Toner, image forming apparatus, image forming method, process cartridge, and developer

Patent metadata

Field	Value
Publication number	US-9804515-B2
Application number	US-201314422270-A
Country	US
Kind code	B2
Filing date	Aug 30, 2013
Priority date	Sep 10, 2012
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A toner of the present invention includes at least a colorant and a resin, has crystallinity CX or 20 or greater, and has a dynamic viscoelasticity characteristic in which a logarithmic value Log G′(50) of storage elastic modulus (Pa) at 50° C. is from 6.5 to 8.0 and a logarithmic value Log G′(65) of storage elastic modulus (Pa) at 65° C. is from 4.5 to 6.0, when the dynamic viscoelasticity characteristic is measured by temperature sweep from 40° C., at a frequency of 1 Hz, at a strain amount control of 0.1%, and at a temperature elevating rate of 2° C./min.

First claim

The invention claimed is:

1. A toner, comprising:
a colorant; and
a resin,
wherein:
the toner has crystallinity CX of 20 or greater, and has a dynamic viscoelasticity characteristic in which a logarithmic value log G′(50) of storage elastic modulus (Pa) at 50° C. is from 6.5 to 8.0, and a logarithmic value log G′(65) of storage elastic modulus (Pa) at 65° C. is from 4.5 to 6.0, where the dynamic viscoelasticity characteristic is measured by temperature sweep from 40° C., at a frequency of 1 Hz, at a strain amount control of 0.1%, and at a temperature elevating rate of 2° C./min; and
the toner has tan δ(50) of 0.1 to 0.4 at 50° C., and tan δ(65) of 0.4 to 2.0 at 65° C., where tan δ indicates loss tangent (loss coefficient) defined by a ratio G″/G′ between storage elastic modulus (G′) and loss elastic modulus (G″).

2. The toner according to claim 1 , wherein toner particles of the toner are formed by granulating the resin in a medium comprising water, an organic solvent, or both thereof.

3. The toner according to claim 1 , wherein the toner contains at least ethyl acetate in an amount of 1 μg/g to 30 μg/g.

4. The toner according to claim 1 , wherein the toner has a core-shell structure.

5. The toner according to claim 1 , wherein the toner contains at least a crystalline polyester resin.

6. The toner according to claim 1 , wherein the toner contains at least a modified polyester resin.

7. The toner according to claim 1 , wherein the toner has an average circularity E of from 0.93 to 0.99.

8. The toner according to claim 1 , wherein the toner has a circularity SF-1 of from 100 to 150, and a circularity SF-2 of from 100 to 140.

9. The toner according to claim 1 , wherein the toner has a weight-average particle size D4 of from 2 μm to 7 μm, and a ratio D4/Dn between the weight-average particle size D4 and a number-average particle size Dn is from 1.00 to 1.25.

10. An image forming apparatus, comprising:
a developing unit comprising a toner and configured to form a visible image with the toner; and
a fixing unit configured to fix the visible image on a recording medium by heat and pressure,
wherein:
the developing unit comprises a tandem developing system in which developing sub-units for at least four or more different developing colors are arranged in series, the tandem developing system has a system speed of 200 mm/sec to 3,000 mm/sec, and at least one of the developing sub-units contains the toner;
the fixing unit has a fixing medium with a surface pressure of 10 N/cm 2 to 3,000 N/cm 2 , and has a fixing nip time of 30 msec to 400 msec;
the toner is the toner according to claim 1 .

11. An image forming method, comprising:
performing development with a toner to form a visible image; and
fixing the visible image on a recording medium by heat and pressure,
wherein:
in the performing, the development is performed by a tandem developing system in which developing sub-units for at least four or more different developing colors are arranged in series, a system speed of the tandem developing system is from 200 mm/sec to 3,000 mm/sec, and at least one of the developing sub-units contains the toner;
in the fixing, a surface pressure of a fixing medium is from 10 N/cm 2 to 3,000 N/cm 2 , and a fixing nip time is from 30 msec to 400 msec; and
the toner is the toner according to claim 1 .

12. A process cartridge, comprising:
a latent image carrier; and
a developing unit containing at least a toner,
wherein the process cartridge supports the latent image carrier and the developing unit integrally and is attachable to and detachable from an image forming apparatus body, and
wherein the toner is the toner according to claim 1 .

13. A two-component developer, comprising:
the toner according to claim 1 ; and
a carrier having a magnetic property.

Assignees

• Sugiura Hideki
• Nakayama Shinya
• Sawada Toyoshi
• Ricoh Co Ltd

Inventors

• Sugiura Hideki
• Nakayama Shinya
• Sawada Toyoshi

Classifications

• G03G2215/0607

  two-component · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/093

  Encapsulated toner particles · CPC title

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/08755

  Polyesters · CPC title