Polypropylene-asphaltene composite and methods thereof

Patent metadata

Field	Value
Publication number	US-9803075-B2
Application number	US-201514980652-A
Country	US
Kind code	B2
Filing date	Dec 28, 2015
Priority date	Dec 28, 2015
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A composite comprising polypropylene and a filler, which comprises asphaltenes extracted from Arabian Heavy crude oil. The composite comprises 90-98 wt % of the polypropylene polymer and 2 wt % to less than 10 wt % of the filler, where the weight percentages are based on a total weight of the composite. A melt-blending method is used to prepare the composites. A material comprising the composite is disclosed.

First claim

The invention claimed is:

1. A polypropylene-asphaltene composite, comprising:
a polypropylene polymer in an amount ranging from 85-98 wt %, and
a filler in an amount ranging from 2 wt % to less than 10 wt %, wherein the filler is an asphaltene and the asphaltene is the only filler present,
wherein the weight percentages are based on a total weight of the composite.

2. The composite of claim 1 , consisting essentially of:
the polypropylene polymer in an amount ranging from about 90-98 wt %, and
the filler in an amount ranging from 2 wt % to less than 10 wt %, wherein the filler is an asphaltene and the asphaltene is the only filler present,
wherein the weight percentages are based on a total weight of the composite.

3. The composite of claim 1 , consisting of:
the polypropylene polymer in an amount ranging from about 90-98 wt %, and
the filler in an amount ranging from 2 wt % to less than 10 wt %, wherein the filler is an asphaltene and the asphaltene is the only filler present,
wherein the weight percentages are based on a total weight of the composite.

4. The composite of claim 1 , wherein asphaltene is present in an amount ranging from 2 wt % to 7.5 wt % of the total weight of the composite.

5. The composite of claim 1 , wherein asphaltene is present in an amount ranging from 2 wt % to 5 wt % of the total weight of the composite.

6. The composite of claim 1 , wherein the composite is in the form of a particle with a largest average diameter ranging from 0.5-5 μm.

7. The composite of claim 1 , which has a peak melting temperature in a range of 165-175° C. and a degree of crystallinity in a range of more than 35% to 40%.

8. The composite of claim 1 , wherein the composite has a tensile strength ranging from 22-30 MPa.

9. The composite of claim 1 , wherein the composite has an elastic modulus ranging from 520-710 MPa.

10. The composite of claim 1 , wherein the asphaltene is extracted from Arabian Heavy crude oil.

11. The composite of claim 1 , wherein the asphaltene comprises carbon atoms in an amount ranging from 83-84 wt %, hydrogen atoms in an amount ranging from 8.2-8.4 wt %, nickel in an amount ranging from 18-20 ppm and vanadium in an amount ranging from 59-61 ppm, where the weight percentages and ppm levels are based on a total weight of the asphaltene, and the asphaltene has an average molecular weight in a range of 1800-1900 Daltons.

12. A method of preparing the polypropylene-asphaltene composite of claim 1 , comprising:
melting a polypropylene polymer to obtain a molten polymer,
blending the molten polymer with a filler to obtain a blended mixture, and
hot pressing the blended mixture to obtain the composite,
wherein the polypropylene polymer is present in an amount ranging from 85-98 wt %, the filler is present in an amount ranging from 2 wt % to less than 10 wt %, the weight percentages are based on a total weight of the composite, and the filler is an asphaltene, which is the only filler present.

13. The method of claim 12 , wherein the blending is performed at a rotor speed of 50 to 100 rpm and at a temperature ranging from 180-210° C.

14. The method of claim 12 , wherein the hot pressing is performed at a temperature ranging from 180-210° C. and a pressure ranging from 8-20 MPa.

15. The method of claim 12 , wherein the composite is in the form of a particle with a largest average diameter ranging from 0.5-5 μm.

16. The method of claim 12 , wherein asphaltene is present in an amount ranging from 2 wt % to less than 10 wt % of the total weight of the composite.

17. The method of claim 12 , wherein the asphaltene is derived from Arabian Heavy crude oil.

18. A material comprising a polypropylene-asphaltene composite, wherein the material is employed in a packaging material, a textile or both, and the polypropylene-asphaltene composite comprises:
a polypropylene polymer in an amount ranging from 85-98 wt %, and
a filler in an amount ranging from 2 wt % to less than 10 wt %, wherein the filler is an asphaltene and the asphaltene is the only filler present,
wherein the weight percentages are based on a total weight of the composite.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Siddiqui Mohammad N

Classifications

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title