Ferrous disintegrable powder compact, method of making and article of same

Patent metadata

Field	Value
Publication number	US-9803439-B2
Application number	US-201313794957-A
Country	US
Kind code	B2
Filing date	Mar 12, 2013
Priority date	Mar 12, 2013
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A disintegrable powder compact includes a matrix; a plurality of dispersed particles including a particle core material dispersed in the matrix; a ferrous alloy including carbon disposed in one of the matrix or particle core material; and a secondary element disposed in the other of the matrix or particle core material, the matrix and the plurality of dispersed particles having different standard electrode potentials. A process for preparing a disintegrable powder compact includes combining a primary particle including a ferrous alloy that includes carbon and a secondary particle to form a composition; compacting the composition to form a preform; and sintering the preform by forming a matrix, wherein the dispersed particles are dispersed in the matrix, the disintegrable powder compact is configured to disintegrate in response to contact with a disintegration fluid, and the primary particle and secondary particle have different standard electrode potentials.

First claim

What is claimed is:

1. A sintered disintegrable powder compact comprising:
a matrix comprising a matrix material, the matrix material comprising aluminum, calcium, cobalt, copper, magnesium, manganese, molybdenum, nickel, silicon, zinc, a rare earth element, or a combination thereof;
a plurality of dispersed particles comprising a particle core material dispersed in the matrix, the particle core material comprising a ferrous alloy which comprises carbon, the dispersed particles having a size of 50 nm to 800 μm, and the matrix being continuous and comprising a network that substantially surrounds the dispersed particles;
the matrix and the plurality of dispersed particles having different standard electrode potentials,
wherein the sintered disintegrable powder compact is free of metal nitrides, and
the sintered disintegrable powder compact is configured to disintegrate in response to contact with a disintegration fluid.

2. The sintered disintegrable powder compact of claim 1 , wherein the dispersed particles further comprise a coating disposed on the particle core material; the dispersed particles further comprising the coating being dispersed throughout the matrix;
the matrix and coating have different standard electrode potentials; and
the coating and particle core materials are different from each other.

3. The sintered disintegrable powder compact of claim 2 , wherein the coating completely surrounds the particle core material and blocks contact between the particle core material and the matrix.

4. The sintered disintegrable powder compact of claim 2 , wherein the coating comprises an aluminum metal, a calcium metal, a cobalt metal, a copper metal, an iron metal, a magnesium metal, a manganese metal, a molybdenum metal, a nickel metal, silicon, a zinc metal, a rare earth metal, or a combination thereof.

5. The sintered disintegrable powder compact of claim 1 , wherein the ferrous alloy is alloy steel, carbon steel, cast iron, stainless steel, tool steel, or a combination thereof.

6. The sintered disintegrable powder compact of claim 1 , wherein the ferrous alloy further comprises aluminum, bismuth, boron, cobalt, copper, chromium, lead, manganese, molybdenum, nickel, niobium, nitrogen, phosphorous, selenium, silicon, sulfur, tantalum, tellurium, titanium, tungsten, vanadium, zirconium, a rare earth element, or a combination thereof.

7. The sintered disintegrable powder compact of claim 1 , further comprising a plurality of secondary particles dispersed in the matrix,
wherein the secondary particles are different from the dispersed particles and the matrix.

8. The sintered disintegrable powder compact of claim 7 , wherein the secondary particles comprise aluminum, calcium, cobalt, copper, iron, magnesium, manganese, molybdenum, nickel, silicon, tungsten, zinc, a rare earth element, ferrous alloy, an oxide thereof, nitride thereof, carbide thereof, intermetallic compound thereof, cermet thereof, or a combination thereof.

9. The sintered disintegrable powder compact of claim 1 , wherein the ferrous alloy is present in an amount from 5 wt % to 95 wt %, based on a weight of the sintered disintegrable powder compact, and the matrix material is present in an amount from 5 wt % to 95 wt %, based on a weight of the sintered disintegrable powder compact.

