Marked thermoplastic compositions, methods of making and articles comprising the same, and uses thereof
US-2016193864-A1 · Jul 7, 2016 · US
US9821585B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9821585-B2 |
| Application number | US-201214351437-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 10, 2012 |
| Priority date | Nov 17, 2011 |
| Publication date | Nov 21, 2017 |
| Grant date | Nov 21, 2017 |
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A laser-marked polymer workpiece is described. The workpiece has a transparent component and an opaque component applied to at least one region of the transparent component. A mark is introduced onto a surface of the opaque component facing the transparent component with at least one laser. The mark is introduced, via a laser, through the transparent component. The mark is a lightening of the surface of the opaque component on which the mark was introduced.
Opening claim text (preview).
The invention claimed is: 1. A method for producing a laser-marked polymer workpiece, comprising: bonding a transparent component having a transmission in visible spectral range equal to or greater than 50% and an opaque component having a transmission in visible spectral range equal to or less than 20% via multi-component injection molding to form a polymer workpiece, the opaque component containing at least one colorant, and irradiating the opaque component through the transparent component with at least one laser thereby introducing a mark on a surface of the opaque component, wherein the mark is a brightening of the opaque component, wherein the opaque component is devoid of a laser sensitive additive, and wherein the at least one colorant comprises at least one black pigment. 2. The method according to claim 1 , wherein the mark is introduced on the surface of the opaque component by a movement of a beam of the laser. 3. The method according to claim 1 , wherein a beam of the laser is focused on a boundary surface between the transparent component and the opaque component. 4. The method according to claim 1 , wherein an emission wavelength of the laser is from 600 nm to 3000 nm. 5. The method according to claim 1 , wherein the laser is operated in pulsed mode and a pulse duration is from 5 ns to 300 ns, and a pulse repetition frequency is from 1 kHz to 500 kHz. 6. The method according to claim 1 wherein an output power of the laser is from 1 W to 50 W. 7. The method according to claim 2 , wherein the beam of the laser is moved at a speed from 200 mm/s to 5000 mm/s. 8. The method according to claim 1 , wherein an emission wavelength of the laser is from 900 nm to 1500 nm. 9. The method according to claim 1 , wherein the laser is operated in pulsed mode and a pulse duration is from 5 ns to 300 ns, and a pulse repetition frequency is from 20 kHz to 150 kHz. 10. The method according to claim 1 wherein an output power of the laser is from 15 W to 35 W. 11. The method according to claim 1 , wherein the black pigment comprises one or more of carbon black, aniline black, bone black, iron oxide black, spinel black, and graphite. 12. The method according to claim 1 , wherein the workpiece comprises one or more of polycarbonate, polyethylene terephthalate, and polymethyl methacrylate.
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