Forward osmosis separation processes

Patent metadata

Field	Value
Publication number	US-9822021-B2
Application number	US-201615161284-A
Country	US
Kind code	B2
Filing date	May 23, 2016
Priority date	Feb 1, 2001
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

Separation processes using forward osmosis are disclosed generally involving the extraction of a solvent from a first solution to concentrate a solute therein by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. One or both of the solute and solvent may be a desired product. By manipulating the equilibrium of the soluble and insoluble species of solute within the second solution, a saturated second solution can be used to generate osmotic pressure on the first solution. The various species of solute within the second solution can be recovered and recycled through the process to affect the changes in equilibrium and eliminate waste products. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources.

First claim

What is claimed is:

1. A method of concentrating at least one solute using a forward osmosis separation process, the method comprising the steps of:
introducing a first solution comprising the at least one solute to a first side of a semi-permeable membrane;
introducing a concentrated draw solution comprising ammonia and carbon dioxide in a molar ratio of at least 1:1, as draw solute, to a second side of the semi-permeable membrane;
concentrating the at least one solute within the first solution by promoting the flow of a solvent from the first solution, across the membrane and into the concentrated draw solution via an osmotic concentration gradient across the semi-permeable membrane, thereby creating a solvent enriched draw solution; and
maintaining the osmotic concentration gradient across the semi-permeable membrane to remove most of the solvent from the concentrated first solution, wherein the step of maintaining the osmotic concentration gradient across the membrane comprises the steps of:
directing the solvent enriched draw solution to a separation process;
removing the at least one draw solute from the solvent enriched draw solution; and
returning the removed draw solute to the second side of the semi-permeable membrane.

2. The method of claim 1 , further comprising the step of extracting the at least one solute from the concentrated first solution.

3. The method of claim 2 , wherein the step of extracting the at least one solute comprises introducing the concentrated first solution to at least one of a solar evaporator, screen filtration, a settling vessel, a hydrocyclone, a precipitator, a force gradient operation, or nucleation point.

4. The method of claim 2 , further comprising processing the extracted at least one solute for at least one of a consumer or an industrial purpose.

5. The method of claim 1 , wherein the at least one solute is selected from the group consisting of a salt, sugar, enzyme, protein, drug, or microorganism.

6. The method of claim 1 , wherein the first solution comprises salts, organic matter, suspended colloids or biological organisms.

7. The method of claim 1 , wherein the first solution comprises wastewater.

8. The method of claim 1 , wherein the step of directing the solvent enriched draw solution to a separation process comprises introducing at least a portion of the solvent enriched draw solution to at least one of a distillation column, a membrane distillation system, or a pervaporation system.

9. The method of claim 1 , further comprising a step of introducing waste heat to remove at least one solute from the solvent enriched draw solution.

10. A forward osmosis separation process, comprising:
introducing a first solution comprising a solvent and at last one precipitable solute on a first side of a semipermeable membrane;
introducing a concentrated draw solution comprising ammonia and carbon dioxide in a molar ratio of at least 1:1, as draw solute, to a second side of the semi-permeable membrane;
concentrating the at least one precipitable solute within the first solution by promoting the flow of the solvent from the first solution, across the membrane and into the concentrated draw solution via an osmotic concentration gradient across the semi-permeable membrane, thereby creating a solvent enriched draw solution;
maintaining the osmotic concentration gradient across the semi-permeable membrane to remove most of the solvent from the first solution;
wherein the step of maintaining the osmotic concentration gradient across the semi-permeable membrane comprises the steps of: directing the solvent enriched draw solution to a separation process; removing draw solutes from the solvent enriched draw solution; returning the draw solutes to the second side of the semi-permeable membrane; and
recovering the at least one precipitable solute from the concentrated first solution.

11. The process of claim 10 , wherein the step of recovering the at least one precipitable solute comprises introducing the concentrated first solution to at least one of a solar evaporator, screen filtration, a settling vessel, a hydrocyclone, a precipitator, a force gradient operation, or nucleation point.

12. The process of claim 10 , wherein the at least one precipitable solute is selected from the group consisting of a salt, sugar, enzyme, protein, drug, or microorganism.

13. The process of claim 10 , wherein the first solution comprises salts, organic matter, suspended colloids, or biological organisms.

14. The process of claim 10 , wherein the at least one precipitable solute comprises an ionic salt species selected from the group consisting of chloride, sulfate, bromide, silicate, iodide, phosphate, sodium, magnesium, calcium, potassium, nitrate, arsenic, lithium, boron, strontium, molybdenum, manganese, aluminum, cadmium, chromium, cobalt, copper, iron, lead, nickel, selenium, silver, and zinc.

Assignees

• Univ Yale

Inventors

• Mcginnis Robert L
• Elimelech Menachem

Classifications

• B01D61/005

  Osmotic agents; Draw solutions · CPC title

• C02F1/445 Primary

  by forward osmosis · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• Y02W10/37

  using solar energy · CPC title

• B01D61/002

  Forward osmosis or direct osmosis · CPC title