Fluid separation systems and methods

Patent metadata

Field	Value
Publication number	US-9821252-B2
Application number	US-201415105806-A
Country	US
Kind code	B2
Filing date	Dec 16, 2014
Priority date	Jan 31, 2014
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A system including a vessel with at least two fluid inlets and a fluid outlet wherein one fluid inlet is positioned higher in the vessel than the other fluid inlet is provided. The fluid inlets may be connected to a polymerization reactor and each fluid inlet may be configured to deliver fluid to the vessel from a different zone of the polymerization reactor. During shut-down of a polymerization reactor, reaction mixture is discharged to a separation system where polymer particles are removed from the mixture prior to being released into the atmosphere.

First claim

What is claimed is:

1. A system for separating particles from a fluid originating from a reactor comprising:
a reactor having a volume over 3.0 m 3 or capacity over 250 kta; and
a vessel defined about a central vertical axis, the vessel comprising a vessel inner surface, at least two fluid inlets including a first fluid inlet and a second fluid inlet, a fluid outlet, and a reservoir configured to contain a coolant at a variable level;
wherein the first fluid inlet is positioned higher in the vessel than the second fluid inlet and the second fluid inlet is positioned higher in the vessel than the level of coolant contained in the reservoir.

2. The system of claim 1 , wherein the fluid inlets are defined on the vessel inner surface.

3. The system of claim 1 , wherein the first fluid inlet is positioned directly above the second fluid inlet.

4. The system of claim 1 , wherein the first fluid inlet is positioned about 180 degrees about the central vertical axis from the second fluid inlet.

5. The system of claim 1 , wherein the fluid outlet is positioned at the top of the vessel concentric with the central vertical axis.

6. The system of claim 1 , wherein the vessel is substantially cylindrical.

7. The system of claim 1 , wherein the fluid inlets are configured to introduce fluid into the vessel tangentially to the vessel inner surface.

8. The system of claim 1 , wherein the fluid inlets are configured to introduce fluid into the vessel in the same tangential direction about the central vertical axis.

9. The system of claim 1 , wherein the fluid inlets have an internal diameter Di, and the difference in height of the first and second fluid inlets is at least 1.5*Di.

10. The system of claim 1 , wherein the first fluid inlet is configured to deliver a higher mass flux of fluid to the vessel than the second fluid inlet.

11. A polymerization system comprising:
a tubular polymerization reactor; and
a separation system comprising:
a vessel comprising at least two fluid inlets including a first fluid inlet and a second fluid inlet, a fluid outlet, and a reservoir configured to contain a coolant at a variable level, wherein the first fluid inlet is positioned higher in the vessel than the second fluid inlet and the second fluid inlet is positioned higher in the vessel than the level of coolant contained in the reservoir;
wherein the fluid inlets are connected to the polymerization reactor and each fluid inlet is configured to deliver fluid to the vessel from a different zone of the polymerization reactor.

12. The polymerization system of claim 11 , wherein the tubular polymerization reactor has a volume over 3.0 m 3 or capacity over 250 kta and is operable at about 120 to about 310 MPa and about 225 to about 375° C.

13. The polymerization system of claim 11 , wherein the polymerization reactor comprises zones including an upstream end, a downstream end, and a midstream zone located between the upstream end and downstream end;
wherein the first fluid inlet is configured to deliver fluid to the vessel from the midstream zone and the second fluid inlet is configured to deliver fluid to the vessel from the downstream end.

14. The polymerization system of claim 11 , wherein the first fluid inlet is configured to deliver a higher mass flux of fluid to the vessel than the second fluid inlet.

15. A method for separating particles from a reaction mixture during shut-down of a polymerization reactor having a volume over 3.0 m 3 or capacity over 250 kta comprising:
letting down the polymerization reactor by opening one or more valves; and
discharging at least a portion of the reaction mixture from the polymerization reactor to a separation system, wherein the separation system comprises:
a vessel comprising at least two fluid inlets including a first fluid inlet and a second fluid inlet, a fluid outlet, and a reservoir configured to contain a coolant at a variable level, wherein the first fluid inlet is positioned higher in the vessel than the second fluid inlet and the second fluid inlet is positioned higher in the vessel than the level of coolant contained in the reservoir.

16. The method of claim 15 , wherein the polymerization reactor is a high-pressure polymerization reactor.

17. The method of claim 15 , further comprising:
discharging at least a portion of the reaction mixture from a point between an upstream end and a downstream end of the polymerization reactor to the separation system through the first fluid inlet; and
discharging at least a portion of the reaction mixture from the downstream end of the polymerization reactor to the separation system through the second fluid inlet.

18. The method of claim 15 , wherein a higher mass flux of reaction mixture is discharged through first fluid inlet into the vessel than through the second fluid inlet.

19. A system for separating particles from a fluid originating from an autoclave reactor comprising:
a vessel defined about a central vertical axis, the vessel comprising a vessel inner surface, at least two fluid inlets including a first fluid inlet and a second fluid inlet, a fluid outlet, and a reservoir configured to contain a coolant at a variable level;
wherein the first fluid inlet is positioned higher in the vessel than the second fluid inlet and the second fluid inlet is positioned higher in the vessel than the level of coolant contained in the reservoir.

20. The system of claim 19 , wherein the first fluid inlet is positioned directly above the second fluid inlet.

21. The system of claim 19 , wherein the first fluid inlet is positioned about 180 degrees about the central vertical axis from the second fluid inlet.

22. The system of claim 19 , wherein the fluid outlet is positioned at the top of the vessel concentric with the central vertical axis.

23. The system of claim 19 , wherein the vessel is substantially cylindrical and the fluid inlets are configured to introduce fluid into the vessel tangentially to the vessel inner surface in the same tangential direction about the central vertical axis.

24. The system of claim 19 , further comprising a valve and an automatic pressure relief device wherein the valve controls fluid flow through one of the fluid inlets and the automatic pressure relief device controls fluid flow through a different fluid inlet.

25. The system of claim 19 , wherein the fluid inlets have an internal diameter Di, and the difference in height of the first and second fluid inlets is at least 1.5*Di.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lammens Henri A
• Cornelissen Philip H
• Clymans Paul J

Classifications

• B01D21/267 Primary

  by using a cyclone · CPC title

• B01J8/0055 Primary

  using cyclones · CPC title

• B04C5/04

  Tangential inlets · CPC title

• C08F110/02

  Ethene · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title