Method for joining substrates

Patent metadata

Field	Value
Publication number	US-9815262-B2
Application number	US-201214000745-A
Country	US
Kind code	B2
Filing date	Feb 21, 2012
Priority date	Feb 22, 2011
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The invention relates to a method of joining substrates. It is the object of the invention in this respect to join substrates of substrate materials together without having to exert an increased effort for a coating with additional coating processes to be carried out and to be able to achieve a good quality of the join connection in so doing. In the method in accordance with the invention a pretreatment of at least one join surface of a substrate to be joined is carried out in low pressure oxygen plasma prior to the actual joining. On the joining, a contact force acts on the substrates to be joined in the range 2 kPa to 5 MPa and in this process a heat treatment is carried out at an elevated temperature of at least 100° C. and at under pressure conditions of a maximum of 10 mbar, preferably <10 −3 mbar.

First claim

The invention claimed is:

1. A method of joining substrates comprising:
applying a pressing force in the range of 2 kPa to 5 MPa on substrates to be joined;
heat treating the substrates at an elevated temperature of at least 100° C. and under pressure conditions of a maximum of 10 mbar;
pretreating at least one joining surface of at least a first of the substrates to be joined prior to the applying of the pressure and the heat treating; and
smoothing at least a portion of the joining surface of the first of the substrates prior to the applying of the pressure and the heat treating such that, after the smoothing, at least the portion of the joining surface has a planarity or a deviation with a specified peak to valley value,
wherein the specified peak to valley value is less than 1 μm per 100 mm of diameter of the portion of the joining surface if a thickness of the first of the substrates is greater than 5 mm, and wherein the specified peak to valley value is less than 10 μm per 100 mm of diameter of the portion of the joining surface if the thickness of the first of the substrates is less than 5 mm, and wherein the pressing force and the heat treating joins the substrates.

2. The method in accordance with claim 1 , wherein the substrates comprise a glass that is predominantly at least one of SiO 2 , a glass ceramic, a crystalline material with a high oxide portion, aluminum oxide, SiC, SiSiC, ZnSe, Si, Ge, and GaAs.

3. The method in accordance with claim 1 , further comprising:
cleaning the joining surface by alternate rinsing with aqueous NH 4 OH solution and H 2 O 2 solution, each of the NH 4 OH solution and the H 2 O 2 solution having a respective concentration in the range of 2 mass % to 4 mass %, subsequent to the cleaning, rinsing the joining surface in distilled or deionized water while simultaneously exposing the substrates to be joined to sound waves in the megahertz range, and
subsequent to the rinsing, drying the substrates.

4. The method in accordance with claim 1 , wherein the pretreating comprises applying a low pressure oxygen plasma to at least the portion of the joining surface.

5. The method in accordance with claim 4 , wherein the low pressure oxygen plasma has a power density in the range 0.5 W/cm 2 to 10 W/cm 2 .

6. The method in accordance with claim 4 , further comprising, subsequent to the applying of the low pressure oxygen plasma, rinsing the joining surface in distilled or deionized water while simultaneously exposing the substrates to sound waves in the megahertz range and
subsequent to the rinsing, drying the joining surface.

7. The method in accordance with claim 1 , further comprising forming a surface layer of a metal, a semiconductor, or a dielectric material on at least the portion of the joining surface prior to the applying of the pressure and the heat treating.

8. The method in accordance with claim 7 , further comprising forming an alternating multilayer system having individual layers of materials having a different index of refraction.

9. The method in accordance with claim 7 , further comprising forming at least one layer of a non-stoichiometric oxide on at least one of the substrates.

10. The method in accordance with claim 1 , wherein the heat treating is carried out under pressure conditions less than 10 −3 mbar.

11. The method in accordance with claim 2 , wherein the glass comprises at least one of yttrium vanadate, yttrium aluminum garnet, and sapphire.

12. The method in accordance with claim 1 , wherein, after the smoothing, the specified peak to valley value is better than 40 μm per 100 mm of diameter of the portion of the joining surface if the thickness of the first of the substrates is less than 1 mm.

