Method for purifying exhaust gas and for regenerating an oxidation catalyst

Patent metadata

Field	Value
Publication number	US-9815023-B2
Application number	US-201314430159-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Sep 21, 2012
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The invention relates to a method for purifying exhaust gas and for regenerating an oxidation catalytic converter, comprising treating the exhaust gas in an oxidation catalytic converter, which comprises a catalytically active material, which contains at least one noble metal and/or at least one base transition metal, wherein the oxidation catalytic converter is operated continuously or at times at a temperature that causes the oxidation of soot particles and/or carbon particles, and/or wherein the oxidation catalytic converter is periodically heated to a temperature that causes the oxidation of soot particles and/or carbon particles.

First claim

The invention claimed is:

1. A method for cleaning offgas and for regenerating an oxidation catalyst, comprising the steps of
treating the offgas in an oxidation catalyst comprising a catalytically active material, wherein the catalytically active material includes a microporous zeolite material containing at least one noble metal and/or at least one base transition metal, wherein the microporous zeolite material is selected from the group consisting of AFI, AEL, BEA, CHA, EUO, FAU, FER, KFI, LTL, MAZ, MOR, MEL, MTW, OFF, TON and MFI,
wherein the oxidation catalyst is operated continuously or intermittently at a temperature which brings about the oxidation of soot and/or carbon particles, and/or
wherein the oxidation catalyst is heated periodically to a temperature which brings about the oxidation of soot and/or carbon particles, and

wherein the offgas is produced by combustion with a high calorific value; and/or
wherein the offgas is produced by combustion of substitute fuels; and/or
wherein the offgas is produced in the manufacture of cement; and/or
wherein the offgas is produced in the combustion of wood, biomass, mineral oil, natural gas, used oil, used tires, used solvents, industrial or communal refuse, waste and/or controlled waste and/or in the manufacture of cement or in a sintered metal plant.

2. The method as claimed in claim 1 ,
wherein the temperature which brings about the oxidation of soot and/or carbon particles is within a region above 280° C.

3. The method as claimed in claim 1 ,
wherein the intermittent operation or the periodic heating of the oxidation catalyst at/to the temperature which brings about the oxidation of soot and/or carbon particles is conducted at time intervals of 0.5 to 10 hours.

4. The method as claimed in claim 1 ,
wherein the temperature which brings about the oxidation of soot and/or carbon particles in the continuous or intermittent operation or in the periodic heating of the oxidation catalyst is set by means of the offgas and/or by means of a heating unit and/or a heat exchanger.

5. The method as claimed in claim 1 ,
wherein the periodic heating of the oxidation catalyst is conducted during or outside the operation of the oxidation catalyst; and/or
wherein the periodic heating of the oxidation catalyst is conducted in an apparatus in which the oxidation catalyst is used for cleaning of the offgas.

6. The method as claimed in claim 1 ,
wherein the continuous or intermittent operation and/or the periodic heating of the oxidation catalyst is conducted in the presence of oxygen and/or air.

7. The method as claimed in claim 1 , wherein the oxidation catalyst is used for the degradation of CO and/or hydrocarbons.

8. The method as claimed in any claim 1 ,
wherein the noble metal used is at least one metal from the platinum group of the Periodic Table and/or Pt and/or Pd; and/or
wherein the base transition metal is selected from the group consisting of Co, Mn, Cu, Cr and Fe or a combination of the transition metals and/or is present as an oxide and/or is reducible.

9. The method as claimed in claim 1 ,
wherein the catalytically active material is used in the form of a solid extrudate or in the form of a washcoat on a support body.

10. The method as claimed in claim 1 ,
wherein the catalytically active material includes a porous SiO 2 binder; and/or
wherein the catalytically active material includes oxides of Si, Ti and/or W; and/or
wherein the catalytically active material includes alumina doped with Ce, La and/or Y; and/or
wherein the catalytically active material includes at least one oxide of the elements from groups IIIa, IVa, IIIb and/or IVb of the Periodic Table of the Elements; and/or
wherein the catalytically active material contains at least one additive; and/or
wherein the catalytically active material has a BET surface area of at least 0.1 m 2 /g.

11. The method as claimed in claim 10 , wherein the catalytically active material includes an oxide of Al, Si, Ti and/or Zr.

12. The method as claimed in claim 10 , wherein the at least one additive is a compound of the alkali metals and/or alkaline earth metals.

13. The method as claimed in claim 10 , wherein the catalytically active material has a BET surface area of at least 10 m 2 /g.

14. The method as claimed in claim 10 , wherein the catalytically active material has a BET surface area of at least 20 m 2 /g.

15. The method as claimed in claim 1 , comprising the steps of
treating the offgas in the oxidation catalyst;
Introducing reducing agent into the offgas; and
treating the offgas in the catalytic converter for selective catalytic reduction;

wherein the introduction of the reducing agent is conducted prior to the treatment of the offgas in the catalytic converter for selective catalytic reduction.

16. The method as claimed in claim 15 ,
wherein the treatment of the offgas in the oxidation catalyst is conducted prior to the introduction of the reducing agent into the offgas or after the treatment of the offgas in the catalytic converter for selective catalytic reduction; and/or
wherein the reducing agent is first introduced into the offgas, then the offgas is treated in the catalytic converter for selective catalytic reduction and then in the oxidation catalyst.

17. The method as claimed in claim 15 ,
wherein the offgas is cleaned at a temperature above 300° C. and/or
wherein the reducing agent used is ammonia and/or urea.

18. The method as claimed in claim 17 , wherein the offgas is cleaned at a temperature above 350° C., and/or below 600° C.

19. The method as claimed in claim 17 , wherein the offgas is cleaned at a temperature below 550° C.

20. The method as claimed in claim 1 ,
wherein the temperature which brings about the oxidation of soot and/or carbon particles is within a region above 300° C.

21. The method as claimed in claim 1 ,
wherein the temperature which brings about the oxidation of soot and/or carbon particles is within a region above 350° C.

22. The method as claimed in claim 1 ,
wherein the intermittent operation or the periodic heating of the oxidation catalyst at/to the temperature which brings about the oxidation of soot and/or carbon particles is conducted at time intervals of 1 to 6 hours; and/or
wherein the temperature which brings about the oxidation of soot and/or carbon particles in the intermittent operation or in the periodic heating of the oxidation catalyst is set for a period in the range from 0.25 to 2 hours.

Assignees

• Clariant Int Ltd

Inventors

• Schuschke Margit
• Klose Frank
• Stein Andane
• Tissler Arno
• Buettner Olaf
• Reznikov Grigory

Classifications

• B01D53/86 Primary

  Catalytic processes · CPC title

• B01J38/02

  Heat treatment · CPC title

• B01D2255/20707

  Titanium · CPC title

• B01J23/44

  Palladium · CPC title

• B01D2255/30

  Silica · CPC title