Composition comprising a pesticide, a surfactant and an alkoxylate of 2-propyheptylamine

Patent metadata

Field	Value
Publication number	US-9814233-B2
Application number	US-201214001611-A
Country	US
Kind code	B2
Filing date	Feb 27, 2012
Priority date	Feb 28, 2011
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The present invention relates to a composition comprising a pesticide, a surfactant and an alkoxylate. Moreover, the invention relates to a concentrate comprising the surfactant and the alkoxylate; and to a process for preparing the composition by bringing into contact the concentrate and a pesticide; or by bringing into contact the pesticide, the surfactant and the alkoxylate; and to the use of the surfactant by addition to a mixture comprising the pesticide and the alkoxylate. The invention furthermore relates to a method of controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the plants to be protected from the respective pest, on the soil and/or on undesirable plants and/or the crop plants and/or their environment. Furthermore, the invention relates to seed comprising the composition.

First claim

We claim:

1. A composition comprising a pesticide, a surfactant and an alkoxylate, wherein the alkoxylate is an amine alkoxylate (A)

or a quaternized derivative (AQ)

of the amine alkoxylate (A), where
R 1 O n , R 2 O m , and R 5 O p and independently of one another are alkoxylate chains comprising ethylene oxide, propylene oxide, butylene oxide or a mixture thereof,
R 3 is an H, —OH, —OR 4 , —[R 5 —O] p —R 6 , C 1 -C 6 -alkyl or an oxygen anion,
R 4 is a C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl or C 2 -C 6 -alkynyl,
R 6 is an H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, —SO 3 R a , —P(O)OR b OR c , —CH 2 CO 2 R d , or —C(O)R e ,
R 7 is 2-propylheptyl,
R a and R d independently of one another are an H, inorganic or organic cations,
R b and R c independently of one another are an H, inorganic or organic cations, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl or C 2 -C 6 -alkynyl,
R e is C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 2 -C 22 -alkynyl, C 6 -C 22 -aryl or C 7 -C 22 -alkylaryl,
n, m and p independently of one another have a value of from 1 to 30,
A − is an agriculturally acceptable anion, or, if R 3 is an oxygen anion, A − is absent;
and wherein at least one surfactant is selected from the group of surfactants consisting of
a) a C 6-18 -alkylpolyglucoside, with a degree of polymerization of from 1.2 to 1.9, and
b) a C 8-18 -alkylbenzenesulfonate.

2. The composition according to claim 1 , wherein the weight ratio of surfactant to alkoxylate is in the range of from 1:99 to 70:30.

3. The composition according to claim 1 , wherein the composition comprises from 1 to 80% by weight of the total of surfactant and alkoxylate.

4. The composition according to claim 1 , wherein the composition comprises at least two different surfactants.

5. A composition comprising a pesticide, a surfactant and an alkoxylate, wherein the alkoxylate is an amine alkoxylate (A)

or a quaternized derivative (AQ)

of the amine alkoxylate (A), where
R 1 O n , R 2 O m , and R 5 O p and independently of one another are alkoxylate chains comprising ethylene oxide, propylene oxide, butylene oxide or a mixture thereof,
R 3 is an H, —OH, —OR 4 , —[R 5 —O] p —R 6 , C 1 -C 6 -alkyl or an oxygen anion,
R 4 is a C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl or C 2 -C 6 -alkynyl,
R 6 is an H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, —SO 3 R a , —P(O)OR b OR c , —CH 2 CO 2 R d , or —C(O)R e ,
R 7 is 2-propylheptyl,
R a and R d independently of one another are an H, inorganic or organic cations,
R b and R c independently of one another are an H, inorganic or organic cations, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl or C 2 -C 6 -alkynyl,
R e is C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 2 -C 22 -alkynyl, C 6 -C 22 -aryl or C 7 -C 22 -alkylaryl,
n, m and p independently of one another have a value of from 1 to 30,
A − is an agriculturally acceptable anion, or, if R 3 is an oxygen anion, A − is absent;
wherein the surfactant is selected from the group consisting of:
a) a C 16-18 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and/or propylene oxide, and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 12 to 35;
b) a C 10 -guerbet alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 2 to 8;
c) an iso-C 13 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 3 to 10;
d) a C 4-8 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 2 to 9; and
g) a phosphate ester of C 8-14 -alkanol alkoxylates.

6. The composition according to claim 1 , wherein at least one surfactant is a C 8-10 -alkylpolyglucoside with a degree of polymerization of from 1.4 to 1.9.

7. The composition according to claim 1 , wherein R 1 , R 2 and R 5 independently of one another are ethylene, ethylene and propylene, ethylene and butylene, or ethylene, propylene and butylene.

8. The composition according to claim 1 , wherein the pesticide is a pesticide with at least one H-acidic group or an anionic salt of the pesticide with at least one H-acidic group.

9. The composition according to claim 1 , wherein, in the amine alkoxylate (A), the total of n and m is from 2 to 40, and in its quaternized derivative (AQ) the total of n, m and p is from 3 to 80.

10. The composition according to claim 1 , wherein R 3 is an H.

11. The composition according to claim 1 , wherein the pesticide comprises a pesticide with at least one H-acidic group.

12. A concentrate comprising the composition according to claim 1 .

13. A method of controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition according to claim 1 is allowed to act on the respective pests, their environment or the plants to be protected from the respective pest, on the soil and/or on undesired plants and/or the crop plants and/or their environment.

14. The method according to claim 13 , wherein the surfactant is an anionic surfactant comprising an anionic group, which is a sulfonate, sulfate, phosphate or carboxylate; and/or a nonionic surfactant, which is a sugar-based surfactant or an alkanol alkoxylate.

15. The method according to claim 13 , wherein the weight ratio of surfactant to alkoxylate is in the range of from 1:99 to 70:30.

16. The method according to claim 13 , wherein the composition comprises from 1 to 80% by weight of the total of surfactant and alkoxylate.

17. The method according to claim 13 , wherein the composition comprises at least two different surfactants.

18. The method according to claim 13 , wherein at least one surfactant is selected among the following surfactants:
a) a C 16-18 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and/or propylene oxide, and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 12 to 35;
b) a C 10 -guerbet alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 2 to 8;
c) an iso-C 13 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 3 to 10;
d) a C 4-8 -alkanol alkoxylate, where the alkoxylate is composed of ethylene oxide and the alkanol alkoxylate has a mean number of alkoxide units in the range of from 2 to 9;
e) a C 8-10 -alkylpolyglucoside, with a degree of polymerization of from 1.4 to 1.9;
f) a C 8-14 -alkylbenzenesulfonate; and
g) a phosphate ester of C 8-14 -alkanol alkoxylates.

19.

Assignees

• Schnabel Gerhard
• Klingelhoefer Paul
• Nolte Marc
• Evans Richard Roger
• Kraemer Gerd
• Zeyer Silke
• Pfenning Matthias
• Basf Se

Inventors

• Schnabel Gerhard
• Klingelhoefer Paul
• Nolte Marc
• Evans Richard Roger
• Kraemer Gerd
• Zeyer Silke
• Pfenning Matthias

Classifications

• A01N33/08 Primary

  containing oxygen or sulfur · CPC title

• C07C217/08

  the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom · CPC title

• A01N25/30 Primary

  characterised by the surfactants · CPC title

• A01N57/20

  containing acyclic or cycloaliphatic radicals · CPC title

• C11D1/00

  Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent · CPC title