Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties

Patent metadata

Field	Value
Publication number	US-9809695-B2
Application number	US-201414563381-A
Country	US
Kind code	B2
Filing date	Dec 8, 2014
Priority date	Dec 8, 2014
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

Resin compositions, layers, and interlayers comprising two or more thermoplastic polymers and at least one RI balancing agent for adjusting the refractive index of at least one of the resins or layers is provided. Such compositions, layers, and interlayers exhibit enhanced optical properties while retaining other properties, such as impact resistance and acoustic performance.

First claim

What is claimed is:

1. An interlayer comprising:
a first poly(vinyl acetal) resin;
a second poly(vinyl acetal) resin having a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said first poly(vinyl acetal) resin;
at least one plasticizer, wherein each plasticizer present in said interlayer has a refractive index of less than 1.460; and
a refractive index (RI) balancing agent, wherein said RI balancing agent includes residues of a high RI aldehyde, and wherein said first poly(vinyl acetal) resin comprises at least 0.5 weight percent of said residues of said high RI aldehyde, based on the total weight of aldehyde residues of said first poly(vinyl acetal) resin,
wherein each of said first and second poly(vinyl acetal) resin are present in said interlayer in an amount of at least 0.5 weight percent, based on the total weight of resins in said interlayer, and wherein said interlayer has a haze value of not more than 5 percent, and
wherein said interlayer comprises a multilayer interlayer having at least a first resin layer and a second resin layer adjacent to said first resin layer, wherein said first resin layer comprises said first poly(vinyl acetal) resin and said second resin layer comprises said second poly(vinyl acetal) resin, wherein said RI balancing agent is present in at least one of said first and said second resin layers, and wherein the absolute value of the difference between the refractive index of said first resin layer and the refractive index of said second resin layer is not more than 0.010.

2. The interlayer of claim 1 , wherein said RI balancing agent comprises at least one solid RI additive, wherein said solid RI additive is present in one of said first and said second resin layers in a higher amount than in the other of said first and said second resin layers.

3. The interlayer of claim 2 , wherein said solid RI additive has a refractive index of at least 1.460 and is present in said second resin layer in a higher amount than in said first resin layer, wherein said solid RI additive is present in said second resin layer in an amount of at least 1 phr.

4. The interlayer of claim 1 , wherein the combined amount of said first and second poly(vinyl acetal) resins comprises at least 80 weight percent of the total weight of all resins in said interlayer, wherein said first poly(vinyl acetal) resin has a residual hydroxyl content of at least 16 weight percent and said second poly(vinyl acetal) resin has a residual hydroxyl content of not more than 15 weight percent, wherein at least one of said first and said second poly(vinyl acetal) resins has a residual acetate content of less than 4 weight percent, wherein said first resin layer has a glass transition temperature that is at least 3° C. higher than the glass transition temperature of said second resin layer, wherein said first resin layer has a refractive index of at least 1.480 and said second resin layer has a refractive index of at least 1.470, wherein said interlayer has a haze value of not more than 2 percent and a loss factor at 20° C. of at least 0.10.

5. A multiple layer panel comprising said interlayer of claim 1 and at least one rigid substrate.

6. The, An interlayer comprising:
a first poly(vinyl acetal) resin;
a second poly(vinyl acetal) resin having a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said first poly(vinyl acetal) resin;
at least one plasticizer, wherein each plasticizer present in said interlayer has a refractive index of less than 1.460; and
a refractive index (RI) balancing agent, wherein said RI balancing agent comprises residues of a high RI aldehyde, wherein said first poly(vinyl acetal) resin comprises at least 0.5 weight percent of residues of said high RI aldehyde, based on the total weight of aldehyde residues of said first poly(vinyl acetal) resin,
wherein each of said first and second poly(vinyl acetal) resin are present in said interlayer in an amount of at least 0.5 weight percent, based on the total weight of resins in said interlayer, and wherein said interlayer has a haze value of not more than 5 percent,
wherein said interlayer comprises a blended resin that includes said first and said second poly(vinyl acetal) resins, wherein one of said first and said second poly(vinyl acetal) resins is dispersed within the other of said first and said second poly(vinyl acetal) resins thereby forming domains of said one of said first and said second poly(vinyl acetal) resins within said other of said first and said second poly(vinyl acetal) resins, and wherein, when blended, the absolute value of the difference between the refractive index of said first poly(vinyl acetal) resin domains and the refractive index of said second poly(vinyl acetal) resin domains is not more than 0.010.

7. A multiple layer panel comprising said interlayer of claim 6 and at least one rigid substrate.

8. An interlayer comprising:
a first poly(vinyl acetal) resin;
a second poly(vinyl acetal) resin; and
a refractive index (RI) balancing agent, wherein said RI balancing agent includes residues of a high RI aldehyde present in at least one of said first and said second poly(vinyl acetal) resins,
wherein said high RI aldehyde is present in an amount of at least 0.5 weight percent, based on the total weight of aldehyde residues of said first or said second poly(vinyl acetal) resin,
wherein said interlayer has a haze value of not more than 5 percent and a loss factor at 20° C. of at least 0.10, and
wherein, in the absence of said RI balancing agent, said interlayer has a haze value of at least 5 percent.

9. The interlayer of claim 8 , wherein said interlayer meets at least one of the following criteria (i) through (iii)—
(i) said first poly(vinyl acetal) resin has a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said second poly(vinyl acetal) resin;
(ii) said first poly(vinyl acetal) resin has a residual acetate content that is at least 2 weight percent higher or lower than the residual acetate content of said second poly(vinyl acetal) resin; and
(iii) said first poly(vinyl acetal) resin comprises at least 0.5 weight percent of residues of at least one aldehyde not present in said second poly(vinyl acetal) resin, based on the weight of total aldehyde residues of said first poly(vinyl acetal) resin.

10. The interlayer of claim 8 , wherein said interlayer comprises at least a first resin layer and a second resin layer adjacent to said first resin layer, wherein said first resin layer comprises said first poly(vinyl acetal) resin and said second resin layer comprises said second poly(vinyl acetal) resin, wherein said RI balancing agent is present in at least one of said first and said second layers, and wherein the absolute value of the difference between the refractive index of said first resin layer and the refractive index of said second resin layer is not more than 0.010.

11. The interlayer of claim 8 , wherein said interlayer comprises a blended resin layer that includes said first poly(vinyl acetal) resin, said second poly(vinyl acetal) resin, and a plasticizer, wherein, in said blended layer, one of said first and said second poly(vinyl acetal) resins is dispersed within the other of said first and said second poly(vinyl acetal) resins thereby forming domains of said one of said first and said second poly(vinyl acetal) resins within said other of said first and said second poly(vinyl acetal) resins, and wherein, when blended, the absolute value of the difference between the refractive index of said first poly(vinyl acetal)

Assignees

• Solutia Inc

Inventors

• Lu Jun
• Li Zhou

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• B32B2571/02

  defensive, e.g. armour plates or anti-ballistic clothing · CPC title

• B32B17/10761

  containing vinyl acetal · CPC title

• B32B2607/02

  Wall papers, wall coverings · CPC title

• B32B27/00

  Layered products comprising {a layer of} synthetic resin {(fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18)} · CPC title