Sealing assembly for a fuel cell stack having a coated metallic sheet intermediate element

Patent metadata

Field	Value
Publication number	US-9812716-B2
Application number	US-201413999163-A
Country	US
Kind code	B2
Filing date	Jan 22, 2014
Priority date	Sep 30, 2004
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

In order to provide a sealing assembly for a fuel cell stack comprising a plurality of fuel cell units, which are arranged consecutively in a stacking direction, wherein each of the fuel cell units comprises a housing with at least one housing part made of a metallic material, which also has an adequate electrical insulation effect and an adequate mechanical strength at a high operating temperature of the fuel cell stack, it is proposed that the sealing assembly comprises at least one intermediate element made of a metallic material, wherein the intermediate element is soldered to a housing part of a first fuel cell unit at at least one location by means of a metal solder and is secured to a housing part of a second fuel cell unit at at least another location, wherein the intermediate element and/or the housing part of the first fuel cell unit is provided with a coating made of a ceramic material.

First claim

The invention claimed is:

1. A fuel cell stack comprising a first fuel cell unit and a second fuel cell unit, which are arranged consecutively in a stacking direction, wherein each of said first and second fuel cell units comprises a respective housing with a respective housing upper part that is provided with at least one of a first fuel gas feed opening and a first oxidising agent feed opening, a respective housing lower part that is provided with at least one of a second fuel gas feed opening and a second oxidising agent feed opening, and a respective intermediate element made from a metallic sheet,
wherein a respective electrically insulating coating is arranged between the respective housing lower part and the respective intermediate element and
wherein the intermediate element of the first fuel cell unit is distinct from the housing lower parts and from the housing upper parts of the first and second fuel cell units and is secured welded and/or soldered to form a connection to the housing upper part of the second fuel cell unit which is solid during operation of the fuel cell stack, and wherein the intermediate element of the first fuel cell unit is soldered to the housing lower part of the first fuel cell unit by means of a solder which is solid at a temperature in the range of about 800° C. to about 900° C.

2. Fuel cell stack according to claim 1 , wherein each of the intermediate elements comprises a frame part, which extends in a ring shape around fluid ducts passing through the fuel cell stack in the stacking direction.

3. Fuel cell stack according to claim 2 , wherein each of the intermediate elements comprises at least one duct boundary part, which is connected to the frame part and either alone or together with the frame part encloses one of the fluid ducts passing through the fuel cell stack.

4. Fuel cell stack according to claim 3 , wherein each of the intermediate elements respectively has a duct boundary part associated with the respective duct for each fuel gas feed duct and each fuel gas discharge duct.

5. Fuel cell stack according to claim 3 , wherein each of the intermediate elements respectively comprises a duct boundary part for each oxidising agent feed duct and each oxidising agent discharge duct.

6. Fuel cell stack according to claim 1 , wherein each of the intermediate elements is formed from a highly corrosion-resistant steel.

7. Fuel cell stack according to claim 1 , wherein each of the electrically Insulating coatings comprises at least one of aluminium oxide, titanium dioxide, zirconium dioxide and magnesium oxide.

8. Fuel cell stack according to claim 1 , wherein each of the electrically insulating coatings is produced by thermal spraying.

9. Fuel cell stack according to claim 1 , wherein each of the intermediate elements is formed from a metal alloy, which contains an oxidisable component.

10. Fuel cell stack according to claim 9 , wherein the metal alloy contains aluminium and/or zirconium as oxidisable component.

11. Fuel cell stack according to claim 9 , wherein each of the electrically insulating coatings is produced by oxidation of an oxidisable component of the metal alloy.

12. Fuel cell stack according to claim 1 , wherein each of the electrically insulating coatings has a thickness of approximately 20 μm to approximately 1000 μm.

13. Fuel cell stack according to claim 1 , wherein the intermediate element of the first fuel cell unit is soldered to the housing lower part of the first fuel cell unit by means of a silver-based solder with added copper.

14. Fuel cell stack according to claim 1 , wherein the intermediate element of the first fuel cell unit is soldered to the housing lower part of the first fuel cell unit by means of a silver-based solder without added copper.

15. Fuel cell stack according to claim 14 , wherein the silver-based solder contains an addition of copper oxide.

16. Fuel cell stack according to claim 1 , wherein the intermediate element of the first fuel cell unit is soldered to the housing lower part of the first fuel cell unit by means of a silver-based solder with added titanium.

17. Fuel cell stack according to claim 1 , wherein the intermediate element of the first fuel cell unit is secured to the housing upper part of the second fuel cell unit by a glass solder.

18. Fuel cell stack according to claim 8 , wherein each of the electrically insulating coatings Is produced by atmospheric plasma spraying, by vacuum plasma spraying or by flame spraying.

Assignees

• Elringklinger Ag

Inventors

• Zerfass Hans-Rainer
• Diez Armin
• Schenk Peter
• Fritz Wolfgang
• Lamp Peter
• Wier Manfred
• Tachtler Joachim

Classifications

• H01M8/0271 Primary

  Sealing or supporting means around electrodes, matrices or membranes · CPC title

• H01M8/12

  operating at high temperature, e.g. with stabilised ZrO2 electrolyte · CPC title

• H01M8/0282

  Inorganic material · CPC title

• H01M8/24

  Grouping of fuel cells, e.g. stacking of fuel cells · CPC title

• H01M8/0286

  Processes for forming seals · CPC title