Long-fibre-reinforced polyamides

Patent metadata

Field	Value
Publication number	US-9815967-B2
Application number	US-201315105011-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 20, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

Disclosed is a polyamide moulding compound suitable for producing moulded articles with improved mechanical properties, the moulding compound including A) at least one amorphous or microcrystalline polyamide, with the proviso that a test piece of polyamide A) has a light transmission according to ASTM D 1003 of at least 80% and a melting heat according to ISO 11357 of <25 J/g, B) 20 to 85% by weight of a long fibre with a round cross-section and C) 0 to 10% by weight of at least one additive, components A) to C) adding up to 100% by weight. Also disclosed is a process for producing moulded bar granulates containing the moulding compound.

First claim

The invention claimed is:

1. A polyamide moulding compound comprising:
A) at least one amorphous or microcrystalline polyamide, with the proviso that a test piece of polyamide A) has a light transmission according to ASTM D 1003 of at least 80% and a melting heat according to ISO 11357 of <25 J/g,
B) an endless fibre with a round cross-section and
C) 0 to 10% by weight of at least one additive,
components A) to C) adding up to 100% by weight;
wherein up to 27% by weight of polyamide A), relative to the total moulding compound, is replaced by an aliphatic polyamide A1), polyamides A and A1) being compatible and the weight ratio of polyamide A) to polyamide A1) being 5:1 to 3.5:1, and the light transmission of a test piece of 2 mm thickness of a compound of A) and A1) being at least 80%,
wherein the at least one amorphous or microcrystalline polyamide A) is PA MACM12 and the aliphatic polyamide A1) is PA12, and
wherein the endless fibre is present in an amount of 50-60% by weight relative to the total polyamide moulding compound.

2. The polyamide moulding compound according to claim 1 , wherein polyamide A) has a melting heat according to ISO 11357 of at most 12 J/g, and a test piece of 2 mm thickness of polyamide A) displays a light transmission according to ASTM D 1003 of at least 80%.

3. The polyamide moulding compound according to claim 1 , wherein the relative viscosity of polyamide A) or A1) is 1.35 to 2.15, measured with 0.5 g in 100 ml m-cresol at 20° C.

4. The polyamide moulding compound according to claim 1 , wherein at least one of the polyamides A) and A1) is amine-terminated.

5. The polyamide moulding compound according to claim 1 , wherein the endless fibre is a glass fibre and/or carbon fibre.

6. The polyamide moulding compound according to claim 1 , wherein the at least one additive or additives C) are contained in a weight proportion of 0.01 to 10% by weight, relative to the total polyamide moulding compound.

7. The polyamide moulding compound according to claim 1 , wherein the at least one additive is selected from inorganic stabilisers, organic stabilisers, lubricants, colorant and marking materials, inorganic pigments, organic pigments, antistatic agents, crystallisation retardants, condensation catalysts, chain regulators, defoamers, chain-lengthening additives, graphite, carbon nanotubes, mould-release agents, optical brighteners, photochromic additives, plasticising agents, metallic pigments, metal flakes, metal-coated particles, and filling and reinforcing materials.

8. The polyamide moulding compound according to claim 7 , wherein the filling and reinforcing materials are nanoscale filling and reinforcing materials, minerals with a particle size of at most 100 nm, or unmodified or modified, natural or synthetic phyllosilicates.

9. The polyamide moulding compound according to claim 1 , which does not include any flame-retardant.

10. The polyamide moulding compound according to claim 1 , which is an endless fibre-reinforced bar granulate.

11. The polyamide moulding compound according to claim 10 , wherein the granulate length is 3 to 25 mm.

12. A method for the production of an endless fibre-reinforced bar granulate comprising subjecting a polyamide moulding compound to a pultrusion process, the polyamide moulding compound comprising:
A) at least one amorphous or microcrystalline polyamide, with the proviso that a test piece of polyamide A) has a light transmission according to ASTM D 1003 of at least 80% and a melting heat according to ISO 11357 of <25 J/g,
B) an endless fibre with a round cross-section and
C) 0 to 10% by weight of at least one additive,
the components A) to C) adding up to 100% by weight;
wherein up to 27% by weight of polyamide A), relative to the total moulding compound, is replaced by an aliphatic polyamide A1), polyamides A) and A1) being compatible and the weight ratio of polyamides A) to polyamide A1) being 5:1 to 3.5:1, and the light transmission of a test piece of 2 mm thickness of a compound of A) and A1) being at least 80%;
wherein the at least one amorphous or microcrystalline polyamide A) is PA MACM12 and the aliphatic polyamide A1) is PA12, and
wherein the endless fibre is present in an amount of 50-60% by weight relative to the total polyamide moulding compound.

Assignees

• Ems Patent Ag

Inventors

• Harder Philipp
• Pfleghar Mark

Classifications

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08K7/14 Primary

  Glass · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08J5/042

  with carbon fibres · CPC title