Interlayer for laminated glass, and laminated glass

Patent metadata

Field	Value
Publication number	US-9821535-B2
Application number	US-201314439647-A
Country	US
Kind code	B2
Filing date	Oct 31, 2013
Priority date	Oct 31, 2012
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

There is provided an interlayer film for laminated glass which is capable of enhancing sound insulating properties in the laminated glass obtained in the case of being used for constituting the laminated glass, and laminated glass prepared using the interlayer film for laminated glass. An interlayer film for laminated glass according to the present invention includes a modified polyvinyl acetate and a plasticizer, and the modified polyvinyl acetate has a vinyl acetate structural unit and a fatty acid vinyl ester structural unit; the laminated glass according to the present invention includes a first laminated glass constituent member, a second laminated glass constituent member, and an interlayer film sandwiched between the first and second laminated glass constituent members, and in the laminated glass according to the present invention, the interlayer film is the interlayer film for laminated glass described above.

First claim

The invention claimed is:

1. An interlayer film for laminated glass, comprising a modified polyvinyl acetate and a plasticizer; and the modified polyvinyl acetate having a vinyl acetate structural unit and a fatty acid vinyl ester structural unit,
the modified polyvinyl acetate having the vinyl acetate structural unit, the fatty acid vinyl ester structural unit and a structural unit derived from a monomer having a carboxyl group,
the modified polyvinyl acetate containing the vinyl acetate structural unit in a content greater than or equal to 45% by mole and less than or equal to 98.99% by mole, the fatty acid vinyl ester structural unit in a content greater than or equal to 1% by mole and less than or equal to 50% by mole, and the structural unit derived from a monomer having a carboxyl group in a content greater than or equal to 0.01% by mole and less than or equal to 5% by mole, in 100% by mole of the total of the vinyl acetate structural unit, the fatty acid vinyl ester structural unit and the structural unit derived from a monomer having a carboxyl group.

2. The interlayer film for laminated glass according to claim 1 ,
wherein the fatty acid vinyl ester structural unit is a structural unit derived from a fatty acid vinyl ester and introduced by the fatty acid vinyl ester, and the fatty acid vinyl ester is vinyl caprylate, vinyl caprate, vinyl laurate, vinyl myristate, vinyl palmitate, vinyl stearate, vinyl cinnamate or vinyl neodecanoate.

3. The interlayer film for laminated glass according to claim 1 ,
wherein the monomer having a carboxyl group is (meth)acrylic acid, maleic acid, fumaric acid, crotonic acid, Taconic acid, a monoester of maleic acid, a monoester of fumaric acid or a monoester of itaconic acid.

4. The interlayer film for laminated glass according to claim 1 ,
wherein the modified polyvinyl acetate contains the vinyl acetate structural unit in a content greater than or equal to 50% by mole in 100% by mole of the total of the vinyl acetate structural unit and the fatty acid vinyl ester structural unit.

5. The interlayer film for laminated glass according to claim 1 ,
wherein the polymerization degree of the modified polyvinyl acetate is greater than or equal to 1000 and less than or equal to 9000.

6. The interlayer film for laminated glass according to claim 1 , being an interlayer film for laminated glass having a one-layer structure provided with only a first layer or a two or more-layered structure provided with the first layer and other layer(s),
wherein the first layer includes the modified polyvinyl acetate and the plasticizer.

7. The interlayer film for laminated glass according to claim 1 ,
wherein the fatty acid vinyl ester structural unit is a structural unit derived from a fatty acid vinyl ester and introduced by the fatty acid vinyl ester, and the number of carbon atoms of the fatty acid vinyl ester is less than or equal to 20.

8. The interlayer film for laminated glass according to claim 7 ,
wherein the number of carbon atoms of the fatty acid vinyl ester is greater than or equal to 5 and less than or equal to 20.

