Polypropylene production processes

Patent metadata

Field	Value
Publication number	US-9809662-B2
Application number	US-201514728599-A
Country	US
Kind code	B2
Filing date	Jun 2, 2015
Priority date	Jun 2, 2015
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

Processes for producing a polypropylene product by using a lower purity propylene stream. An operating parameter of the separation zone for a dehydrogenation zone effluent may be adjusted or controlled to lower the purity of the propylene stream produced by the separation zone. The reflux rate of propylene-propane splitter may be reduced. The duty of the reboiler for the propylene-propane splitter may be lowered. The number of stages in the propylene-propane splitter may be decreased.

First claim

What is claimed is:

1. A process for producing polypropylene from a propylene stream comprising less than 99.5% by volume of polypropylene, the process comprising:
dehydrogenating a feed stream including propane in a dehydrogenation zone to provide an olefin steam, the olefin stream including propylene and propane;
separating the olefin stream in a separation zone into a propylene stream and a propane stream, the propylene stream comprising less than 99.5% by volume of propylene;
converting propylene from the propylene stream into polypropylene within a conversion zone;
adjusting an operating parameter of the separation zone to lower a purity of the propylene stream; and,
monitoring a purity of polypropylene from the conversion zone after the operating parameter of the separation zone has been adjusted.

2. The process of claim 1 wherein the propylene stream comprises at least 95% by volume propylene.

3. The process of claim 1 wherein the propylene stream comprises at between 97 and 95% by volume propylene.

4. The process of claim 1 wherein the operating parameter comprises a reflux rate of the separation zone.

5. The process of claim 1 wherein the operating parameter comprises a number of stages in the separation zone.

6. The process of claim 1 further comprising:
adjusting the operating parameter based upon the purity of the polypropylene.

7. The process of claim 6 further comprising:
monitoring the purity of the polypropylene after the operating parameter of the separation zone has been adjusted based upon the purity of the polypropylene; and,
adjusting the operating parameter of the separation zone to increase the purity of the propylene stream.

8. A process for producing polypropylene from a propylene stream comprising less than 99.5% by volume of polypropylene, the process comprising:
passing a feed stream to a dehydrogenation zone including a catalyst and being configured to dehydrogenate propane in the feed stream and provide an olefin stream, the olefin stream including propylene and propane;
passing the olefin stream to a separation zone having one or more columns being operated to separate a propylene stream from the olefin stream, the propylene stream comprising between 95 and 99.5% by volume of propylene;
passing the propylene stream to a conversion zone being operated to convert propylene into polypropylene;
adjusting an operating parameter of at least one column in the separation zone to lower a purity of the propylene stream; and,
monitoring a purity of the polypropylene from the conversion zone after the operating parameter of the at least one column of the separation zone has been adjusted.

9. The process of claim 8 wherein the propylene stream comprises between 95 and 97% by volume of propylene.

10. The process of claim 8 wherein the operating parameter comprises a reflux rate of a column in the separation zone.

11. The process of claim 10 wherein the column comprises a propylene-propane splitter column.

12. The process of claim 8 wherein the operating parameter comprises a number of stages in a column in the separation zone.

13. The process of claim 12 wherein the column comprises a propylene-propane splitter column.

14. The process of claim 8 further comprising:
adjusting the operating parameter based upon the purity of the polypropylene to increase the purity of the propylene stream.

15. The process of claim 14 further comprising:
monitoring the purity of the polypropylene after the purity of the propylene stream has been increased; and,
adjusting the operating parameter of the at least one column of the separation zone to lower the purity of the propylene stream.

16. The process of claim 15 wherein the at least one column of the separation zone comprises a propylene-propane splitter column.

Assignees

• Uop Llc

Inventors

• Kanyuh Adam J
• Banach Michael J
• James Robert B

Classifications

• C07C5/333

  Catalytic processes · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C07C11/06

  Propene · CPC title