Substrate with a partial metal multilayer, glazing unit and process

Patent metadata

Field	Value
Publication number	US-9809492-B2
Application number	US-201314646908-A
Country	US
Kind code	B2
Filing date	Nov 22, 2013
Priority date	Nov 23, 2012
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

The invention relates to a substrate ( 30 ) coated on one face ( 31 ) with a multilayer of thin films ( 34 ) comprising at least one metal functional layer ( 140 ) based on silver or made of silver and two antireflective coatings ( 120, 160 ), the said antireflective coatings each comprising at least one antireflective layer ( 124, 164 ), the said functional layer ( 140 ) being disposed between the two antireflective coatings ( 120, 160 ), characterized in that the said metal functional layer ( 140 ) is a discontinuous layer having a surface area occupation factor in the range between 50% and 98%, or even between 53% and 83%.

First claim

The invention claimed is:

1. A substrate comprising, on a face of the substrate, a multilayer of thin films comprising, in the following order from the face of the substrate:
a first antireflective coating comprising an antireflective layer;
a first metal functional layer comprising silver, wherein the first metal functional layer is a discontinuous layer having a surface area occupation factor in the range of 53% to 98% and is in the form of interconnected islands with uncovered regions between the islands; and
a second antireflective coating comprising an antireflective layer.

2. The substrate of claim 1 , wherein the first metal functional layer has a thickness e:
1.0≦e ≦4.5 nm, which is deposited on a layer comprising titanium dioxide TiO 2 ; or
1.0≦e ≦4.5 nm, which is deposited on a layer comprising zinc and tin oxide SnZnO x ;or
1.0≦e ≦5.0 nm, which is deposited on a layer comprising zinc oxide ZnO; or
1.0≦e ≦7.0 nm, which is deposited on a layer comprising silicon nitride Si 3 N 4 ; or
1.0≦e ≦5.0 nm, which is deposited on a layer comprising nickel.

3. The substrate of claim 1 , wherein the first antireflective coating comprises a medium index antireflective layer comprising a material having a refractive index in the range of from 1.8 to 2.2 at 550 nm.

4. The substrate of claim 1 , wherein the first antireflective coating comprises a high index antireflective layer comprising a material having a refractive index in the range of from 2.3 to 2.7 at 550 mu.

5. The substrate of claim 1 , wherein the second antireflective coating comprises a medium index antireflective layer comprising a material having a refractive index in the range of from 1.8 to 2.2 at 550 nm.

6. The substrate of claim 1 , wherein the second antireflective coating comprises a high index antireflective layer comprising a material having a refractive index in the range of from 2.3 to 2.7 at 550 nm.

7. The substrate of claim 1 , wherein the multilayer of thin films further comprises a second metal functional layer and a third antireflective coating comprising an antireflective layer such that the multilayer of thin films has the following configuration from the face of the substrate:
the first antireflective coating;
the first metallic functional layer;
the second antireflective coating;
the second metallic functional layer; and
the third antireflective coating,
wherein the second metal functional layer is a discontinuous layer having a surface area occupation factor in the range of 53% to 98% and is in the form of interconnected islands with uncovered regions between the islands.

8. The substrate of claim 7 , wherein the multilayer of thin films further comprises a third metal functional layer and a fourth antireflective coating comprising an antireflective layer such that the multilayer of thin films has the following configuration from the face of the substrate:
the first antireflective coating;
the first metallic functional layer;
the second antireflective coating;
the second metallic functional layer;
the third antireflective coating;
the third metallic functional layer; and
the fourth antireflective coating,
wherein the third metal functional layer is a discontinuous layer having a surface area occupation factor in the range of 53% to 98% and is in the form of interconnected islands with uncovered regions between the islands.

9. The substrate of claim 1 , wherein the multilayer of thin films further comprises a barrier undercoat comprising a thin layer comprising nickel or titanium having a physical thickness e′ such that 0.2 nm ≦e′≦2.5 nm,
wherein the barrier undercoat is in direct contact with the first metallic functional layer and disposed between the first metallic functional layer and the first antireflective coating.

10. The substrate of claim 1 , wherein a last layer of the multilayer of thin films, which is furthest from the face of the substrate, comprises an oxide comprising titanium dioxide or a mixed oxide of zinc and tin.

11. A multiple glazing unit, comprising at least two substrates which are held together by a chassis structure, said glazing unit forming a separation between an exterior space and an interior space, in which at least one gas separation interface is disposed between the two substrates, wherein one of the two substrates is the substrate of claim 1 .

12. A process, comprising:
depositing the first metal functional layer, the first antireflective coating, and the second antireflective coating, thereby forming the substrate of claim 1 .

13. The substrate of claim 7 , wherein the first antireflective coating and the second antireflective coating each comprise a medium index antireflective layer comprising a material having a refractive index in the range of from 1.8 to 2.2 at 550 nm.

14. The substrate of claim 7 , wherein the first antireflective coating and the second antireflective coating each comprise a high index antireflective layer comprising a material having a refractive index in the range of from 2.3 to 2.7 at 550 nm.

15. The substrate of claim 7 , wherein the second antireflective coating and the third antireflective coating each comprise a medium index antireflective layer comprising a material having a refractive index in the range of from 1.8 to 2.2 at 550 nm.

16. The substrate of claim 7 , wherein the second antireflective coating and the third antireflective coating each comprise a high index antireflective layer comprising a material having a refractive index in the range of from 2.3 to 2.7 at 550 nm.

17. The substrate of claim 1 , wherein the multilayer of thin films further comprises a barrier overcoat comprising a thin layer comprising nickel or titanium having a physical thickness e′ such that 0.2 nm ≦e′≦2.5 nm,
wherein the barrier overcoat is in direct contact with the first metallic functional layer and disposed between the first metallic functional layer and the second antireflective coating.

18. The substrate of claim 1 , where the first metallic layer has a surface area occupation factor in the range of 53-83%.

19. The substrate of claim 7 , wherein the first metallic functional layer and the second metal functional layer each have a surface area occupation factor in the range of 53-83%.

20. The substrate of claim 8 , wherein the first metallic functional layer, the second metal functional layer, and the third metallic functional layer each have a surface area occupation factor in the range of 53-83%.

Assignees

• Saint Gobain
• Centre Nat De La Rech Scient (C N R S )
• Centre Nat De La Rech Scient (C N R S)

Inventors

• Alzate Lina
• Dalmas Davy
• Barthel Etienne
• Nicolas David
• Georges Benoit

Classifications

• C03C2217/40

  Coatings comprising at least one inhomogeneous layer · CPC title

• C03C17/3613

  Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other · CPC title

• C03C17/36 Primary

  at least one coating being a metal · CPC title

• C03C17/366

  Low-emissivity or solar control coatings · CPC title

• Y10T428/24868

  Translucent outer layer · CPC title