Epoxy ester compound, cellulose ester resin composition, optical film, and liquid-crystal display device

Patent metadata

Field	Value
Publication number	US-9815973-B2
Application number	US-201515516181-A
Country	US
Kind code	B2
Filing date	Sep 17, 2015
Priority date	Oct 3, 2014
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The present invention has an object to provide a compound which has excellent compatibility even with a cellulose ester resin having a low acetylation degree, is capable of providing an optical film having a high Rth value and high bleed resistance, and can be suitably used as a retardation enhancer; a cellulose ester resin composition including the compound; an optical film including the resin composition; and a liquid-crystal display device including the optical film. The present invention provides an epoxy ester compound represented by the following Formula (1) (in the formula, R 1 to R 4 each independently represent an alkyl group having 1 to 3 carbon atoms; and A's each represent an aromatic group (a1) or an aliphatic group (a2) having 1 to 4 carbon atoms, and the average presence ratio [(a1)/(a2)] of the aromatic groups (a1) to the aliphatic groups (a2) is 99.9/0.1 to 80/20 in terms of a molar ratio).

First claim

The invention claimed is:

1. A mixture of epoxy ester compounds represented by the following Formula (1):

wherein R 1 to R 4 each independently represent an alkyl group having 1 to 3 carbon atoms, A's each represent an aromatic group (a1) or an aliphatic group (a2) having 1 to 4 carbon atoms, and the average presence ratio (a1):(a2) of the aromatic groups (a1) to the aliphatic groups (a2) is from 99.9:0.1 to 80:20 in terms of a molar ratio.

2. The mixture of the epoxy ester compounds according to claim 1 , wherein the aromatic group (a1) is a phenyl group, a para-tolyl group, a meta-tolyl group, or an ortho-tolyl group.

3. The mixture of the epoxy ester compounds according to claim 1 , wherein the aliphatic group (a2) is a methyl group, an ethyl group, or a propyl group.

4. The mixture of the epoxy ester compounds according to claim 1 , wherein the average presence ratio (a1):(a2) of the aromatic groups (a1) to the aliphatic groups (a2) is from 98:2 to 85:15 in terms of a molar ratio.

5. The mixture of the epoxy ester compounds according to claim 1 , wherein R 1 to R 4 are each a methyl group.

6. A cellulose ester resin composition comprising a cellulose ester resin (X) and the mixture of epoxy ester compounds (Y) according to claim 1 .

7. The cellulose ester resin composition according to claim 6 , wherein the mixture of epoxy ester compounds (Y) is included in the proportion of 0.5 to 30 parts by mass with respect to 100 parts by mass of the cellulose ester resin (X).

8. An optical film comprising the cellulose ester resin composition according to claim 6 .

9. A liquid-crystal display device comprising the optical film according to claim 8 .

10. A retardation enhancer which is a mixture of epoxy ester compounds represented by the following Formula (1):

wherein R 1 to R 4 each independently represent an alkyl group having 1 to 3 carbon atoms, A's each represent an aromatic group (a1) or an aliphatic group (a2) having 1 to 4 carbon atoms, and the average presence ratio (a1):(a2) of the aromatic groups (a1) to the aliphatic groups (a2) is from 99.9:0.1 to 80:20 in terms of a molar ratio.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Yoshimura Hiroshi
• Ota Miki
• TAJIRI Yusuke
• Suzuki Osamu

Classifications

• C08K5/12

  of cyclic polycarboxylic acids · CPC title

• C07C69/76 Primary

  Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring · CPC title

• C08L1/12 Primary

  Cellulose acetate · CPC title

• C07C69/21

  of hydroxy compounds with more than three hydroxy groups (esters of sugars C07H) · CPC title

• C07C69/84

  of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring · CPC title