Method for producing a film having luminescent particles

Patent metadata

Field	Value
Publication number	US-9816027-B2
Application number	US-201214110916-A
Country	US
Kind code	B2
Filing date	Feb 10, 2012
Priority date	Apr 15, 2011
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A method for producing a film having luminescent particles is described. The method has steps a) mixing a thermoplastic and a luminescent pigment containing a hydroxyalkyl terephthalate of the formulate: R 1 —COO—P(OH)x-COO—R 2 and obtaining a thermoplastic mixture; and b) homogenizing the thermoplastic mixture to 150° C. to 200° C. in an extruder, by way of an extrusion nozzle, and obtaining a thermoplastic film.

First claim

The invention claimed is:

1. A method for producing a film having luminescent particles, comprising:
a. mixing a thermoplastic and a luminescent pigment containing a hydroxyalkyl terephthalate of the formula R 1 —COO—P(OH)x-COO—R 2 , thereby obtaining a thermoplastic mixture without a solvent, wherein the thermoplastic mixture contains 0.5 g to 8 g of luminescent pigment per kg of the thermoplastic,
wherein R 1 , R 2 is an alkyl, aryl, or allyl radical having 1 C to 10 C atoms, P is a phenyl ring, OH is a hydroxyl group bound to the phenyl ring, and x is an integer from 1 to 4, and

b. homogenizing the thermoplastic mixture in an extruder at 150° C. to 200° C., and obtaining a thermoplastic film via an extrusion nozzle of the extruder,
wherein the extruder is heated in an extruder intake comprising a first 20% of the length of the extruder screw to a temperature of 135° C. to 150° C., wherein the extruder is heated in an extruder middle to temperature of 150° C. to 170° C.,
wherein the extruder is heated in an extruder discharge comprising a last 20% of the length of the extruder screw to a temperature of 160° C. to 180° C., and
wherein the thermoplastic film is conveyed with an extrusion rate of 10 mm/s to 20 mm/s.

2. The method according to claim 1 , wherein the luminescent pigment contains diethyl 2,5-dihydroxyterephtalate.

3. The method according to claim 1 , wherein the luminescent pigment has an excitation maximum in a range from 380 nm to 420 nm and/or an emission maximum in a range from 430 nm to 500 nm.

4. The method according to claim 1 , wherein the luminescent pigment comprises benzopyranes, naphthopyranes, 2H-naphthopyranes, 3H-naphthopyranes, 2H-phenanthropyranes, 3H-phenanthropyranes, photochromic resins, coumarins, xanthines, naphthalinic acid derivatives, oxazoles, stilbenes, styryls, perylenes, lanthanides, preferably Y 2 O 3 :Eu, YVO 4 :Tm, Y 2 O 2 S:Pr, Gd 2 O 2 S:Tb, and/or mixtures thereof.

5. The method according to claim 1 , wherein the thermoplastic film is conveyed in the extruder via a single extruder screw.

6. The method according to claim 1 , wherein the thermoplastic film is conveyed in a thickness of 0.3 mm to 1 mm.

7. The method according to claim 6 , wherein the thickness is 0.76 mm.

Assignees

• Labrot Michael
• Elmer Monique
• Sablayrolles Jean
• Clabau Frederic
• Sekisui Chemical Co Ltd

Inventors

• Labrot Michael
• Elmer Monique
• Sablayrolles Jean
• Clabau Frederic

Classifications

• G02B27/0101

  characterised by optical features (G02B27/0172 takes precedence) · CPC title

• B32B17/10779

  containing polyester · CPC title

• B29C47/827

  Operations & Transport · mapped topic

• B29C47/786

  Operations & Transport · mapped topic

• C09K9/02

  Organic tenebrescent materials · CPC title