Configurations and method of integrating a gas to liquids (GTL) plant in a refinery

Patent metadata

Field	Value
Publication number	US-9815692-B2
Application number	US-201514811745-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	Jul 28, 2014
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A crude oil processing plant that comprises a Fischer-Tropsch reactor is disclosed. The crude oil processing plant comprises a crude oil processing section and a hydrogen production section. The hydrogen production section is coupled to a hydrocracker in the crude oil processing section to deliver a high purity hydrogen stream. The Fischer-Tropsch reactor receives a syngas stream from the hydrogen production section and produces a hydrocarbon stream. When light crude oil is processed, the hydrocracker typically has excess capacities to upgrade the hydrocarbon stream from the Fischer-Tropsch reactor.

First claim

What is claimed is:

1. A crude oil processing plant having a crude oil processing section and a hydrogen production section, wherein the crude oil processing section includes a distillation unit and a hydrocracker, wherein the hydrogen production section includes a steam methane reformer and a shift reactor, and wherein the hydrogen production section is coupled to the hydrocracker to deliver a high purity hydrogen stream, the plant comprising:
a Fischer-Tropsch reactor coupled to the steam methane reformer, and the hydrocracker, wherein the Fischer-Tropsch reactor is configured to receive a first portion of a steam methane reformer product stream and produce (i) a hydrocarbon stream to deliver to the hydrocracker and (ii) a tail gas stream to deliver to at least one of the shift reactor and the steam methane reformer; and
a saturator that is configured to receive a water stream from the Fischer-Tropsch reactor, a carbon dioxide stream, and a first portion of a feed gas to produce a mixed gas stream.

2. The plant of claim 1 , wherein the hydrocracker is configured to receive the hydrocarbon stream, the high purity hydrogen stream, and a fractionated crude oil from the distillation unit to produce a mixture of a naphtha, jet fuel, and a diesel product.

3. The plant of claim 2 , wherein the hydrocracker is configured to produce the diesel product having a cetane number of at least 45.

4. The plant of claim 2 , wherein the distillation column is configured to receive a light crude oil to produce the fractionated crude oil.

5. The plant of claim 1 , wherein the steam methane reformer is configured to receive a second portion of the feed gas and the mixed stream to produce the steam methane reformer product stream.

6. The plant of claim 1 , wherein the hydrogen production section comprises a carbon dioxide removal unit that is configured to receive a shift reactor product stream to produce the carbon dioxide stream and a carbon dioxide removal unit product stream, and wherein the steam methane reformer receives the tail gas.

7. The plant of claim 6 , wherein the hydrogen production section comprises a methanation reactor configured to receive the carbon dioxide removal unit product stream to produce the high purity hydrogen stream.

8. The plant of claim 1 , wherein the hydrogen production section comprises a pressure swing adsorption unit that is configured to receive a shift reactor product stream from the shift reactor to produce the carbon dioxide stream and the high purity hydrogen stream, and wherein the shift reactor receives the tail gas.

9. The plant of claim 1 , wherein the feed gas is at least one of natural gas stream and a refinery gas stream.

10. A method of processing crude oil in a crude oil processing plant having a crude oil processing section and a hydrogen production section, wherein the crude oil processing section includes a distillation unit and a hydrocracker, wherein the hydrogen production section includes a steam thane reformer and a shift reactor, and wherein the hydrogen production section is coupled to the hydrocracker to deliver a high purity hydrogen stream, the method comprising:
fluidly coupling a Fischer-Tropsch reactor to the steam methane reformer, the shift reactor, and the hydrocracker;
feeding a first portion of a steam methane reformer product stream to the Fischer-Tropsch reactor to generate a hydrocarbon stream and a tail gas stream;
feeding the hydrocarbon stream to the hydrocracker, and the tail gas stream to at least one of the shift reactor and the steam methane reformer; and
combining a water stream from the Fischer-Tropsch reactor, a carbon dioxide stream, and a first portion of a feed gas in a saturator to produce a mixed gas stream.

11. The method of claim 10 , further comprising generating a mixture of a naphtha, jet fuel, and a diesel product via the hydrocracker, wherein the hydrocracker receives the hydrocarbon stream, the high purity hydrogen stream, and a fractionated crude oil from the distillation unit.

12. The method of claim 11 , wherein feeding the hydrocarbon stream to the hydrocracker comprises providing a Fischer-Tropsch wax in an amount effective to enhance a cetane number of the diesel product.

13. The method of claim 10 , further comprising feeding the mixed gas stream and a second portion of a feed gas to the steam methane reformer to produce the steam methane reformer product gas, wherein the mixed gas stream is fed in an amount effective to reduce a steam requirement for the steam methane reformer.

14. The method of claim 10 , further comprising removing carbon dioxide from a shift reactor product stream in a carbon dioxide removal unit to produce the carbon dioxide stream and a carbon dioxide removal product stream, and feeding the carbon dioxide removal product stream to a methanation reactor to produce the high purity hydrogen stream, and wherein the tail gas is fed to the steam methane reformer.

15. The method of claim 10 , further comprising removing carbon dioxide from a shift reactor product stream in a pressure swing adsorption unit to produce the carbon dioxide stream and the high purity hydrogen stream, and wherein the tail gas is fed to the shift reactor.

16. A method of retrofitting a heavy crude oil processing plant having a crude oil processing section and a hydrogen production section, wherein the crude oil processing section includes a distillation unit and a hydrocracker, wherein the hydrogen production section includes a steam methane reformer and a shift reactor, and wherein the hydrogen production section is coupled to the hydrocracker to deliver a high purity hydrogen stream, the method comprising:
fluidly coupling a Fischer-Tropsch reactor to the steam methane reformer and the hydrocracker, wherein the Fischer-Tropsch reactor receives a first portion of a syngas stream to generate a hydrocarbon stream that is fed to the hydrocracker; and
fluidly coupling a saturator to the Fischer-Tropsch reactor, a carbon dioxide source, a feed gas source, and the steam methane reformer, wherein the saturator receives a carbon dioxide stream from the carbon dioxide source, a water stream from the Fischer-Tropsch reactor, and a portion of a feed gas from the feed gas source to produce a mixed gas stream that is fed to the steam methane reformer.

17. The method of claim 16 , wherein the steam methane reformer receives the mixed gas stream and a second portion of the feed gas to produce the syngas stream, and a second portion of the syngas stream is fed to the shift reactor.

Assignees

• Fluor Tech Corp

Inventors

• Ravikumar Ravi
• Koppel Paul E
• Dabee Sanjiv
• Zychowicz Johnathon

Classifications

• C10G47/00 Primary

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title

• C01B2203/0216

  containing a non-catalytic steam reforming step · CPC title

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title

• C10G2/32

  with the use of catalysts · CPC title

• C10G2400/02

  Gasoline · CPC title