Fluoro-rubber composition and cross-linked rubber article using same

Patent metadata

Field	Value
Publication number	US-9815972-B2
Application number	US-201514642885-A
Country	US
Kind code	B2
Filing date	Mar 10, 2015
Priority date	Nov 29, 2012
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

To provide a fluoro-rubber composition whereby good hardness and good elongation are obtainable in a rubber article after cross-linking, and a cross-linked rubber article using the same.
A fluoro-rubber composition comprising a fluoro-rubber, a hydrophobic silica and a cross-linking agent, wherein the hydrophobic silica is one having hydrophobized with hexamethyldisilazane or silicone oil, and the content of the hydrophobic silica is from 1 to 50 parts by mass and the content of the cross-linking agent is from 0.1 to 5 parts by mass, per 100 parts by mass of the fluoro-rubber; and a cross-linked rubber article obtained by cross-linking such a fluoro-rubber composition.

First claim

What is claimed is:

1. A fluoro-rubber composition comprising:
a fluoro-rubber;
a hydrophobic silica in an amount of from 1 to 50 parts by mass per 100 parts by mass of the fluoro-rubber;
a cross-linking agent which is an organic peroxide, in an amount of from 0.1 to 5 parts by mass per 100 parts by mass of the fluoro-rubber;
a cross-linking assistant selected from the group consisting of triallyl cyanurate, triallyl isocyanurate, triacryl formal, triallyl trimellitate, dipropargyl terephthalate, diallyl phthalate, tetraallyl terephthalamide, triallyl phosphate, trimethallyl isocyanurate, 1,3,5-triacryloylhexahydro-1,3,5-triazin, m-phenylenediamine bismaleimide, p-quinone dioxime, p,p′-dibenzoylquinone dioxine, dipropargyl terephthalate, and N,N′,N″,N′″-tetraallyl terephthalamide in an amount of from 0.1 to 30 parts by mass per 100 parts by mass of the fluoro-rubber; and
carbon black in an amount of from 1 to 50 parts by mass per 100 parts by mass c fluoro-rubber,
wherein the hydrophobic silica is one which is hydrophobized with hexamethyldisilazane and the hydrophobic silica has a specific surface of from 25 to 200 m 2 /g.

2. The fluoro-rubber composition according to claim 1 , wherein the hydrophobic silica has an average primary particle size of from 5 to 50 nm.

3. The fluoro-rubber composition according to claim 1 , wherein the fluoro-rubber is at least one member selected from the group consisting of a vinylidene fluoride/hexafluoropropylene copolymer, a tetrafluoroethylene/propylene copolymer, a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene copolymer and a tetrafluoroethylene/propylene/vinylidene fluoride copolymer.

4. The fluoro-rubber composition according to claim 3 , wherein the fluoro-rubber is a tetrafluoroethylene/propylene copolymer.

5. The fluoro-rubber composition according to claim 1 , wherein the cross-linking assistant is at least one member selected from the group consisting of triallyl cyanurate, triallyl isocyanurate and trimethallyl isocyanurate.

6. A cross-linked rubber article obtained by cross-linking the fluoro-rubber composition as defined in claim 1 .

7. The cross-linked rubber article according to claim 6 , wherein the cross-linked rubber article is a rubber member for oil drilling.

8. The fluoro-rubber composition according to claim 1 , wherein the amount of the cross-linking agent is from 0.5 to 3 parts by mass per 100 parts by mass of the fluoro-rubber.

9. The fluoro-rubber composition according to claim 1 , wherein the amount of the hydrophobic silica is from 10 to 45 parts by mass per 100 parts by mass of the fluoro-rubber.

10. The fluoro-rubber composition according to claim 1 , wherein the amount of the hydrophobic silica is from 20 to 40 parts by mass per 100 parts by mass of the fluoro-rubber.

11. The fluoro-rubber composition according to claim 1 , wherein the hydrophobic silica is a dry silica.

12. The fluoro-rubber composition according to claim 5 , wherein the amount of the cross-linking agent is from 0.5 to 3 parts by mass per 100 parts by mass of the fluoro-rubber.

13. The fluoro-rubber composition according to claim 11 , wherein the hydrophobic silica has an average primary particle size of from 5 to 50 nm.

14. The fluoro-rubber composition according to claim 12 , wherein the hydrophobic silica is a dry silica.

15. The fluoro-rubber composition according to claim 13 , wherein the amount of the hydrophobic silica is from 20 to 40 parts by mass per 100 parts by mass of the fluoro-rubber.

16. The fluoro-rubber composition according to claim 14 , wherein the hydrophobic silica has an average primary particle size of from 5 to 50 nm.

17. The fluoro-rubber composition according to claim 14 , wherein the amount of the hydrophobic silica is from 20 to 40 parts by mass per 100 parts by mass of the fluoro-rubber.

18. The fluoro-rubber composition according to claim 16 , wherein the amount of the hydrophobic silica is from 20 to 40 parts by mass per 100 parts by mass of the fluoro-rubber.

19. The fluoro-rubber composition according to claim 1 , wherein the specific surface area of the hydrophobic silica is from 130 to 185 m 2 /g.

Assignees

• Asahi Glass Co Ltd

Inventors

• Yamada Takeshi
• Iruya Ken

Classifications

• C08K9/06 Primary

  with silicon-containing compounds · CPC title

• C08K5/14

  Peroxides · CPC title

• C09K3/1009

  Fluorinated polymers, e.g. PTFE · CPC title

• C08L83/08

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen · CPC title

• C08K5/3477

  Six-membered rings · CPC title