Production method of fatty acid ester

Patent metadata

Field	Value
Publication number	US-9809531-B2
Application number	US-201515510943-A
Country	US
Kind code	B2
Filing date	Nov 17, 2015
Priority date	Nov 20, 2014
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

A method for producing a fatty acid ester through desulfurization of sulfur from a fatty acid ester using a catalyst,
wherein the catalyst carries a catalyst metal on a support, (a) the catalyst contains as the catalyst metal one or more elements selected from the elements of group 9, group 10 and group 11 of the periodic table, (b) the total pore volume of the catalyst is 0.05 mL/g or more, and (c) the volume of pores with a pore size of 0.1 μm or more and 500 μm or less is 50% or more of the total pore volume of the catalyst. A desulfurization method using the desulfurization and a method for producing an alcohol through hydrogenation of the fatty acid ester obtained through the desulfurization are also provided.

First claim

The invention claimed is:

1. A method for producing a fatty acid ester through desulfurization of sulfur from a fatty acid ester using a catalyst,
wherein the catalyst carries a catalyst metal on a support,
(a) the catalyst contains as the catalyst metal one or more elements selected from the elements of group 9, group 10 and group 11 of the periodic table,
(b) the total pore volume of the catalyst is 0.05 mL/g or more, and
(c) the volume of pores with a pore size of 0.1 μm or more and 500 μm or less is 50% or more of the total pore volume of the catalyst.

2. The method for producing a fatty acid ester according to claim 1 , wherein the volume of pores with a pore size of 0.1 μm or more and 500 μm or less in the catalyst is 70% or more of the total pore volume.

3. The method for producing a fatty acid ester according to claim 1 , wherein the porosity of the catalyst is 30% or more and 99% or less.

4. The method for producing a fatty acid ester according to claim 1 , wherein the median of the pore size of the catalyst is 0.1 μm or more and 100 μm or less.

5. The method for producing a fatty acid ester according to claim 1 , wherein the carried amount of the catalyst metal per unit volume of the catalyst is 0.02 g/mL or more and 1.0 g/mL or less.

6. The method for producing a fatty acid ester according to claim 1 , wherein the carried amount of the catalyst metal per unit mass of the catalyst is 0.01 g/g or more and 0.7 g/g or less.

7. The method for producing a fatty acid ester according to claim 1 , wherein the support has a porous structure.

8. The method for producing a fatty acid ester according to claim 1 , wherein the support is a fiber structure.

9. The method for producing a fatty acid ester according to claim 1 , wherein the catalyst is obtained by the following coating material preparation step, carrying step and calcining step:
the coating material preparation step: a step in which a catalyst precursor coating material or a catalyst metal oxide coating material is produced by dispersing a catalyst precursor or a catalyst metal oxide in a dispersion medium;
the carrying step: a step in which the catalyst precursor coating material or the catalyst metal oxide coating material obtained in the coating material preparation step is carried on the support; and
the calcining step: a step in which the catalyst precursor or the catalyst metal oxide carried on the support in the carrying step is calcined.

10. The method for producing a fatty acid ester according to claim 9 , wherein the catalyst precursor is a compound which is converted to a catalyst metal oxide by calcining.

11. The method for producing a fatty acid ester according to claim 9 , wherein the carrying step is a carrying step by immersing the support in the catalyst precursor coating material or the catalyst metal oxide coating material.

12. The method for producing a fatty acid ester according to claim 9 , wherein the catalyst precursor coating material or the catalyst metal oxide coating material contains a binder.

13. The method for producing a fatty acid ester according to claim 12 , wherein the binder is an oxide of a metal other than the catalyst metal.

14. The method for producing a fatty acid ester according to claim 1 , wherein the catalyst metal is one or more elements selected from Co, Ni and Cu.

15. A method for producing an alcohol through desulfurization of sulfur from a fatty acid ester using a catalyst and hydrogenation of the obtained fatty acid ester,
wherein the catalyst carries a catalyst metal on a support,
(a) the catalyst contains as the catalyst metal one or more elements selected from the elements of group 9, group 10 and group 11 of the periodic table,
(b) the total pore volume of the catalyst is 0.05 mL/g or more, and
(c) the volume of pores with a pore size of 0.1 μm or more and 500 μm or less is 50% or more of the total pore volume of the catalyst.

16. The method for producing an alcohol according to claim 15 ,
wherein the hydrogenation of the fatty acid ester is conducted using a catalyst carrying a catalyst metal on a support,
wherein the catalyst contains one or more elements selected from the elements of group 9, group 10 and group 11 of the periodic table, the total pore volume of the catalyst is 0.05 mL/g or more, and the volume of pores with a pore size of 0.1 μm or more and 500 μm or less in the catalyst is 50% or more of the total pore volume.

17. A desulfurization method for desulfurization of sulfur from a fatty acid ester using a catalyst,
wherein the catalyst carries a catalyst metal on a support,
(a) the catalyst contains as the catalyst metal one or more elements selected from the elements of group 9, group 10 and group 11 of the periodic table,
(b) the total pore volume of the catalyst is 0.05 mL/g or more, and
(c) the volume of pores with a pore size of 0.1 μm or more and 500 μm or less is 50% or more of the total pore volume of the catalyst.

Assignees

• Kao Corp

Inventors

• Okada Nobuhiko
• Yamamoto Katsutoshi
• Homma Taichi
• Harima Kazuyuki

Classifications

• B01J37/0036

  Grinding · CPC title

• B01J37/18

  with gases containing free hydrogen · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C07C67/60 Primary

  by treatment giving rise to chemical modification (by chemisorption C07C67/56) · CPC title

• C07C29/149 Primary

  with hydrogen or hydrogen-containing gases · CPC title