Waste heat recovery in a chemical process and plant, particularly for the synthesis of ammonia

Patent metadata

Field	Value
Publication number	US-9810104-B2
Application number	US-201414444710-A
Country	US
Kind code	B2
Filing date	Jul 28, 2014
Priority date	Sep 3, 2009
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

A method for recovering waste heat in a process for the synthesis of a chemical product, particularly ammonia, where the product is used as the working fluid of a thermodynamic cycle; the waste heat is used to increase the enthalpy content of a high-pressure liquid stream of said product ( 11 ), delivered by a synthesis section ( 10 ), thus obtaining a vapor or supercritical product stream ( 20 ), and energy is recovered by expanding said vapor or supercritical stream across at least one suitable ex-pander ( 13 ); the method is particularly suited to recover the heat content of the syngas effluent after low-temperature shift.

First claim

The invention claimed is:

1. A process for the synthesis of a chemical product, comprising the steps of:
obtaining at least one make-up reactant in a front-end section;
reacting said least one make-up reactant in a synthesis section, obtaining said product in a high-pressure liquid state;
heating at least a portion of the liquid product delivered by the synthesis section by heat exchange with a waste heat source made available by said process, obtaining an expandable stream of said product in a vapour state or supercritical state;
expanding said expandable product stream to recover energy, obtaining an expanded product stream, and
condensing said expanded product stream by heat exchange with a suitable cooling medium, obtaining a product condensate stream; and
wherein a portion of the product condensate is pumped substantially at the same pressure of said synthesis section; said portion of the product condensate is then re-heated by heat exchange with said waste heat source or a further waste heat source; after said heating, said portion of product stream is then expanded to recover energy and condensed back to liquid, thus forming a closed loop.

2. The process according to claim 1 , said waste heat source being one or more process stream(s) at a temperature below 350° C.

3. The process according to claim 2 , said waste heat source comprising one or more of the following: a process stream taken from said front-end section; a process stream taken from said synthesis loop; a flue gas from a combustion process; a flue gas from a reforming process of said front-end section.

4. The process according to claim 1 , said chemical product being ammonia, said liquid product being liquid ammonia at a pressure in the range 80-300 bar.

5. The process according to claim 4 , wherein:
said liquid ammonia at a pressure of 100-180 bar and a temperature in the range −30 to 10° C. is heated to around 250° C. by heat exchange with said waste heat source, obtaining a supercritical ammonia stream;
the supercritical ammonia stream is then expanded to a condensation pressure between 10 and 20 bar; and
the ammonia stream is then condensed at a condensation temperature corresponding to said condensation pressure, obtaining a low pressure ammonia condensate.

6. The process according to claim 5 , the condensation pressure being around 14-16 bar and the condensation temperature being around 35° C., the condensation being effected by heat exchange of the condensing ammonia stream with cooling air or water at ambient temperature.

7. The process according to claim 4 , said waste heat source comprising one or more of the following:
the ammonia make-up syngas taken from a low-temperature shift reactor of a front-end reforming section;
the ammonia make-up syngas effluent from a methanator of the front-end reforming section;
the flue gas from a steam reformer of the front-end section;
the hot product stream from the synthesis loop.

8. A plant for the synthesis of a chemical product, the plant comprising a front-end section adapted to provide at least one make-up reactant, and a high-pressure synthesis section for reacting said least one make-up reactant and obtaining said chemical product in a liquid state, the plant being characterized by comprising an energy recovery section, said energy recovery section comprising at least:
a heat exchanger disposed to exchange heat between at least a portion of the liquid product delivered by the synthesis section, and a waste-heat source stream, obtaining an expandable stream of said product in a vapour state or supercritical state;
an expander receiving said expandable stream in vapour state or supercritical state, and delivering mechanical energy produced by expansion of said stream, and
a condenser downstream said expander, and disposed to condense the effluent of said expander;
wherein a portion of the product condensate is pumped substantially at the same pressure of said synthesis section; said portion of the product condensate is then re-heated by heat exchange with said waste heat source or a further waste heat source; after said heating, said portion of product stream is then expanded to recover energy and condensed back to liquid, thus forming a closed loop.

9. A method for revamping a plant for producing ammonia, the plant comprising a front-end reforming section adapted to provide a make-up ammonia syngas, and a high-pressure synthesis loop, the method comprising the steps of:
arranging a heat exchange for heating at least a portion of the liquid ammonia product, by means of heat exchange with at least one source of waste heat, so obtaining a stream of heated, high-pressure ammonia stream in a vapour or supercritical state;
providing the provision of at least an expander, for the expansion of said ammonia stream and the production of energy from said waste heat; and
providing a condenser adapted to condense the ammonia effluent at the outlet of said expander;
wherein a portion of the product condensate is pumped substantially at the same pressure of said synthesis section; said portion of the product condensate is then re-heated by heat exchange with said waste heat source or a further waste heat source; after said heating, said portion of product stream is then expanded to recover energy and condensed back to liquid, thus forming a closed loop.

10. The method according to claim 9 , said source of waste heat being one or more of the following: the ammonia make-up syngas taken from a low-temperature shift reactor of the front-end reforming section; the ammonia make-up syngas effluent from a methanator of the front-end reforming section; the flue gas from a steam reformer of the front-end section; the hot product stream from the synthesis loop.

11. A method for recovering waste heat in a process for the synthesis of a chemical product, where at least one make-up reactant is obtained in a front-end section, and reacted in a synthesis section operating at a pressure higher than said front-end section, obtaining said product in a liquid state and at a high pressure, the method comprising the steps of:
using said waste heat to increase the enthalpy content of at least a portion of the liquid product delivered by the synthesis section, by indirect heat exchange, thus obtaining an expandable product stream in a vapour or supercritical state, and
recovering energy by expanding said vapour or supercritical stream across at least one suitable expander;
wherein a portion of the product condensate is pumped substantially at the same pressure of said synthesis section; said portion of the product condensate is then re-heated by heat exchange with said waste heat source or a further waste heat source; after said heating, said portion of product stream is then expanded to recover energy and condensed back to liquid, thus forming a closed loop.

12. The process according to claim 1 , said waste heat source being one or more process stream(s) at a temperature in the range 50-300° C.

13. A method for revamping a plant for producing ammonia, the plant comprising a front-end reforming section adapted to provide a make-up ammonia syngas, and a high-pressure synthesis loop, the method comprising the steps of:
arranging a heat exchange for heating at least a portion of the liquid ammonia product, by means of heat exchange with at least one source of waste heat, so obtaining a stream of heated, high-pressure ammonia stream in a vapour or supercritical state;
providing the provision of at least an expander and a generator connected to said expander, for the expansion of said ammonia stream and the production of energy from said waste heat; and
pro

Assignees

• Filippi Ermanno
• Ostuni Raffaele
• Casale Sa

Inventors

• Filippi Ermanno
• Ostuni Raffaele

Classifications

• C01B2203/068

  Ammonia synthesis · CPC title

• C01C1/047

  by condensation · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• F01K25/08 Primary

  using special vapours · CPC title

• C01B2203/84

  Energy production · CPC title