Active energy ray curable composition, ink, inkjet ink, method for producing cured product, apparatus for producing cured product, composition storage container, cured product, and processed product

Patent metadata

Field	Value
Publication number	US-9815993-B2
Application number	US-201615233455-A
Country	US
Kind code	B2
Filing date	Aug 10, 2016
Priority date	Mar 17, 2015
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

An active energy ray curable composition including a polymerizable compound is provided. When a three-layer cured product of the active energy ray composition is obtained by a specific procedure, the three-layer cured product has (1) a stretchability of 1.1 or more and (2) a glass transition temperature of 50° C. or more. The stretchability is defined by a ratio L 2 /L 1 , wherein L 1 represents a first length of the cured product before a tensile test and L 2 represents a second length of the cured product after the tensile test. The tensile test includes stretching the cured product along with the substrate with a tensile tester at a stretching speed of 20 mm/min and a temperature of 180° C.

First claim

What is claimed is:

1. An active energy ray curable composition, comprising a polymerizable compound comprising a polyfunctional reactive compound having at least two polymerizable ethylenic unsaturated double bonds and a combination of at least two monofunctional reactive compounds having one polymerizable ethylenic unsaturated double bond, including a high-Tg monofunctional reactive compound and a low-Tg monofunctional reactive compound,
wherein:
a homopolymer of the high-Tg monofunctional reactive compound has a glass transition temperature of 90° C. or more, and a homopolymer of the low-Tg monofunctional reactive compound has a glass transition temperature of less than 90° C.;
the high-Tg monofunctional reactive compound accounts for 60% by mass or more of the total mass of monofunctional reactive compounds; and
when a three-layer cured product of the active energy ray composition is obtained by:
forming a first film of the active energy ray curable composition having an average thickness of 10 μm on a polycarbonate substrate having a thickness of 100 μm and irradiating the first film with an active energy ray having a light quantity of 1,500 mJ/cm 2 ;
forming a second film of the active energy ray curable composition having an average thickness of 10 μm on the first film and irradiating the second film with an active energy ray having a light quantity of 1,500 mJ/cm 2 ; and
forming a third film of the active energy ray curable composition having an average thickness of 10 μm on the second film and irradiating the third film with an active energy ray having a light quantity of 1,500 mJ/cm 2 ,
the three-layer cured product has:
(1) a stretchability of 1.1 or more, the stretchability being defined by a ratio L 2 /L 1 ;
(2) a glass transition temperature of 50° C. or more,

wherein:
L 1 represents a first length of the cured product before a tensile test;
L 2 represents a second length of the cured product after the tensile test: and
the tensile test includes stretching the cured product along with the substrate with a tensile tester at a stretching speed of 20 min/min and a temperature of 180° C.

2. The active energy ray curable composition of claim 1 , wherein the cured product has a storage elastic modulus of from 0.85 to 10 MPa at 90° C.

3. The active energy ray curable composition of claim 1 , wherein the cured product has a glass transition temperature of 100° C. or more.

4. The active energy ray curable composition of claim 1 , wherein a homopolymer of the high-Tg monofunctional reactive compound has a glass transition temperature of 97° C. or more.

5. The active energy ray curable composition of claim 1 , wherein the high-Tg monofunctional reactive compound accounts for more than 60% by mass of the total monofunctional reactive compounds.

6. The active energy ray curable composition of claim 1 , wherein the a polyfunctional reactive compound has a functional group number of from 2 to 5.

7. The active energy ray curable composition of claim 6 , wherein the polyfunctional reactive compound having at least two polymerizable ethylenic unsaturated double bonds accounts for 5% to 40% by mass of the polymerizable compound.

8. An ink, comprising the active energy ray curable composition of claim 1 .

9. An inkjet ink, comprising the ink of claim 8 .

10. A method for producing a cured product, the method comprising:
discharging the active energy ray curable composition of claim 1 to a surface of a substrate by inkjet recording; and
emitting an active energy ray to the active energy ray curable composition on the surface of the substrate to cause the active energy ray curable composition to cure.

11. An apparatus for producing a cured product, the apparatus comprising:
a container to contain the active energy ray curable composition of claim 1 ;
a discharger to discharge the active energy ray curable composition to a surface of a substrate by inkjet recording; and
a hardener to emit an active energy ray to the active energy ray curable composition on the surface of the substrate to cause the active energy ray curable composition to cure.

12. A composition storage container, comprising:
a container; and
the active energy ray curable composition of claim 1 contained in the container.

13. A cured product, produced by a method comprising curing the active energy ray curable composition of claim 1 .

14. A processed product, produced by a method comprising stretching-processing the cured product of claim 13 .

Assignees

• Kohzuki Shizuka
• Yoshino Mie
• Arita Manabu
• Kobayashi Hiroki
• Ricoh Co Ltd

Inventors

• Kohzuki Shizuka
• Yoshino Mie
• Arita Manabu
• Kobayashi Hiroki

Classifications

• C09D11/30

  Inkjet printing inks · CPC title

• C09D11/101 Primary

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title

• B41J2/01

  Ink jet · CPC title

• C09D11/322

  Pigment inks · CPC title