Hydrophobic and oleophobic coatings

Patent metadata

Field	Value
Publication number	US-9809712-B2
Application number	US-201314090047-A
Country	US
Kind code	B2
Filing date	Nov 26, 2013
Priority date	Nov 26, 2013
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

A hydrophobic surface comprises a surface texture and a coating disposed on the surface texture, wherein the coating comprises an amorphous diamond like carbon material doped with 10 to 35 atomic percent of Si, O, F, or a combination comprising at least one of the foregoing, or a low surface energy material selected from fluoropolymer, silicone, ceramic, fluoropolymer composite, or a combination comprising at least one of the foregoing; and wherein the surface texture comprises a micro texture, a micro-nano texture, or a combination of a micro texture and a micro-nano texture.

First claim

What is claimed is:

1. A hydrophobic surface comprising a surface texture and a coating disposed on the surface texture, wherein the coating comprises a first layer disposed directly on the surface texture and a second layer disposed on the first layer, the first layer comprising a conforming material and the second layer comprising an amorphous diamond like carbon material doped with 25 to 35 atomic percent of a dopant comprising a combination of Si and O or a combination of Si, O, and F, the diamond like carbon material comprising 60 to 90 atomic percent of sp 2 bonded carbon and 10 to 40 atomic percent of sp 3 bonded carbon; and the conforming material comprising polytetrafluoroethylene, fluorinated ethylene propylene, perfluoroalkoxy, polyvinylidene fluoride, polydimethylsiloxane, polyphenylene sulfide, metal-polytetrafluoroethylene composites, or a combination comprising at least one of the foregoing; and wherein the surface texture comprises a micro texture, a micro-nano texture, or a combination of a micro texture and a micro-nano texture; and the coating has a scratch hardness of greater than 100 ksi, determined according to ASTM standard D7027-05 (2009) using a micro-scratch tester.

2. The hydrophobic surface of claim 1 , wherein the diamond like carbon material further comprises 15 to 25 atomic percent of hydrogen atoms.

3. The hydrophobic surface of claim 1 , wherein an atomic concentration of the dopant in the coating decreases in a direction from the coating towards the surface texture.

4. The hydrophobic surface of claim 1 , wherein the texture has a hexagonal pattern.

5. The hydrophobic surface of claim 4 , wherein the texture comprises pillars having a circular cross-section with a height (c) of 20 μm to 160 μm, a width (a) of 10 μm to 60 μm, and a spacing (b) of 10 μm to 100 μm.

6. The hydrophobic surface of claim 5 , wherein the width (a), spacing (b), and height (c) are selected based on the equation

R
=

1
+

2
⁢
π
⁢

⁢
ac

3

⁢

(

a
+
b

)

2

,

wherein R is between 2 and 4.

7. The hydrophobic surface of claim 5 , wherein at least one pillar further comprises a nano texture on a surface of the at least one pillar.

8. The hydrophobic surface of claim 1 , wherein the contact angle of the coating is increased by at least 30% as compared to the same coating disposed on a surface without the texture.

9. The hydrophobic surface of claim 1 , wherein the substrate comprises a metal.

10. The hydrophobic surface of claim 1 , wherein the coating has a thickness of 0.01 to 100 microns.

11. A hydrophobic surface comprising a coating disposed on an un-textured surface, wherein the coating comprises a first layer disposed directly on the un-textured surface and a second layer disposed on the first layer, the first layer comprising a conforming material and the second layer comprising an amorphous diamond like carbon material doped with 25 to 35 atomic percent of a dopant comprising a combination of Si and O, or a combination of Si, O, and F, the diamond like carbon material comprising 60 to 90 atomic percent of sp 2 bonded carbon and 10 to 40 atomic percent of sp 3 bonded carbon and wherein the un-textured surface comprises a metal; and the conforming material comprising polytetrafluoroethylene, fluorinated ethylene propylene, perfluoroalkoxy, polyvinylidene fluoride, polydimethylsiloxane, polyphenylene sulfide, metal-polytetrafluoroethylene composites, or a combination comprising at least one of the foregoing; and the coating has a scratch hardness of greater than 100 ksi, determined according to ASTM standard D7027-05 (2009) using a micro-scratch tester.

12. The hydrophobic surface of claim 11 , wherein the diamond like carbon material further comprises 15 to 25 atomic percent of hydrogen atoms.

13. The hydrophobic surface of claim 12 , wherein an atomic concentration of the dopant decreases in a direction from the coating towards the un-textured surface.

14. A method of producing a hydrophobic surface, the method comprising forming a texture on a surface of a substrate to provide a textured surface, forming a coating on the textured surface, wherein the coating comprises a first layer disposed directly on the surface texture and a second layer disposed on the first layer, the first layer comprising a conforming material and the second layer comprising an amorphous diamond like carbon material doped with 25 to 35 atomic percent of a dopant comprising a combination of Si and O, or a combination of Si, O, and F, the diamond like carbon material comprising 60 to 90 atomic percent of sp2 bonded carbon and 10 to 40 atomic percent of sp3 bonded carbon; the conforming material comprising polytetrafluoroethylene, fluorinated ethylene propylene, perfluoroalkoxy, polyvinylidene fluoride, polydimethylsiloxane, polyphenylene sulfide, metal-polytetrafluoroethylene composites, or a combination comprising at least one of the foregoing.

15. The method of claim 14 , wherein the second layer is disposed on the first layer via physical vapor deposition, chemical vapor deposition, and plasma-assisted vapor deposition.

16. The method of claim 14 , wherein the second layer is disposed on the first layer via plasma ion immersion implantation and deposition.

17. The method of claim 14 , wherein forming the texture comprises laser ablating, sand blasting, laser additive manufacturing, extrusion, stamping, chemical etching, electro-chemical etching, or depositing small particles on the surface of the substrate.

18. The method of claim 14 , wherein forming a texture comprises forming a micro texture, and forming a nano texture on the micro texture.

19. The method of claim 18 , wherein forming a nano texture comprises heating the substrate comprising the micro structure to an elevated temperature under argon and oxygen.

20. The method of claim 18 , wherein forming a nano texture comprises chemical etching, electrical etching, or a combination thereof.

Assignees

• Kumar Deepak
• Xu Zhiyue
• Baker Hughes A Ge Co Llc

Inventors

• Kumar Deepak
• Xu Zhiyue

Classifications

• Y10T428/30

  Self-sustaining carbon mass or layer with impregnant or other layer · CPC title

• Y10T428/24355

  Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] · CPC title

• C23C16/30

  Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides · CPC title

• C23C16/26 Primary

  Deposition of carbon only · CPC title

• C09D1/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title