Curing method for polyether

Patent metadata

Field	Value
Publication number	US-9815933-B2
Application number	US-201615096365-A
Country	US
Kind code	B2
Filing date	Apr 12, 2016
Priority date	May 23, 2008
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

This invention relates to a novel curing method of oligomers, using metal triflates, and particularly to the curing of hydroxyl terminated elastomers to achieve crosslinked polymers. The method finds particular use as an alternative cure methodology to replace isocyanate curing. There is further provided a cured and crosslinked polymer binder, which is particularly suitable and compatible for use with energetic materials.

First claim

The invention claimed is:

1. A method of making a durable isocyanate-free paint comprising the steps of:
forming an admixture of at least one hydroxy terminated oligomer, at least one epoxy terminated oligomer and at least one metal trifluoromethanesulfonate salt catalyst, wherein the admixture does not react with water, and wherein the admixture is formed in a substantial absence of solvent; and
curing the resultant admixture at 30 to 85° C. substantially in the absence of a solvent to form a layer of the isocyanate-free paint,
wherein the at least one hydroxy terminated oligomer is of formula (i)

wherein A is a monomer repeat unit, m is the average number of monomer repeat units in the range of from 5 to 100, x is in the range of from 2 to 20, and the at least one epoxy terminated oligomer is of formula (ii)

wherein B is a monomer repeat unit, n is the average number of monomer repeat units in the range of from 5 to 100, and y is in the range of from 2 to 20; and
wherein at least one of the epoxy or hydroxy terminated oligomer comprises 5% to 10% w/w of an oligomer which has greater than 2 functional groups selected from the group consisting of hydroxyl and epoxy functional groups, so as to promote crosslinking in the final crosslinked polymer
and wherein A and B are independently selected from monomer repeat units comprising hydrocarbyl, esters, carbonates, ethers, amides, aromatics, heterocyclic or copolymers comprising mixtures thereof,
wherein the admixture further comprises at least one filler material, and
wherein the at least one filler material is an energetic material.

2. A method according to claim 1 , wherein at least one of the at least one hydroxy terminated oligomer and the at least one epoxy terminated oligomer comprises 5 to 10% w/w of an oligomer which has 3 to 5 functional groups selected from the group consisting of hydroxyl and epoxy functional groups.

3. A method according to claim 1 , wherein the admixture comprises a further epoxy terminated oligomer, which contains an average of 2.5 to 4 epoxy groups per oligomer chain, and is present in the range of from 5-10% w/w.

4. A method according to claim 1 wherein the metal of the at least one metal catalyst is a lanthanide or group III metal.

5. A method according to claim 4 wherein the metal of the at least one metal catalyst is scandium or yttrium.

6. A method according to claim 1 , wherein the curing step is carried out in the temperature range of from 40 to 85° C.

7. A method according to claim 6 , wherein the curing step is carried out in the temperature range of from 40 to 60° C.

8. A method according to claim 1 wherein the catalyst is present in an amount of from 0.01% to 2% by mass of the admixturer.

9. A method according to claim 1 comprising uniformly dispersing the energetic material in said admixture.

10. A method according to claim 1 , wherein the energetic material comprises ammonium dinitramide.

Assignees

• Qinetiq Ltd

Inventors

• Torry Simon Andrew
• Cunliffe Anthony Vernon
• Tod David Arthur

Classifications

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C08L2666/22

  Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20 · CPC title

• C08G59/688

  containing phosphorus · CPC title

• C08G59/24 Primary

  carbocyclic · CPC title

• C08G59/245 Primary

  aromatic · CPC title