Omnidirectional high chroma red structural colors

Patent metadata

Field	Value
Publication number	US-9810824-B2
Application number	US-201615144283-A
Country	US
Kind code	B2
Filing date	May 2, 2016
Priority date	Jan 28, 2015
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

A multilayer thin film that reflects an omnidirectional high chroma red structural color. The multilayer thin film may include a reflector layer, at least one absorber layer extending across the reflector layer, and an outer dielectric layer extending across the at least one absorber layer. The multilayer thin film reflects a single narrow band of visible light when exposed to white light and the outer dielectric layer has a thickness of less than or equal to 2.0 quarter wave (QW) of a center wavelength of the single narrow band of visible light.

First claim

What is claimed is:

1. A multilayer interference thin film that reflects an omnidirectional high chroma red structural color comprising:
a multilayer thin film having a reflector layer, at least one absorber layer extending across the reflector layer; and an outer dielectric layer extending across the at least one absorber layer;
wherein the multilayer thin film reflects a single narrow band of visible light when exposed to white light and the outer dielectric layer has a thickness of less than or equal to 2.0 quarter wave (QW) of a center wavelength of the single narrow band of visible light, the single narrow band of visible light having:
a visible full width half maximum (FWHM) width of less than 200 nm;
a color between 0° and 30° on a Lab color space; and
a hue shift of less than 30° on the Lab color space when the multilayer thin film is viewed at angles between 0-45° relative to a direction normal to an outer surface of the outer dielectric layer.

2. The multilayer interference thin film of claim 1 , wherein the reflector layer has a thickness between 5-200 nm and is made from at least one of Al, Ag, Pt and Sn.

3. The multilayer interference thin film of claim 1 , wherein the at least one absorber layer is at least one dielectric absorber layer extending between the reflector layer and the outer dielectric layer.

4. The multilayer interference thin film of claim 3 , wherein the at least one dielectric absorber layer is made from at least one of an oxide and a nitride.

5. The multilayer interference thin film of claim 4 , wherein the at least one dielectric absorber layer is made from at least one of Fe 2 O 3 and TiN, and has a thickness between 5-500 nm.

6. The multilayer interference thin film of claim 1 , wherein the outer dielectric layer has an index of refraction greater than 1.6.

7. The multilayer interference thin film of claim 6 , wherein the outer dielectric layer is made from at least one of MgF 2 , ZnS and TiO 2 .

8. The multilayer interference thin film of claim 7 , wherein the center wavelength of the single narrow band of reflected visible light is between 600-700 nm and the thickness of the outer dielectric layer is less than 175 nm.

9. The multilayer interference thin film of claim 1 , wherein the at least one absorber layer is a dielectric absorber layer and a transparent absorber layer.

10. The multilayer thin film of claim 9 , wherein the transparent absorber layer extends across the dielectric absorber layer and is located between the dielectric absorber layer and the outer dielectric layer.

11. The multilayer interference thin film of claim 9 , wherein the dielectric absorber layer is made from at least one of Fe 2 O 3 and TiN.

12. The multilayer interference thin film of claim 10 , wherein the dielectric absorber layer has a thickness between 5-500 nm.

13. The multilayer interference thin film of claim 9 , wherein the transparent absorber layer is made from at least one of Cr, Ge, Ni, stainless steel, Ti, Si, V, TiN, W, Mo, Nb and Fe 2 O 3 .

14. The multilayer interference thin film of claim 13 , where the transparent absorber layer has a thickness between 5-20 nm.

15. The multilayer interference thin film of claim 1 , wherein the single narrow band of visible light has a visible FWHM width of less than 200 nm, a color between 5° and 25° on the Lab color space, and a hue shift of less than 20° on the Lab space color map when the multilayer thin film is viewed at angles between 0-45° relative to a direction normal to an outer surface of the outer dielectric layer.

16. The multilayer interference thin film of claim 1 , wherein the single narrow band of visible light has a visible FWHM width of less than 200 nm, a color between 10° and 25° on the Lab color space, and a hue shift of less than 15° on the Lab space color map when the multilayer thin film is viewed at angles between 0-45° relative to a direction normal to an outer surface of the outer dielectric layer.

17. An omnidirectional high chroma red structural color multilayer thin film comprising:
a multilayer thin film having a reflector layer, a dielectric absorber layer extending across the reflector layer, an outer dielectric layer extending across the dielectric absorber layer and a transparent absorber layer extending between the dielectric absorber layer and the outer dielectric layer;
wherein the multilayer thin film reflects a single narrow band of visible light when exposed to white light and the outer dielectric layer has a thickness of less than or equal to 2.0 quarter wave (QW) of a center wavelength of the single narrow band of visible light, the single narrow band of visible light having:
a visible full width half maximum (FWHM) FWHM width of less than 200 nm;
a color between 0° and 30° on a Lab color space; and
a hue shift of less than 30° on the Lab color space when the multilayer thin film is viewed at angles between 0-45° relative to a direction normal to an outer surface of the outer dielectric layer.

18. The omnidirectional high chroma red structural color multilayer thin film of claim 17 , wherein the dielectric absorber layer is made from at least one of an oxide and a nitride, and has a thickness between 5-500 nm.

19. The omnidirectional high chroma red structural color multilayer thin film of claim 18 , wherein the dielectric absorber layer is made from at least one of Fe 2 O 3 and TiN.

20. The omnidirectional high chroma red structural color multilayer thin film of claim 17 , wherein the transparent absorber layer is made from at least one of Cr, Ge, Ni, stainless steel, Ti, Si, V, TiN, W, Mo, Nb and Fe 2 O 3 , and has a thickness between 5-20 nm.

Assignees

• Toyota Motor Eng & Mfg North America Inc

Inventors

• Banerjee Debasish
• Zhou Li Qin

Classifications

• G02B5/0825

  the reflecting layers comprising dielectric materials only · CPC title

• G02B5/0858

  the reflecting layers comprising a single metallic layer with one or more dielectric layers · CPC title

• G02B5/286 Primary

  having four or fewer layers, e.g. for achieving a colour effect · CPC title

• G02B5/26

  Reflecting filters (G02B5/28 takes precedence) · CPC title