Polycarbonate polyol compositions and methods

Patent metadata

Field	Value
Publication number	US-9809678-B2
Application number	US-201615161684-A
Country	US
Kind code	B2
Filing date	May 23, 2016
Priority date	Sep 8, 2008
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

First claim

What is claimed is:

1. A method for the synthesis of aliphatic polycarbonate polyols having a high percentage of —OH end groups, the method comprising the steps of:
a) contacting a reaction mixture comprising one or more epoxides in the presence of carbon dioxide with a polymerization system comprising:
a metallosalenate metal complex; and
a chain transfer agent having a plurality of sites capable of initiating copolymerization of epoxides and CO 2 ;
wherein the chain transfer agent has a structure Y-A-(Y) n ,
where:
each —Y group is independently a functional group capable of initiating chain growth of epoxide CO 2 copolymers and each Y group may be the same or different;
-A- is a covalent bond or a multivalent moiety; and
n is an integer between 1 and 10, inclusive;

wherein the molar ratio of metal complex to epoxide ranges from 1:100 to 1:1,000,000

b) allowing the polymerization reaction to proceed until a desired molecular weight aliphatic polycarbonate polyol has formed, wherein in the aliphatic polycarbonate polyol composition
at least 97% of the end groups are hydroxyl groups, and
more than 95% of the linkages formed by the metal complex are carbonate linkages; and

c) terminating the polymerization.

2. The method of claim 1 , wherein at least 50% of epoxide in the reaction mixture is converted to aliphatic polycarbonate polyol.

3. The method of claim 1 , wherein the molar ratio of chain transfer agent to metal complex is between 10:1 and 1,000:1.

4. The method of claim 1 , wherein the molar ratio of chain transfer agent to metal complex is between 40:1 and 400:1.

5. The method of claim 1 , wherein the molar ratio of chain transfer agent to metal complex is greater than 1000:1.

6. The method of claim 1 , wherein at least 98% of the end groups of the polycarbonate polyol formed are OH groups.

7. The method of claim 1 , wherein at least 99% of the end groups of the polycarbonate polyol formed are OH groups.

8. The method of claim 1 , wherein the PDI of the polycarbonate polyol formed is less than 1.6.

9. The method of claim 1 , wherein the PDI of the polycarbonate polyol formed is less than 1.2.

10. The method of claim 1 , wherein at least 97% of the linkages formed by the metal complex are carbonate linkages.

11. The method of claim 1 , wherein greater than 98% of the linkages formed by the metal complex are carbonate linkages.

12. The method of claim 1 , wherein at least 99% of the linkages formed by the metal complex are carbonate linkages.

13. The method of claim 1 , wherein the polycarbonate polyol has an average molecular weight number between 300 g/mol and 20,000 g/mol.

14. The method of claim 1 , wherein the epoxide comprises propylene oxide.

15. The method of claim 14 , wherein the head-to-tail ratio of the polycarbonate polyol is greater than 80%.

16. The method of claim 14 , wherein the head-to-tail ratio of the polycarbonate polyol is greater than 90%.

17. The method of claim 14 , wherein the head-to-tail ratio of the polycarbonate polyol is greater than 95%.

18. The method of claim 1 , wherein less than 5% cyclic byproduct is formed.

19. The method of claim 18 , wherein the polymerization byproduct is cyclic carbonate.

20. The method of claim 1 , wherein the chain transfer agent is selected from the group consisting of: water; polyhydric alcohols; polyacids; hydroxy acids; primary amines; polyamines, amino alcohols, amino acids, aldehyde hydrates, ketone hydrates, formaldehyde, polyhydric thiols, hydroxy thiols, amino thiols, and mercapto acids, boronic acids, and mixtures of any two or more of these.

21. The method of claim 1 , wherein the chain transfer agent is selected from the group consisting of: water; polyhydric alcohols; polyacids; and hydroxy acids, and mixtures of any two or more of these.

22. The method of claim 1 , further comprising the step of calculating a molar ratio of epoxide relative to metal complex to be used in the polymerization, the calculation comprising the substeps of: i) selecting a desired length of time for which the polymerization reaction is to be run, ii) multiplying the selected length of time for which the polymerization reaction is to run by the turnover frequency of the metal complex under the reaction conditions iii) multiplying this result by the desired mol % conversion of epoxide, and iv) using the inverse of this result as the ratio of metal complex to epoxide used for the reaction.

23. The method of claim 1 , further comprising the step of calculating the ratio of chain transfer agent to polymerization metal complex to be used in the polymerization, the calculation comprising the substeps of: i) selecting a desired length of time for which the polymerization reaction is to be run, ii) multiplying the selected length of time for which the polymerization reaction is to run by the turnover frequency of the metal complex under the reaction conditions, iii) multiplying this result by the desired mol% conversion of epoxide; v) taking the value from step (iii) and multiplying this result by the molecular weight of the repeating unit of the polycarbonate; vi) selecting a desired molecular weight for the polyol and dividing the result from step (v) by this number; and vii) subtracting the number of chains produced per metal complex molecule from the result of step (vi) and taking the result as the ratio of chain transfer agent to metal complex used in step (a).

24. The method of claim 1 , further comprising the steps of measuring the amount of water present in the reaction mixture and reducing the amount of chain transfer agent added to the reaction mixture by an amount determined by the result of the water measurement.

25. The method of claim 1 , further comprising the step of drying the reaction mixture prior to step (b).

26. The method of claim 1 , further comprising the steps of measuring the molecular weight of the polymer formed in the reaction mixture at two or more time points, extrapolating the time at which a desired molecular weight of polymer will have formed, and terminating the polymerization reaction at the extrapolated time.

27. The method of claim 26 , wherein the molecular weight of the polymer is determined by gel permeation chromatography.

28. The method of claim 1 , wherein less than 1% cyclic byproduct is formed.

29. The method of claim 28 , wherein the polymerization byproduct is cyclic carbonate.

Assignees

• Novomer Inc
• Saudi Aramco Tech Co

Inventors

• Allen Scott D
• Coates Geoffrey W
• Cherian Anna E
• Simoneau Chris A
• Gridnev Alexei A
• Farmer Jay J

Classifications

• C08G64/34 Primary

  and cyclic ethers · CPC title

• C08G18/44

  Polycarbonates · CPC title

• C08G64/0208

  saturated · CPC title

• C08G64/0216

  containing a chain-terminating or -crosslinking agent · CPC title