Configurations, systems, and methods for recovery of elemental sulfur using a solvent

Patent metadata

Field	Value
Publication number	US-9821267-B2
Application number	US-201414508758-A
Country	US
Kind code	B2
Filing date	Oct 7, 2014
Priority date	Oct 7, 2013
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

Elemental sulfur carrying capacity of a hydrocarbonaceous solvent is improved by first loading the solvent with sulfur and subsequent hydrotreatment under conditions that convert at least some of the elemental sulfur in the sulfur loaded solvent to hydrogen sulfide while preserving at least 95% of the monoaromatic and polyaromatic components in the solvent.

First claim

What is claimed is:

1. A method of increasing elemental sulfur carrying capacity of a sulfur removal solvent, comprising:
contacting a lean hydrocarbonaceous solvent with elemental sulfur to so produce a sulfur loaded solvent, wherein the lean hydrocarbonaceous solvent comprises a plurality of monoaromatic and polyaromatic components;
subjecting the sulfur loaded solvent to a catalytic hydrogenation step that converts at least some of the elemental sulfur to hydrogen sulfide and that preserves at least 95% of the plurality of monoaromatic and polyaromatic components to so produce a conditioned solvent; and
wherein the conditioned solvent has an elemental sulfur carrying capacity that is higher than an elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent,
wherein the elemental sulfur is high-purity or pure.

2. The method of claim 1 , wherein the plurality of monoaromatic and polyaromatic components in the lean hydrocarbonaceous solvent are present in an amount of between 35 wt % and 85 wt %.

3. The method of claim 1 , wherein the lean hydrocarbonaceous solvent is a diesel oil or a light cycle oil.

4. The method of claim 1 , wherein the temperature of the catalytic hydrogenation step is between 150° C. and 350° C.

5. The method of claim 1 , wherein the temperature of the catalytic hydrogenation step is between 170° C. to 210° C. when performed with a molybdenum catalyst, or wherein the temperature of the catalytic hydrogenation step is between 295° C. to 335° C. when performed with a cobalt-molybdenum catalyst.

6. The method of claim 1 , wherein the elemental sulfur carrying capacity of the conditioned solvent is at least 10% greater than the elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent.

7. The method of claim 1 , wherein the elemental sulfur carrying capacity of the conditioned solvent is at least 20% greater than the elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent.

8. A method of improving sulfur removal from a sulfur-containing production stream, comprising:
forming a conditioned solvent by loading a lean hydrocarbonaceous solvent having a plurality of monoaromatic and polyaromatic components with elemental sulfur to produce a sulfur loaded solvent and by catalytic hydrogenation of the sulfur loaded solvent;
wherein the catalytic hydrogenation converts at least some of the elemental sulfur in the sulfur loaded solvent to hydrogen sulfide while preserving at least 95% of the plurality of monoaromatic and polyaromatic components, and wherein the conditioned solvent has an elemental sulfur carrying capacity that is higher than an elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent; and
contacting the sulfur-containing production stream with the conditioned solvent to produce a rich solvent and a treated production stream,
wherein the elemental sulfur is high-purity or pure.

9. The method of claim 8 , further comprising subjecting the rich solvent to catalytic hydrogenation under conditions substantially the same as those used for forming the conditioned solvent.

10. The method of claim 8 , wherein the elemental sulfur is obtained from the sulfur-containing production stream.

11. The method of claim 8 , wherein the conditioned solvent comprises at least 20% of the rich solvent after catalytic hydrogenation.

12. The method of claim 8 , wherein the conditioned solvent is the rich solvent after catalytic hydrogenation.

13. The method of claim 8 , wherein the catalytic hydrogenation is performed using a molybdenum catalyst and/or cobalt-molybdenum catalyst at a hydrogen partial pressure of between 50-200 psia and a temperature of between 170° C. and 335° C.

14. The method of claim 8 , wherein the elemental sulfur carrying capacity of the conditioned solvent is at least 10% greater than the elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent.

15. The method of claim 8 , wherein the elemental sulfur carrying capacity of the conditioned solvent is at least 20% greater than the elemental sulfur carrying capacity of the lean hydrocarbonaceous solvent.

16. The method of claim 1 , wherein the catalytic hydrogenation step is performed using a molybdenum catalyst and/or cobalt-molybdenum catalyst at a hydrogen partial pressure of between 50-200 psia.

17. The method of claim 1 , further comprising:
contacting a sulfur-containing production stream with the conditioned solvent to produce a rich solvent and a treated production stream.

18. The method of claim 17 , further comprising:
subjecting the rich solvent to catalytic hydrogenation under conditions substantially the same as those used for forming the conditioned solvent.

19. The method of claim 1 , wherein the elemental sulfur is obtained from the sulfur-containing production stream.

20. The method of claim 8 , wherein the lean hydrocarbonaceous solvent is a diesel oil or a light cycle oil.

Assignees

• Fluor Tech Corp

Inventors

• Graham Curt
• Jacobs Garry
• Cabrera Jesus
• Aljazzar Ghaith

Classifications

• C01B17/162

  from elemental sulfur and hydrogen · CPC title

• B01D53/1493 Primary

  Selection of liquid materials for use as absorbents · CPC title

• B01D53/1456

  Removing acid components · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• B01D53/1418

  Recovery of products · CPC title