10. The sintered disintegrable powder compact of claim 1 , wherein the dispersed particles have a spherical or spheroidal shape.

11. The sintered disintegrable powder compact of claim 1 , wherein a hollow space is disposed in at least a portion of the plurality of the dispersed particles.

12. The sintered disintegrable powder compact of claim 1 , wherein the sintered disintegrable powder compact is a disintegrable downhole tool comprising a slip, and the slip comprises a wicker disposed on a substrate.

13. The sintered disintegrable powder compact of claim 1 , wherein the matrix material comprises magnesium and an alloying element, the alloying element being present in an amount from 0.1 wt % to 15 wt % based on the weight of the matrix material and the balance of the weight being magnesium.

14. The sintered disintegrable powder compact of claim 1 , wherein the sintered disintegrable powder compact has a compressive strength from 15 kilopounds per square inch to 150 kilopounds per square inch.

15. The sintered disintegrable powder compact of claim 1 , wherein the particle core material comprises a nanostructured material having an average grain size of less than 100 nm.

16. The sintered disintegrable powder compact of claim 1 , wherein dispersed particles are present in an amount of 70 wt. % to 95 wt. %, and the matrix material is present in an amount of 10 wt. % to 30 wt. %, each based on the total weight of the sintered disintegrable powder compact.

17. The sintered disintegrable powder compact of claim 1 , wherein an average distance between adjacent dispersed particles is 1 micron to 75 microns.

18. A process for preparing a sintered disintegrable powder compact, the process comprising:
combining:
a primary particle comprising a ferrous alloy which comprises carbon; and
a secondary particle to form a composition;

compacting the composition to form a preform; and
sintering the preform to form the sintered disintegrable powder compact by
forming a matrix from the secondary particle, the matrix comprising a matrix material, the matrix material comprising aluminum, calcium, cobalt, copper, magnesium, manganese, molybdenum, nickel, silicon, zinc, a rare earth element, or a combination thereof; and
forming a plurality of dispersed particles from the primary particle, the dispersed particles comprising a particle core material dispersed in the matrix, the particle core material comprising the ferrous alloy which comprises carbon, the dispersed particles having a size of 50 nm to 800 nm, and the matrix being continuous and comprising a network that substantially surrounds the dispersed particles;

wherein the sintered disintegrable powder compact is configured to disintegrate in response to contact with a disintegration fluid,
the primary particle and secondary particle have different standard electrode potentials; and
the matrix and the plurality of dispersed particles have different standard electrode potentials.

19. The process of claim 18 , further comprising coating the primary particle with an element comprising aluminum, calcium, cobalt, copper, iron, magnesium, manganese, molybdenum, nickel, silicon, zinc, a rare earth element, or a combination thereof prior to combining the primary particle and the secondary particle.

20. A sintered disintegrable powder compact comprising:
a matrix, the matrix comprising a ferrous alloy which comprises carbon;
a plurality of dispersed particles comprising a particle core material dispersed throughout the matrix, the particle core material comprising aluminum, calcium, cobalt, copper, iron, magnesium, manganese, molybdenum, nickel, silicon, zinc, a rare earth element, or a combination thereof;
wherein the matrix and the plurality of dispersed particles have different standard electrode potentials,
the dispersed particles are not a carbide; and
the sintered disintegrable powder compact is free of metal nitrides.

Assignees

• Xu Zhiyue
• Zhang Zhihui
• Xu Yingqing
• Baker Hughes

Inventors

• Xu Zhiyue
• Zhang Zhihui
• Xu Yingqing

Classifications

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• C22C33/02 Primary

  by powder metallurgy · CPC title

• B22F3/12

  Both compacting and sintering (by forging B22F3/17) · CPC title

• B22F5/003

  Articles made for being fractured or separated into parts · CPC title

• E21B29/00 Primary

  Cutting or destroying pipes, packers, plugs or wire lines, located in boreholes or wells, e.g. cutting of damaged pipes, of windows; Deforming of pipes in boreholes or wells; Reconditioning of well casings while in the ground · CPC title