Process for producing modified poly(propene), the modified poly(propene) and the use thereof, and the polymer blend

Patent metadata

Field	Value
Publication number	US-9815951-B2
Application number	US-201414913620-A
Country	US
Kind code	B2
Filing date	Aug 25, 2014
Priority date	Aug 23, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The present application refers to a process for the modification of polypropylene, wherein amount, size and configuration of the branches are controlled, the process comprising the steps of (A) preparing a bis(sulphonazide) (BSA) masterbatch by dispersing BSA in polyolefin; (B) adding (i) at least one fatty acid salt with metal cation having valence of 1 + to 3 + ; and (ii) the BSA masterbatch prepared in step (A) to the polypropylene to be modified. Said modified polypropylene of the present invention possesses properties suitable for use in foaming, blowing, thermoforming, recoating, film extrusion, BOPP, spinning processes and other processes and applications, and it is also suitable to be in contact with food products.

First claim

What is claimed is:

1. A process for the production of a modified polypropylene, characterized in that it comprises:
(A) preparing a bis(sulfonazide) (BSA) masterbatch by dispersing BSA in polypropylene; and
(B) adding (i) at least one fatty acid salt with a metal cation of valence 1 + to 3 + , and (ii) the BSA masterbatch prepared in step (A) in the polypropylene to be modified;
wherein steps (A) and (B) are carried out by extrusion.

2. The process in accordance with claim 1 , wherein the extruder screw is selected from a single, double or planetary screw, interpenetrating or non-interpenetrating and counter-rotating or co-rotating screw.

3. The process in accordance with claim 2 , characterized in that in step (A) the screw L/D is higher than 20 and in step (B) the extruder is selected from an industrial extruder having a diameter higher than 250 mm and L/D higher than 10, or the compounding extruder with a diameter of 20 to 250 mm and L/D higher than 25.

4. The process in accordance with claim 1 , characterized in that the residence time of step (A) is lower than 40 s and residence time of step (B) is lower than 30 s.

5. The process in accordance with claim 1 , characterized in that the extrusion temperature of step (A) is lower than 190° C., and the extrusion temperature of step (B) is lower than 270° C.

6. The process in accordance with claim 1 , characterized in that steps (A) and (B) occur integrally or independently.

7. The process in accordance with claim 1 , characterized in that BSA is selected from the group consisting of sulphonyl azides, poly(sulfonyl azides), phosphazene azides, poly(phosphazene azides), silyl azides, poly(silyl azides), formyl azides, poly(formyl azides), azides, poly(azides), N-chlorosulfonamides salts, N,N-dichlorosulfonamides, inner salts of 2-trialkyl-1-sulfonylhydrazides, diazo alkanes, poly(diazo alkanes), geminally-substituted methylene groups, ketenes, metallocarbenes, and mixtures thereof.

8. The process in accordance with claim 1 , characterized in that BSA is 4,4′-diphenyl ether bis(sulphonazide).

9. The process in accordance with claim 1 , characterized in that BSA is in a liquid, suspension and solid form, in physical mixtures with polymers and/or in molecular melt form.

10. The process in accordance with claim 1 , characterized in that in step (A) the amount of BSA in the masterbatch is lower than 7.5%.

11. The process in accordance with claim 1 , characterized in that the amount of molecular melt in the masterbatch is between 5% and 35% in the masterbatch composition.

12. The process in accordance with claim 1 , characterized in that the amount of BSA in the modified polypropylene ranges from 200 to 2000 ppm.

13. The process in accordance with claim 1 , characterized in that the polypropylene of step (A) is a polypropylene selected from the group consisting of homopolymers, copolymers, heterophasic copolymer/homopolymer matric (HECO) of random propylene/alpha-olefin heterophasic copolymer matrix (RAHECO) and/or random copolymer (RACO) comprising propylene/ethylene and/or α-olefin containing from 4 to 10 carbon atoms.

14. The process in accordance with claim 13 , characterized in that IF of the polypropylene ranges from 1 to 300 g/min.

15. The process in accordance with claim 1 , characterized in that the polypropylene to be modified in step B is selected from the group consisting of homopolymers, copolymers, heterophasic copolymer/homopolymer matric (HECO) of random propylene/alpha-olefin heterophasic copolymer matrix (RAHECO) and/or random copolymer (RACO) comprising propylene/ethylene and/or α-olefin containing from 4 to 10 carbon atoms.

16. The process in accordance with claim 15 , characterized in that IF of the polypropylene to be modified ranges from 1 to 300 g/min.

17. The process in accordance with claim 1 , characterized in that the polypropylene to be modified is step B is in the form of a pellet, spheres, powder and/or mixtures thereof.

18. The process in accordance with claim 1 , characterized in that additives selected from the group consisting of nucleants, flame retardants, pigments, anti-UV agents, COF controllers, mold-release agents, IR-absorption agents, demolding auxiliaries, anti-static agents, and mixtures thereof are optionally added in steps (A) and/or (B).

19. The process in accordance with claim 1 , characterized in that antioxidants selected from the group consisting of phenolic antioxidants, phosphates, phosphites, and mixtures thereof are optionally added in steps (A) and/or (B).

20. The process in accordance with claim 1 , characterized in that compatibilizers or fatty acid salts with metal cations having valence of 1 + to 3 + are optionally added in step (A).

21. The process in accordance with claim 1 , characterized in that the fatty acid salts are stearates and the metal cation is selected from Ca, Zn, Mg, Na, Li and Ba.

22. The process in accordance with claim 1 , characterized in that in step (B) the fatty acid salts are added in an amount ranging from 200 to 6000 ppm based on the total mass of modified polypropylene.

23. The process in accordance with claim 1 , characterized in that the masterbatch has a reduction of domains of BSA and/or molecular melt for median values lower than 50 mm.

24. Modified polypropylene produced by the process as defined in claim 1 , characterized in that it has g′ lower than 1, B n greater than 0.1 and IF lower than 100 g/10 min.

25. Modified polypropylene, in accordance with claim 24 , characterized in that it has g′ superior to 0.55 and B n lower than 4 atoms per 1000 carbon atoms.

26. Modified polypropylene, in accordance with claim 24 , characterized in that it has a melt strength higher than 30 cN, extensibility higher than 11 cm/s, activation energy lower than 120 kJ/mol, g′ lower than 0.75, B n higher than 2 carbon atoms per every 1000 atoms and IF between 2 and 6 g/10 min.

27. Modified polypropylene, in accordance with claim 24 , characterized in that it has an amount of residues lower than 6 ppm.

28. Use of the modified polypropylene, as defined in claim 24 , characterized in that it is for application in foaming, thermoforming, injection, blown films, flat films, BOPP, injection, fibers, raffia, recoating, and blowing.

29. Polymer blend comprising the modified polypropylene, as defined in claim 24 , characterized in that it comprises at least one polymer selected from linear PP homopolymer, random and heterophasic copolymers, HDPE, LDPE, LLDPE, EVA, copolymer of ethene/octene, ethene/butane, ethene hexene, EPR thermoplastic rubbers, and mixtures thereof.

30. Polymer blend, in accordance with claim 29 , characterized in that the modified polypropylene is present in amounts ranging from 5% to 95%.

Assignees

• Braskem Sa

Inventors

• De Azeredo Ana Paula
• Farah Marcelo

Classifications

• C08K5/43 Primary

  Compounds containing sulfur bound to nitrogen · CPC title

• C08L23/12

  Polypropene · CPC title

• C08F8/00

  Chemical modification by after-treatment (graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C) · CPC title

• C08L2310/00

  Masterbatches · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title