 2 —Al 2 O 3 mixture is shaped into a green body. The green body is pressureless sintered in a non-oxidizing atmosphere at a firing temperature in the approximate range between 1600° C. and 2050° C. The present invention succeeds in preparing, via pressureless sintering, a proportionality-associated range of compositions in the CrB 2 —Al 2 O 3 system, which is a potentially “advanced” ceramic system. A typical inventively fabricated CrB 2 —Al 2 O 3 composite is inventively configured in a complex shape, and has “advanced” material (e.g., mechanical) properties that are favorable for a contemplated application. Inventive manufacture of ceramic-ceramic composites is thus dually attributed, and uncommonly so, with complex shape-ability and advanced capability.

First claim

What is claimed is:

1. A method for making a chromium diborid-aluminum oxide two-phase ceramic composite body, the method comprising:
mixing chromium diboride powder and aluminum oxide powder to produce a mixture, said mixture consisting of said chromium diboride and said aluminum oxide, wherein said chromium diboride constitutes a percentage by volume of said mixture in the range between 21% and 30%, and said aluminum oxide constitutes a percentage by volume of said mixture in the range between 70% and 79%;
shaping said mixture to form a green body, said green body including said chromium diboride and said aluminum oxide;
pressureless sintering said green body in a non-oxidizing atmosphere at a firing temperature in the range between 1600° C. and 1699° C., the pressureless sintered said green body including said chromium diboride and said aluminum oxide;
wherein said pressureless sintering of said green body is performed to obtain a chromium diboride-aluminum oxide two-phase ceramic composite that is fully dense.

2. The method of claim 1 wherein the method further comprises milling said mixture prior to said shaping.

3. The method of claim 1 wherein said non-oxidizing atmosphere is one of a vacuum, an inert gas, and a reducing gas.

4. The method of claim 1 wherein said shaping includes using at least one shaping technique selected from the group consisting of die pressing, cold isostatic pressing, extrusion, slip casting, and injection molding.

5. The method of claim 1 wherein the method further comprises cooling the pressureless sintered said green body.

6. The method of claim 5 wherein the method further comprises at least one of:
machining said green body prior to said pressureless sintering; and
machining the cooled pressureless sintered said green body.

7. The method of claim 1 wherein said chromium diboride constitutes a percentage by volume of said mixture in the range between 22% and 30%, and said aluminum oxide constitutes a percentage by volume of said mixture in the range between 70% and 78%.

8. The method of claim 1 wherein said chromium diboride constitutes a percentage by volume of said mixture in the range between 23% and 30%, and said aluminum oxide constitutes a percentage by volume of said mixture in the range between 70% and 77%.

9. A method for making a CrB 2 —Al 2 O 3 two-phase ceramic composite article, the method comprising:
preparing a blend of chromium diboride powder and aluminum oxide powder, said blend consisting of said chromium diboride and said aluminum oxide,
wherein the prepared said blend of chromium diboride powder and aluminum oxide powder is in volumetric proportions in the range between 21% CrB 2 -79% Al 2 O 3 and 30% CrB 2 -70% Al 2 O 3 ;
shaping said blend into a green body, said green body including said chromium diboride and said aluminum oxide;
densifying said green body in the absence of applied pressure in a non-oxidizing atmosphere, said densifying of said green body including heating said green body in a furnace to a temperature in the range between 1600° C. and 1699° C., the densified said green body including said chromium diboride and said aluminum oxide;
wherein said densifying of said green body is performed to obtain a chromium diboride-aluminum oxide two-phase ceramic composite that is fully dense.

10. The method of claim 9 wherein said shaping of said blend includes cold isostatic pressing.

11. The method of claim 9 wherein said non-oxidizing atmosphere is either a vacuous atmosphere or a gaseous atmosphere.

12. The method of claim 11 wherein said gaseous atmosphere is either an inert gaseous atmosphere or a reducing gaseous atmosphere.

13. The method of claim 9 wherein the method further comprises at least one of:
machining said green body prior to said densifying of said green body; and
machining the densified said green body.

14. The method of claim 9 wherein the prepared said blend of chromium diboride powder and aluminum oxide powder is in volumetric proportions in the range between 22% CrB 2 -78% Al 2 O 3 and 30% CrB 2 -70% Al 2 O 3 .

15. The method of claim 9 wherein the prepared said blend of chromium diboride powder and aluminum oxide powder is in volumetric proportions in the range between 23% CrB 2 -77% Al 2 O 3 and 30% CrB 2 -70% Al 2 O 3 .

Assignees

• Martin Curtis A
• Zaykoski James A
• Talmy Inna G
• Us Navy

Inventors

• Martin Curtis A
• Zaykoski James A
• Talmy Inna G

Classifications

• C04B35/5805 Primary

  based on borides · CPC title

• A61L27/427 Primary

  of other specific inorganic materials not covered by A61L27/422 or A61L27/425 · CPC title

• B32B3/16

  secured to a flexible backing · CPC title

• F16C2206/60

  Silicon nitride (Si3N4)l · CPC title

• F16C33/6696

  with solids as lubricant, e.g. dry coatings, powder · CPC title