Moderately alkaline cleaning compositions for proteinaceous and fatty soil removal at low temperatures

Patent metadata

Field	Value
Publication number	US-9803160-B2
Application number	US-201514750188-A
Country	US
Kind code	B2
Filing date	Jun 25, 2015
Priority date	Oct 12, 2011
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

The present invention comprises chlorinated and non-chlorinated alkaline cleaning compositions for removal of proteinaceous and fatty soils at low temperature, i.e. less than 120° F., with little or no deleterious affect on cleaning performance. According to the invention, applicants have found that adding additional alkalinity makes protein removal more difficult and reducing the amount of alkalinity actually improves performance. According to the invention optimized combinations of chlorine and alkalinity components for low temperature cleaning as well as a surfactant system optimized for low temperature fatty soil removal are disclosed.

First claim

What is claimed is:

1. A method of removing proteinaceous soils or proteinaceous and fatty soils from a surface comprising:
contacting said surface with an alkaline and chlorine cleaning composition comprising an amine oxide surfactant that has at least 50% of the carbon chain lengths of 14 or greater at a temperature of less than 100° F.; an active alkalinity source; and a source of chlorine, wherein the chlorine is present at about 25 ppm to 1500 ppm, and wherein said proteineaceous soils or proteinaceous and fatty soils are removed from said surface, wherein chlorine and said active alkalinity source are in a ratio of greater than 3:1 on a weight basis.

2. A method of removing proteinaceous soils and fatty soils comprising:
providing a cleaning composition comprising:
a source of chlorine, wherein the chlorine is present at about 25 ppm to 1500 ppm;
a source of active alkalinity, wherein the active alkalinity is present at about 25 ppm to 5000 ppm; and
an amine oxide surfactant that has at least 50% of the carbon chain lengths of 14 or greater and has the following formula:

wherein the arrow is a semi-polar bond, R 1 is a long alkyl radical with 14 to 24 carbon atoms; R 2 and R 3 are alkyl or hydroxyalkyl of 1-3 carbon atoms or a mixture thereof, and wherein R 4 is an alkaline or a hydroxyalkylene group containing 2 to 3 carbon atoms, and n is between 0 and 20, wherein said chlorine and active alkalinity source are in a ratio of greater than 3:1 on a percent weight basis; and
contacting the surface with the cleaning composition at a temperature of less than 100° F., wherein the proteinaceous and fatty soils are removed from the surface.

3. The method of claim 2 wherein said chlorine and said active alkalinity source are in a ratio of greater than 5:1 on a weight basis.

4. A method of removing proteinaceous soils or proteinaceous and fatty soils from a surface comprising:
providing a cleaning composition comprising:
from about 25 ppm to about 1650 ppm of an active alkalinity source;
from about 75 ppm to 1500 ppm of an active chlorine source; and
from about 100 ppm to about 2,000 ppm of a tertiary amine oxide surfactant that has at least 50% of the alkyl carbon chain lengths of 14 or greater; and

contacting said surface with said cleaning composition at a temperature of 80° F. or lower,
wherein the proteinaceous soil or proteinaceous and fatty soils are removed from the surface, wherein chlorine and said active alkalinity source are in a ratio of greater than 3:1 on a weight basis.

5. The method of claim 2 wherein the temperature is 50° F. or lower.

6. The method of claim 4 , wherein the tertiary amine oxide surfactant is a C14 amine oxide.

7. The method of claim 4 , wherein said chlorine and said active alkalinity source are in a ratio of greater than 5:1 on a weight basis.

8. The method of claim 4 , wherein said active alkalinity source is sodium hydroxide and said active chlorine source is sodium hypochlorite.

Assignees

• Ecolab Usa Inc

Inventors

• Sun Xin
• Gandara Jacquilyne
• Ryther Robert J
• Mohs Thomas R
• Cummings Walter D

Classifications

• C11D7/3209

  Amines or imines with one to four nitrogen atoms; Quaternized amines · CPC title

• C11D3/3956

  Liquid compositions · CPC title

• C11D3/30

  Amines; Substituted amines {; Quaternized amines} · CPC title

• C11D3/3955

  Organic bleaching agents (C11D3/3951 takes precedence) · CPC title

• C11D7/3263

  Amides or imides · CPC title