Aqueous dispersion of a copolymer

Patent metadata

Field	Value
Publication number	US-9803103-B2
Application number	US-201414905595-A
Country	US
Kind code	B2
Filing date	Jun 4, 2014
Priority date	Jul 17, 2013
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

An aqueous dispersion containing at least one copolymer, the copolymer being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane, where a water-soluble initiator is used, the metered addition of the olefinically unsaturated monomers is effected in such a way that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers, in the reaction solution is not exceeded over the entire duration of the reaction, and the mixture of the olefinically unsaturated monomers contains at least one polyolefinically unsaturated monomer.

First claim

The invention claimed is:

1. An aqueous dispersion, comprising at least one copolymer obtained by
(i) initially charging an aqueous dispersion of at least one polyurethane, and then
(ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane,
wherein:
the polymerizing occurs in the presence of a water-soluble initiator;
a metered addition of the olefinically unsaturated monomers occurs such that a concentration of 6.0% by weight, based on a total amount of the olefinically unsaturated monomers, in a reaction solution of the polymerizing is not exceeded during the entire duration of the polymerizing; and
the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer.

2. The aqueous dispersion as claimed in claim 1 , wherein the metered addition of the olefinically unsaturated monomers occurs such that a concentration of 5.0% by weight, based on the total amount of the olefinically unsaturated monomers, in the reaction solution is not exceeded during the entire duration of the polymerizing.

3. The aqueous dispersion as claimed in claim 2 , wherein the metered addition of the olefinically unsaturated monomers occurs such that a concentration of 4.0% by weight, based on the total amount of olefinically unsaturated monomers, in the reaction solution is not exceeded during the entire duration of the polymerizing.

4. The aqueous dispersion of claim 1 , wherein the mixture of the olefinically unsaturated monomers comprises 0.1 to 6.0 mol % of the at least one polyolefinically unsaturated monomer.

5. The aqueous dispersion of claim 1 , wherein the mixture of the olefinically unsaturated monomers comprises 0.1 to 2.0 mol % of the at least one polyolefinically unsaturated monomer.

6. The aqueous dispersion of claim 1 , wherein the mixture of the olefinically unsaturated monomers comprises 0.1 to 6.0 mol % of allyl methacrylate and does not contain any further polyolefinically unsaturated monomers.

7. The aqueous dispersion of claim 1 , wherein the mixture of the olefinically unsaturated monomers comprises 0.1 to 2.0 mol % of allyl methacrylate and does not contain any further polyolefinically unsaturated monomers.

8. The aqueous dispersion of claim 1 , wherein the mixture of olefinically unsaturated monomers comprises less than 10.0% by weight of vinylaromatic monomers, based on the total amount of olefinically unsaturated monomers.

9. The aqueous dispersion of claim 1 , wherein the mixture of olefinically unsaturated monomers comprises less than 5.0% by weight of vinylaromatic monomers, based on the total amount of olefinically unsaturated monomers.

10. The aqueous dispersion of claim 1 , wherein the mixture of olefinically unsaturated monomers does not contain any vinylaromatic monomers.

11. The aqueous dispersion of claim 1 , wherein the aqueous dispersion has a gel content of 40 to 90% by weight, based on solids in the dispersion.

12. The aqueous dispersion of claim 1 , wherein the copolymer comprises
(A) a core comprising at least one polyurethane, and
(B) a shell comprising at least one polymer obtained by polymerization of olefinically unsaturated monomers.

13. A coating material, comprising the aqueous dispersion of claim 1 .

14. A waterborne basecoat, comprising the aqueous dispersion of claim 1 .

15. A process for producing a multicoat color and/or effect paint system, the process comprising
(i) applying a pigmented waterborne basecoat to a substrate,
(ii) forming a polymer film from the pigmented waterborne basecoat applied in stage (i),
(iii) applying a clearcoat layer to the polymer film as a basecoat layer, and then
(iv) curing the basecoat layer together with the clearcoat layer,
wherein the pigmented waterborne basecoat comprises the aqueous dispersion of claim 1 .

16. The process of claim 15 , wherein the substrate is an automobile body, a plastic part for installation of an automobile body, or both.

17. A process for producing the aqueous dispersion of claim 1 , the process comprising
(i) initially charging an aqueous dispersion of at least one polyurethane, and then
(ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane,
wherein:
the polymerizing occurs in the presence of a water-soluble initiator;
a metered addition of the olefinically unsaturated monomers occurs such that a concentration of 6.0% by weight, based on a total amount of the olefinically unsaturated monomers, in a reaction solution of the polymerizing is not exceeded during the entire duration of the polymerizing; and
the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer.

Assignees

• Basf Coatings Gmbh
• BASF Coating GmbH

Inventors

• Reuter Hardy
• Steinmetz Bernhard
• Blohm Matthias
• Teichmann Carsten
• Göb Bianca

Classifications

• C08F290/067

  Polyurethanes; Polyureas · CPC title

• C08G18/765

  alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring · CPC title

• C09D151/08 Primary

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08G18/8141

  masked · CPC title

• C09D175/06

  from polyesters · CPC title