Process for preparing dispersion powders

Patent metadata

Field	Value
Publication number	US-9815977-B2
Application number	US-201414782875-A
Country	US
Kind code	B2
Filing date	Mar 25, 2014
Priority date	Apr 10, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The invention provides a process for preparing dispersion powders by spray drying of aqueous polymer dispersions of polymers of one or more ethylenically unsaturated monomers selected from the group encompassing vinyl esters, methacrylic esters, acrylic esters, olefins, dienes, vinylaromatics, and vinyl halides with a drying gas in a nozzle atomization dryer, characterized in that the aqueous polymer dispersion (feed), before being atomized, is preheated under pressure to a temperature of 100° C. to 200° C. and is atomized at this temperature, the pressure being set such that the aqueous phase of the polymer dispersion does not boil at the temperature selected.

First claim

The invention claimed is:

1. A process for preparing dispersion powders, comprising:
spray drying an aqueous polymer dispersion feed of one or more polymers of one or more vinyl ester, methacrylic ester, acrylic ester, monoolefin, diene, vinylaromatic, or vinyl halide monomer(s) or comonomer(s), the polymers having a glass transition temperature Tg of from −20° C. to +40° C., with a drying gas in a nozzle atomization dryer, further comprising preheating the aqueous polymer dispersion feed under pressure to a temperature of 100° C. to 200° C. before atomizing, and atomizing at this temperature, the pressure being such that the aqueous phase of the polymer dispersion does not boil at the preheating temperature.

2. The process of claim 1 , wherein the aqueous polymer dispersion feed, before being atomized, is preheated under pressure to a temperature of 100° C. to 150° C.

3. The process of claim 1 , wherein the aqueous polymer dispersion feed, before being atomized, is preheated under pressure to a temperature of 110° C. to 140° C.

4. The process of claim 1 , wherein the aqueous polymer dispersion is atomized in a nozzle atomization dryer by means of one or more single-fluid nozzles, one or more two-fluid nozzles, or one or more multifluid nozzles.

5. The process of claim 2 , wherein the aqueous polymer dispersion is atomized in a nozzle atomization dryer by means of one or more single-fluid nozzles, one or more two-fluid nozzles, or one or more multifluid nozzles.

6. The process of claim 1 , wherein the preheating takes place under pressure on a suction side or a pressure side of a pump which conveys the aqueous polymer dispersion feed to the nozzles.

7. The process of claim 6 , wherein the preheating takes place on the suction side of the pump at a pressure of up to 20 bar abs.

8. The process of claim 6 , wherein the preheating takes place on the pressure side of the pump at a pressure of 10 to 200 bar abs.

9. The process of claim 6 , wherein the drying gas is preheated to an entry temperature of 130° C. to 210° C.

10. The process of claim 1 , wherein the aqueous polymer dispersion spray dried comprises at least one polymer selected from the group consisting of vinyl acetate homopolymers, copolymers of vinyl acetate with ethylene; copolymers of vinyl acetate with ethylene and one or more further vinyl esters; copolymers of vinyl acetate with one or more further vinyl esters; copolymers of vinyl acetate with ethylene and acrylic ester; copolymers of vinyl acetate with ethylene and vinyl chloride; copolymers of vinyl chloride and ethylene and optionally one or more further vinyl esters; copolymers of styrene with acrylic ester; and copolymers of styrene with 1,3-butadiene, the polymers optionally containing 0.1 to 10 wt %, based on the total weight of the polymer, of one or more auxiliary monomers in copolymerized form.

Assignees

• Wacker Chemie Ag

Inventors

• Killat Stefan

Classifications

• B01J2/06

  in a liquid medium · CPC title

• C08J2327/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• B29B9/10

  by moulding the material, i.e. treating it in the molten state · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08J2331/04

  Homopolymers or copolymers of vinyl acetate · CPC title