High temperature steam electrolysis facility (HTSE) with allothermal hydrogen production

Patent metadata

Field	Value
Publication number	US-9803290-B2
Application number	US-201314371283-A
Country	US
Kind code	B2
Filing date	Jan 9, 2013
Priority date	Jan 9, 2012
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A high temperature steam electrolysis or fuel cell electric power generating facility, including at least two electrochemical reactors fluidly connected in series to each other by their cathode compartment(s). At least one heat exchanger is arranged between two reactors in series, a primary circuit of the heat exchanger being connected to an external heat source configured to provide heat to fluid(s) at an outlet of an upstream reactor prior to be introduced at an inlet of a downstream reactor.

First claim

The invention claimed is:

1. A high temperature steam electrolysis or fuel cell electric power generation facility, comprising:
at least two electrochemical reactors;
wherein each electrochemical reactor comprises at least one electrochemical unit cell, each cell including a cathode, an anode, and an electrolyte interposed between the cathode and the anode, at least one connecting element including at least one compartment for gas flow to the cathode, being arranged in electrical contact with the cathode of the unit cell, and at least one connecting element including at least one compartment for gas flow to the anode being arranged in electrical contact with the anode of the unit cell, and
wherein both electrochemical reactors are fluidly connected in series to each other at least by one gas flow compartment,
and further comprising at least one heat exchanger including a circuit fluidly connected in series to an outlet of one of the gas flow compartments of one of both reactors and to an inlet of one of the gas flow compartments of the other one of both reactors and including another circuit fluidly connected to a heat source external to the reactors.

2. The high temperature steam electrolysis or fuel cell electric power generation facility according to claim 1 , wherein each reactor comprises a stack of a plurality of electrochemical unit cells, an interconnecting plate being arranged between two adjacent unit cells and an electrical contact with an electrode of one of both unit cells and an electrode of the other one of both unit cells, the interconnecting plate including at least one cathode compartment and at least one anode compartment for gas flow to the cathode and anode respectively.

3. The high temperature steam electrolysis or fuel cell electric power generation facility according to claim 1 , wherein each heat exchanger is fluidly connected in series to the outlet of both two gas flow compartments of one of both reactors and to the inlet of the two gas flow compartments of the other one of both reactors.

4. The high temperature steam electrolysis or fuel cell electric power generation facility according to claim 1 , wherein each heat exchanger is fluidly connected in series to the outlet of a single one of both gas flow compartments of one of both reactors and to the inlet of a single one of the gas flow compartments of the other one of both reactors, the outlet of the other compartment of each reactor being connected to an independent circuit.

5. The high temperature steam electrolysis or fuel cell electric power generation facility according to claim 1 , further comprising at least, in its downstream part, two reactors fluidly connected in parallel to each other.

6. A high temperature steam electrolysis method implemented by a facility according to claim 1 , comprising:
a) operating in allothermal mode at least in the electrolysis reactors, a most upstream of the facility with a temperature gradient between a fluid inlet and outlet of one of said reactors restricted to a predetermined value ΔT;
b) generating heat by the external heat source to provide a temperature increase in the order of the predetermined value ΔT at least to the fluid exiting from the cathode compartment(s) of a first reactor prior to be introduced into those of the second reactor, provided in series, downstream of the first reactor.

7. The high temperature steam electrolysis method according to claim 6 , wherein the heat gradient value ΔT predetermined in a) is at most equal to 100 K, or to 50 K.

8. The high temperature steam electrolysis method according to claim 6 , wherein a) is performed to have all the electrolysis reactors operating in allothermal mode.

9. The high temperature steam electrolysis method according to claim 6 , wherein a) is performed to have a part of the reactors, downstream or most downstream, operating in autothermal mode.

10. The high temperature steam electrolysis method according to claim 6 , wherein in each electrolysis reactor, a fluid flow is carried out in the cathode compartment(s) in co-current with that of the fluid in the anode compartment(s).

11. The high temperature steam electrolysis method according to claim 6 , wherein in each electrolysis reactor, a fluid flow is carried out in the cathode compartment(s) in counter-current with that of the fluid in the anode compartment(s).

12. The high temperature steam electrolysis method according to claim 6 , wherein in each electrolysis reactor, a fluid is carried out in the cathode compartment(s) in cross-current with that of the fluid in the anode compartment(s).

13. The high temperature steam electrolysis according to claim 10 , wherein in each electrolysis reactor, a fluid flow is further carried out in co-current with that of the fluid between consecutive reactors.

14. The high temperature steam electrolysis method according to claim 10 , wherein in each electrolysis reactor, a fluid flow is further carried out in counter-current with that of the fluid between consecutive reactors.

15. The high temperature steam electrolysis method according to claim 6 , wherein a discharge of oxygen produced by each electrolysis reactor is carried out.

Assignees

• Commissariat A L'Energie Atomique Et Aux Ene Alt
• Commissariat L Energie Atomique Et Aux Energies Alternatives

Inventors

• Bertier Luc

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• H01M8/04708

  of fuel cell reactants · CPC title

• C25B9/00

  Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• H01M8/04716

  of fuel cell exhausts · CPC title