Method for hot-dip coating of a steel flat product

Patent metadata

Field	Value
Publication number	US-9803270-B2
Application number	US-201214377337-A
Country	US
Kind code	B2
Filing date	Dec 13, 2012
Priority date	Feb 8, 2012
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A method which allows process-stable hot-dip coating of Ni-alloy steel flat products in a cost- and resource-effective manner, including the following steps: a) provision of a steel flat product obtained by cold- or hot-rolling; b) within 1-30 s, heating the steel flat product to a holding temperature between 700 and 1100° C., under a heating atmosphere of N2; c) holding the steel flat product at the holding temperature for a holding duration of 10-120 s under a holding atmosphere of N2; d) cooling the steel flat product from the holding temperature to a strip inlet temperature of 430-800° C.; and e) passing the steel flat product through an inlet zone, in which an inert or reducing inlet atmosphere predominates, and passing the steel flat product through a melt bath, wherein TP 1 >TP 2 >TP 4.

First claim

The invention claimed is:

1. A method for hot-dip coating of a steel flat product with a metallic protective coating, comprising:
a) providing a steel flat product obtained by cold- or hot-rolling, which is produced from a steel containing at least 2.0 wt. % Ni and at least 5.0 wt. % Cr;
b) heating of the steel flat product, for a period of 1-30 s, to a holding temperature between 700 and 1100° C., wherein the heating takes place under a heating atmosphere, wherein a dew point of the heating atmosphere is −15° C. to +30° C. and the heating atmosphere contains N 2 and unavoidable contaminants, and optionally one or more of the following constituents by volume:
H 2 : 1-50%,
CO: 0.1-2.0%,
CO 2 : 5.0-15.0%;

c) holding the heated steel flat product at the holding temperature for a holding duration of 10-120 s under a holding atmosphere which consists of N 2 and unavoidable contaminants, 1.0-50.0 vol. % H 2 and up to 1.0 vol. % O 2 , and wherein a dew point of the holding atmosphere is −30° C. to 0° C.;
d) cooling the steel flat product from the holding temperature to a strip inlet temperature of 430-800° C.;
e) passing the steel flat product through an inlet zone, in which the steel flat product is held under an inert or reducing inlet atmosphere until entry into a melt bath, and subsequent passage through the melt bath in which the steel flat product is hot-dip coated with a metallic coating;
wherein the dew point of the heating atmosphere is higher than the dew point of the holding atmosphere, and the dew point of the holding atmosphere is higher than the dew point of the inlet atmosphere.

2. The method according to claim 1 , wherein the holding temperature is 700 to 850° C.

3. The method according to claim 1 , wherein the heating atmosphere further contains 1.0-5.0 vol. % H 2 .

4. The method according to claim 1 , wherein the heating is carried out in a directly heated furnace zone and the heating atmosphere further contains 1-50 vol. % H 2 , 0.1-2.0 vol. % CO and 5.0-15.0 vol. % CO 2 .

5. The method according to claim 1 , wherein the H 2 content of the holding atmosphere is 1.0-5.0 vol. %.

6. The method according to claim 1 , wherein the dew point of the holding atmosphere is −30° C. to −10° C.

7. The method according to claim 1 , wherein the O 2 content of the holding atmosphere is maximum 0.1 vol. %.

8. The method according to claim 1 , wherein following cooling to the strip inlet temperature, the steel flat product undergoes an overageing treatment in which the steel flat product is held for 1-30 s under an overageing atmosphere at the strip inlet temperature, that the overageing atmosphere contains N 2 and unavoidable contaminants, and optionally 1-50 vol. % H 2 , and wherein a dew point of the overageing atmosphere is −50° C. to −25° C.

9. The method according to claim 8 , wherein the H 2 content of the overageing atmosphere is 1.0-5.0 vol. %.

10. The method according to claim 8 , wherein the dew point of the heating atmosphere is greater than the dew point of the holding atmosphere is greater than the dew point of the overageing atmosphere is greater than or equal to the dew point of the inlet atmosphere.

11. The method according to claim 1 , wherein the inlet atmosphere consists of N 2 and unavoidable contaminants and optionally 1.0-50.0 vol. % H 2 , and wherein a dew point of the inlet atmosphere is −80° C. to −25° C.

12. The method according to claim 1 , wherein the steel flat product is immersed in the melt bath for 1-10 s.

13. The method according to claim 1 , wherein the steel from which the steel flat product is produced contains by weight:
Cr: 5.0-30.0%
Ni: 2.0-30.0%
Mn: ≦6.0%
Mo: ≦5.0%
Si: ≦2.0%
Cu: ≦2.0%
Ti: ≦1.0%
Nb: ≦1.0%
V: ≦0.5%
N: ≦0.2%
Al: ≦2.0%
C: ≦0.5%, and

the balance being iron and unavoidable contaminants.

Assignees

• Thyssenkrupp Steel Europe Ag
• Outokumpu Nirosta Gmbh

Inventors

• Blumenau Marc
• Gusek Christopher
• Jindra Fred
• Schoenenberg Rudolf
• Krautschick Hans-Joachim

Classifications

• B32B15/012

  one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy · CPC title

• C22C38/40

  with nickel · CPC title

• C22C38/58 Primary

  with more than 1.5% by weight of manganese · CPC title

• C23C2/40

  Plates; Strips · CPC title

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title