13. The method in accordance with claim 1 , wherein, after the smoothing, at least the portion of the joining surface has a surface roughness of less than 3 nm root mean square.

14. The method in accordance with claim 1 , wherein, after the smoothing, at least the portion of the joining surface has a surface roughness of less than 1 nm root mean square.

15. A method of joining substrates comprising:
providing or receiving a plurality of substrates to be joined, the substrates comprising a glass comprising at least one of SiO 2 , a glass ceramic, a crystalline material with a high oxide portion, an aluminum oxide, SiC, SiSiC, ZnSe, Si, Ge, and GaAs;
smoothing at least a portion of a joining surface of a first of the plurality of the substrates such that, after the smoothing, at least the portion of the joining surface has a surface roughness less than 1 nm root mean square, and, after the smoothing, at least the portion of the joining surface has a planarity or a deviation with a specified peak to valley value,
wherein the specified peak to valley value is less than 1 μm per 100 mm of diameter of the portion of the joining surface if a thickness of the first of the plurality of the substrates is greater than 5 mm, and the specified peak to valley value is less than 10 pm of per 100 mm of diameter of the portion of the joining surface if the thickness of the first of the plurality of the substrates is less than 5 mm; forming a surface layer of metal, a semiconductor, or a dielectric material on at least the portion of the joining surface; cleaning the joining surface by alternate rinsing with aqueous NH 4 OH solution and H 2 O 2 solution, each of the NH 4 OH solution and the H 2 O 2 solution having a respective concentration in the range of 2 mass % to 4 mass %

subsequent to the cleaning, rinsing the joining surface with distilled or deionized water while simultaneously exposing the plurality of the substrates to sound waves in the megahertz range;
subsequent to the rinsing, drying the joining surface;
subsequent to the drying, plasma-treating at least the portion of the joining surface with low pressure oxygen plasma having a power density in the range 0.5 W/cm 2 to 10 W/cm 2 ;
subsequent to the plasma-treating, applying a pressing force in the range of 2 kPa to 5 MPa on the plurality of the substrates; and
heat treating the plurality of the substrates at an elevated temperature of at least 100° C. and under pressure conditions of less than 10 −3 mbar while applying the pressing force on the plurality of the substrates, wherein the pressing force and the heat treating joining the plurality of substrates.

16. The method in accordance with claim 4 , wherein the low pressure oxygen plasma is applied over a time period of at least 60 seconds.

17. The method in accordance with claim 16 , wherein the applying of the low pressure oxygen plasma comprises multiple successive plasma action over the time period.

18. The method in accordance with claim 16 , wherein the applying of the low pressure oxygen plasma comprises a continuous process over the time period.

19. The method in accordance with claim 2 , wherein the crystalline material with the high oxide portion comprises at least one of a vanadate, a garnet, KTiOPO 4 , LiB 3 O 5 , or LiNbO 3 .

20. The method in accordance with claim 15 , wherein the crystalline material with the high oxide portion comprises at least one of a vanadate, a garnet, KTiOPO 4 , LiB 3 O 5 , or LiNbO 3 .

Assignees

• Kalkowski Gerhard
• Rothhardt Carolin
• Rohde Mathias
• Eberhardt Ramona
• Fraunhofer Ges Forschung
• Friedrich-Schiller-Universität Jena

Inventors

• Kalkowski Gerhard
• Rothhardt Carolin
• Rohde Mathias
• Eberhardt Ramona

Classifications

• H10P90/1914

  using bonding · CPC title

• C04B2237/06

  Oxidic interlayers · CPC title

• C04B2237/36

  Non-oxidic · CPC title

• C03B23/20

  Uniting glass pieces by fusing without substantial reshaping · CPC title

• C03C27/06

  Joining glass to glass by processes other than fusing (fusing C03B23/20; units for use as elements for closing wall or like openings and comprising two or more parallel glass panes in spaced relationship, the panes being permanently secured together E06B3/66) · CPC title