Storing method of activated catalysts for Fischer-Tropsch synthesis

Patent metadata

Field	Value
Publication number	US-9815046-B2
Application number	US-201414392244-A
Country	US
Kind code	B2
Filing date	Nov 26, 2014
Priority date	Nov 28, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The present invention relates to a method for producing the activated catalyst for Fischer-Tropsch synthesis comprising: a first step of reducing a catalyst for Fischer-Tropsch synthesis; a second step of preparing liquid hydrocarbon in which a part or all of molecular oxygen is eliminated; and a third step of introducing the reduced catalyst prepared in the first step into the liquid hydrocarbon prepared in the second step while blocking its contact with air. Since the reduced catalyst used for Fischer-Tropsch synthesis is introduced into liquid hydrocarbon from which molecular oxygen is removed or coated by liquid hydrocarbon, the catalyst for Fischer-Tropsch synthesis activated based on the present invention maintains a high activity even if exposed to the air for a long time, thereby easily facilitating the long-term storage and long-distance transfer of the reduced catalyst.

First claim

The invention claimed is:

1. A method for producing an activated catalyst for Fischer-Tropsch synthesis comprising:
a first step of reducing a catalyst for Fischer-Tropsch synthesis using hydrogen or carbon monoxide-containing reduced gas;
a second step of eliminating molecular oxygen by bubbling an inert gas in liquid hydrocarbon for more than 12 hours to prepare liquid hydrocarbon in which a part or all of molecular oxygen is eliminated, wherein the liquid hydrocarbon is a saturated or unsaturated hydrocarbon having 5 or more carbons, and the liquid hydrocarbon is a liquid at room temperature;
a third step of introducing the reduced catalyst prepared in the first step into the liquid hydrocarbon prepared in the second step without contacting the catalyst with air to prepare a coated catalyst particle with the liquid hydrocarbon; and
a fourth step of isolating the coated catalyst particle prepared in the third step from the liquid hydrocarbon.

2. The method for producing the activated catalyst according to claim 1 , wherein the first step is carried out at a temperature ranging from 300 to 500° C.

3. The method for producing the activated catalyst according to claim 1 , wherein the inert gas is inert to the reduced catalyst.

4. The method for producing the activated catalyst according to claim 1 , wherein the inert gas is selected from the group consisting of nitrogen, neon, helium, argon, krypton, xeon, radon, and a mixture thereof.

5. The method for producing the activated catalyst according to claim 1 , wherein the liquid hydrocarbon is squalane.

6. The method for producing the activated catalyst according to claim 1 , wherein the inert gas is bubbled for more than 24 hours to eliminate molecular oxygen in the liquid hydrocarbon.

7. The method for producing the activated catalyst according to claim 1 , wherein the catalyst comprises cobalt or iron as an active ingredient.

8. The method for producing the activated catalyst according to claim 1 , wherein the catalyst is supported by any one support selected from the group consisting of silica, alumina, titania, zeolite, a mesopore carbon structure, a carbon nanotube, mesopore silica, a silica/alumina mixture, a titania/silica mixture and an alumina/titania mixture.

9. The method for producing the activated catalyst according to claim 7 , wherein the catalyst containing the metal further comprises one or more co-catalyst metals selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh), ruthenium (Ru) and rhenium (Re).

10. A method for preparing liquid or solid hydrocarbon using a Fischer-Tropsch synthesis reaction comprising:
step a) activating a catalyst for Fischer-Tropsch synthesis according to claim 1 to generate an activated catalyst;
step b) applying the activated catalyst to a Fischer-Tropsch synthesis reactor; and
step c) carrying out the Fischer Tropsch synthesis reaction using the activated catalyst.

11. The method of claim 10 , wherein the Fischer-Tropsch synthesis reaction is carried out at a temperature ranging from 200 to 300° C.

12. The method of claim 10 , wherein the Fischer-Tropsch synthesis reactor is a tube type fixed-bed reactor.

13. The method of claim 10 further comprising a step of collecting and storing the activated catalyst after step a).

14. The method of claim 10 , wherein the catalyst is activated by reducing at a temperature ranging from 300 to 500° C.

Assignees

• Korea Res Inst Chemical Tech

Inventors

• Ha Kyoung Su
• Kwak Geun Jae
• Woo Min Hee
• Lee Yun Jo
• Jun Ki Won

Classifications

• B01J31/02

  containing organic compounds or metal hydrides · CPC title

• C07C1/045

  Regeneration · CPC title

• B01J23/8913 Primary

  Cobalt and noble metals · CPC title

• C10G2400/22

  Higher olefins · CPC title

• B01J23/88

  Molybdenum · CPC title