Selectivity of ionic liquid alkylation

Patent metadata

Field	Value
Publication number	US-9815049-B2
Application number	US-201615331702-A
Country	US
Kind code	B2
Filing date	Oct 21, 2016
Priority date	Nov 10, 2015
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A method of controlling a hydrocarbon conversion process is described. The method involves introducing a reactant into a reaction zone containing an ionic liquid catalyst. The reaction zone has at least two zones. The mass transfer resistance in the second zone is greater than the mass transfer resistance in the first zone.

First claim

What is claimed is:

1. A method of minimizing secondary reactions producing undesired products in an alkylation reaction of a paraffin and an olefin comprising:
introducing a paraffin having 3 to 8 carbon atoms and an olefin having 2 to 8 carbon atoms into an alkylation reactor containing an ionic liquid catalyst comprising ionic liquid droplets to alkylate the paraffin with the olefin to produce an alkylated product, the reaction reactor having at least two reaction zones with the second reaction zone down-stream from the first reaction zone, the first reaction zone having a first mass transfer resistance in the ionic liquid droplets and the second reaction zone having a second mass transfer resistance in the ionic liquid droplets greater than the first mass transfer resistance, wherein the second mass transfer resistance is greater than the first mass transfer resistance by changing the first mass transfer resistance, the second mass transfer resistance, or both; wherein the first mass transfer resistance, the second mass transfer resistance, or both are changed by at least one of:
by changing a size of droplets of the ionic liquid catalyst;
by changing a viscosity of the ionic liquid catalyst; and
by adjusting fresh/regenerated ionic liquid catalyst to reaction zones.

2. The method of claim 1 wherein the first mass transfer resistance, the second mass transfer resistance, or both are changed by changing a size of droplets of the ionic liquid in the second zone compared to a size of droplets of the ionic liquid catalyst in the first zone.

3. The method of claim 2 wherein the size of the droplets of ionic liquid in the second zone is changed by increasing a shear rate of the first zone, decreasing a shear rate of the second zone, or both.

4. The method of claim 2 wherein the size of the droplets of the ionic liquid in the second zone is greater than the size of the droplets in the second zone.

5. The method of claim 2 wherein the size of the droplets of the ionic liquid is changed using a static mixer designed to increase the size of the droplets of the ionic liquid in the second zone compared to the size of the droplets of the ionic liquid in the first zone.

6. The method of claim 1 wherein the first mass transfer resistance, the second mass transfer resistance, or both are changed by changing a viscosity of the ionic liquid catalyst under reactor operating conditions in the first zone, the second zone, or both.

7. The method of claim 6 wherein the viscosity of the ionic liquid catalyst under reactor operating conditions in the first zone, the second zone, or both is changed by operating the first zone at a higher temperature than the second zone.

8. The method of claim 6 wherein the viscosity of the ionic liquid catalyst under reactor operating conditions in the first zone, the second zone, or both is changed by using an ionic liquid having a higher viscosity in the second zone.

9. The method of claim 6 wherein the viscosity of the ionic liquid catalyst under reactor operating conditions in the first zone, the second zone, or both is changed by adding a viscosity reducing additive to the ionic liquid catalyst in the first zone, adding a viscosity increasing additive to the ionic liquid in the second zone, or both.

10. The method of claim 6 wherein the viscosity of the ionic liquid under reactor operating conditions in the second zone is greater than the viscosity of the ionic liquid under reactor operating conditions in the first zone.

11. The method of claim 1 wherein the reaction zone comprises at least two reactors, and wherein the first reactor comprises the first zone, and the second reactor comprises the second zone.

12. The method of claim 11 wherein the reaction zone comprises at least two continuous stirred tank reactors or at least two plug flow reactors.

13. The method of claim 11 wherein the first mass transfer resistance is changed by adding fresh ionic liquid catalyst or regenerated ionic liquid catalyst to the first zone, or the second mass transfer resistance is changed by recycling spent ionic liquid catalyst to the second reactor, or both.

14. The method of claim 1 wherein the second mass transfer resistance is changed by increasing an amount of ionic liquid catalyst in the second zone compared to an amount of ionic liquid catalyst in the first zone.

Assignees

• Uop Llc

Inventors

• Lafyatis David S
• Mueller Sean G
• Xu Zhanping
• Nafis Douglas A
• Mehlberg Robert
• Detrick Kurt
• Buchbinder Avram M

Classifications

• C07C2/26

  with hydrides or organic compounds (C07C2/20 takes precedence) · CPC title

• B01J2231/20

  Olefin oligomerisation or telomerisation · CPC title

• C07C2/58 Primary

  Catalytic processes · CPC title

• C07C5/2727

  with hydrides or organic compounds (C07C5/2718 takes precedence) · CPC title

• B01J31/0284

  of an aromatic ring, e.g. pyridinium · CPC title