9. The interlayer film for laminated glass according to claim 1 ,
wherein the modified polyvinyl acetate is obtained by allowing vinyl acetate and a fatty acid vinyl ester to undergo copolymerization in the presence of a compound having a structural unit represented by the following formula (X):

wherein X1 and X2 each represent an alkyl group with 1 to 12 carbon atoms, a hydrogen atom or a metal salt, Y1 represents a carboxylic acid group, a carboxylic acid ester group, a carboxylic acid metal salt or a hydrogen atom, g represents an integer of 0 to 3, and h represents an integer of 0 to 12.

10. The interlayer film for laminated glass according to claim 9 ,
wherein the modified polyvinyl acetate is obtained by allowing the vinyl acetate and the fatty acid vinyl ester to undergo copolymerization in the presence of a compound having a structural unit represented by the formula (X).

11. The interlayer film for laminated glass according to claim 9 ,
wherein the modified polyvinyl acetate has the vinyl acetate structural unit, the fatty acid vinyl ester structural unit and a structural unit derived from a monomer having a carboxyl group, and
the modified polyvinyl acetate is obtained by allowing the vinyl acetate, the fatty acid vinyl ester, and the monomer having a carboxyl group to undergo copolymerization in the presence of a compound having a structural unit represented by the formula (X).

12. The interlayer film for laminated glass according to claim 1 , being provided with a first layer and a second layer layered on a first surface of the first layer,
wherein the first layer includes the modified polyvinyl acetate and the plasticizer.

13. The interlayer film for laminated glass according to claim 12 ,
wherein the second layer includes a polyvinyl acetal resin, and
the acetylation degree of the polyvinyl acetal resin in the second layer is less than or equal to 15% by mole and the content ratio of hydroxyl groups therein is greater than or equal to 20% by mole.

14. The interlayer film for laminated glass according to claim 12 , being further provided with a third layer layered on a second surface opposite to the first surface of the first layer.

15. The interlayer film for laminated glass according to claim 14 ,
wherein the third layer includes a polyvinyl acetal resin, and
the acetylation degree of the polyvinyl acetal resin in the third layer is less than or equal to 15% by mole and the content ratio of hydroxyl groups therein is greater than or equal to 20% by mole.

16. Laminated glass, comprising:
a first laminated glass constituent member,
a second laminated glass constituent member, and
the interlayer film for laminated glass according to claim 1 ; and the interlayer film for laminated glass being sandwiched between the first and second laminated glass constituent members.

17. An interlayer film for laminated glass, being provided with a first layer, a second layer layered on a first surface of the first layer and a third layer layered on a second surface opposite to the first surface of the first layer,
the first layer including a modified polyvinyl acetate and a plasticizer,
the content of the plasticizer in the first layer being greater than or equal to 25 parts by weight relative to 100 parts by weight of the modified polyvinyl acetate in the first layer,
the modified polyvinyl acetate having a vinyl acetate structural unit and a fatty acid vinyl ester structural unit.

18. An interlayer film for laminated glass according to claim 17 ,
wherein the second layer includes a thermoplastic resin and a plasticizer, and the third layer includes a thermoplastic resin and a plasticizer.

19. Laminated glass, comprising:
a first laminated glass constituent member,
a second laminated glass constituent member, and
the interlayer film for laminated glass according to claim 17 ; and the interlayer file for laminated glass being sandwiched between the first and second laminated glass constituent members.

Assignees

• Sekisui Chemical Co Ltd
• Denki Kagaku Kogyo Kk

Inventors

• Shimamoto Michio
• Iwamoto Tatsuya
• Komatsu Ryousuke
• Yoshida Shougo
• Tanno Nobuyuki
• Hashimoto Takao
• Otake Hirohisa

Classifications

• B32B17/10605

  Type of plasticiser · CPC title

• B32B2250/40

  Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA · CPC title

• B32B2307/102

  Insulating · CPC title

• B32B2250/03

  3 layers · CPC title

• B60J1/02

  arranged at the vehicle front {, e.g. structure of the glazing, mounting of the glazing (on windscreen mounted antenna wire H01Q1/1271)} · CPC title