Curable silicone composition

Patent metadata

Field	Value
Publication number	US-9809708-B2
Application number	US-201415303885-A
Country	US
Kind code	B2
Filing date	Apr 15, 2014
Priority date	Apr 15, 2014
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

This invention provides a curable composition, which comprises a RTV silicone and an uncrosslinked or partially crosslinked rubber and/or elastomer providing initial strength to the composition, wherein the ratio of the silicone to the rubber and/or elastomer ranges from 1:2 to 15:1 by weight. The curable composition has improved handling and application properties in addition to good thermal conductive performance, UV and thermal aging performance, electrical insulation performance, and adhesive performance.

First claim

The invention claimed is:

1. A curable composition, comprising a room temperature vulcanizable (RTV) silicone and at least one of an uncrosslinked rubber, a partially crosslinked rubber and an elastomer providing initial strength to the composition, wherein the ratio of the RTV silicone to the at least one of an uncrosslinked rubber, a partially crosslinked rubber and an elastomer ranges from 1:2 to 15:1 by weight.

2. The composition according to claim 1 , wherein the RTV silicone has a Mn of from 10,000 g/mol to 3,000,000 g/mol.

3. The composition according to claim 1 , wherein the RTV silicone has a viscosity of 10,000 cps or more.

4. The composition according to claim 1 , wherein the RTV silicone comprises at least one selected from the group consisting of a hydroxyl silicone resin, an alkoxyl silicone resin, and a combination thereof.

5. The composition according to claim 4 , wherein the alkoxyl silicone resin comprises at least one selected from the group consisting of methoxyl silicone resin, ethoxyl silicone resin, and a combination thereof.

6. The composition according to claim 1 , wherein the at least one of an uncrosslinked rubber, a partially crosslinked rubber and an elastomer has a Mooney viscosity of at least 10 at 100° C.

7. The composition according to claim 1 , wherein the at least one of an uncrosslinked rubber, a partially crosslinked rubber and an elastomer comprises at least one selected from the group consisting of butyl rubber, fluoroelastomer (FKM), ethylene propylene diene rubber (EPDM), ethylene propylene rubber (EPR), nitrile rubber (NBR), hydrogenated nitrile rubber (HNBR), acrylate rubber (ACM), polyurethane rubber (PUR), natural rubber (NR), styrene butadiene rubber (SBR), polychloroprene rubber (CR), polybutadiene rubber (BR), polyisoprene rubber (IR), chlorosulfonated polyethylene (CSM), polysulfide rubber (PSR), chlorohydrin rubber (CO), and the combination thereof.

8. The composition according to claim 1 , wherein the at least one of an uncrosslinked rubber, a partially crosslinked rubber and an elastomer comprises at least one selected from the group consisting of butyl rubber, fluoroelastomer (FKM), hydrogenated nitrile rubber (HNBR), ethylene propylene diene rubber (EPDM), and the combination thereof.

9. The composition according to claim 1 , wherein the ratio of RTV silicone to the rubber and/or elastomer ranges from 1:1.5 to 10:1 by weight.

10. The composition according to claim 1 , further comprising at least one component selected from the group consisting of a crosslinker, a catalyst, a co-crosslinker, a reinforcing material, an adhesive promoter, a pigment, a toner, a fire retardant, a surface modifier, a thickener, a rheology modifier, and a combination thereof.

11. The composition according to claim 10 , wherein the crosslinker comprises at least one selected from the group consisting of methyltriacetoxysilane, methyltrimethoxysilane, methyl tri(isopropenyloxy) silane, methyltrimethylethylketoximesilane, vinyltrimethoxysilane, vinyltriethoxysilane, γ-(methacryloxy)propyltrimethoxysilane, aminopropyltriethoxysilane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, γ-(2,3-epoxypropoxy)propyltrimethoxysilane, γ-mercaptopropyltriethoxysilane, γ-mercaptopropyltrimethoxysilane, methyltriethoxysilane, tetramethoxysilane, tetrapropoxysilane, tetraethoxysilane, and ethyltriacetoxysilane.

12. The composition according to claim 10 , wherein the catalyst comprises at least one selected from the group consisting of titanium complex, dibutyltin diacetate, (tetramethylguanidino) propyl triethoxy silane, dibutyltin dilaurate, and stannous octoate.

13. The composition according to claim 10 , wherein the reinforcing material comprises at least one selected from the group consisting of fumed silica, calcium carbonate, titanium oxide, mica and a combination thereof.

14. The composition according to claim 1 , further comprising at least one component selected from the group consisting of γ-(2,3-epoxypropoxy) propyl trimethoxysilane, carbon black, DecaBDE, and antimony trioxide.

15. The composition according to claim 1 , wherein the RTV silicone is from 20 wt % to 50 wt %, based on the total weight of the composition.

16. The composition according to claim 1 , wherein the at least one of the uncrosslinked rubber, the partially crosslinked rubber and the elastomer is from 5 wt % to 40 wt %, based on the total weight of the composition.

17. The composition according to claim 10 , wherein the amount of the crosslinker is from 0.1% to 20% by weight based on the amount of RTV silicone.

18. The composition according to claim 10 , wherein the amount of the catalyst is from 0.5% to 10% by weight based on the amount of RTV silicone.

19. The composition according to claim 10 , wherein the amount of the reinforcing material is from 10% to 300% by weight based on the amount of RTV silicone.

Assignees

• 3M Innovative Properties Co

Inventors

• Wang Yaming
• Zhou Wei
• Cui Wei
• Wu Qing
• Jin Zhou
• Guan Zheng

Classifications

• C08G77/16

  to hydroxy groups · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L83/04 Primary

  Polysiloxanes · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title