Melt polymerization polycarbonate quenching

Patent metadata

Field	Value
Publication number	US-9803049-B2
Application number	US-201515113548-A
Country	US
Kind code	B2
Filing date	Mar 25, 2015
Priority date	Mar 27, 2014
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

In an embodiment, a melt polymerization process comprises melt polymerizing reactants in at least two polymerization units, in the presence of a catalyst composition to form polymerized polycarbonate; adding a quencher composition comprising one or both of a liquid quencher composition and a solid quencher composition; mixing the quencher composition with the polymerized polycarbonate for a period of time of greater than or equal to 5 seconds prior to the addition to the polymerized polycarbonate of any additives having a reactive OH group or reactive ester group; directing the polymerized polycarbonate to an extruder; and directing an additive to the extruder.

First claim

I claim:

1. A melt polymerization process comprising:
melt polymerizing reactants in at least two polymerization units, in the presence of a catalyst composition to form polymerized polycarbonate, wherein the catalyst composition comprises a catalyst comprising a source of one or both of alkali and alkaline earth metal ions;
adding a liquid quencher composition by a method comprising
combining a liquid carrier and a quencher in a quencher vessel to form the liquid quencher composition and adding the liquid quencher composition to the polymerized polycarbonate at a pressure of greater than or equal to 2 bars; wherein the liquid carrier is free of water and phenol;
mixing the quencher composition with the polymerized polycarbonate for a period of time of greater than or equal to 5 seconds prior to the addition to the polymerized polycarbonate of any additives having a reactive OH group or reactive ester group;
filtering the polymerized polycarbonate;
directing the polymerized polycarbonate to an extruder;
directing an anthraquinone colorant, a phenolic antioxidant, a UV absorber, a release agent, a flame retardant, or a combination comprising one or more of the foregoing to the extruder; and
adding an anti-drip agent.

2. The process of claim 1 , wherein the liquid carrier comprises diarylcarbonate, bisphenol A, polycarbonate oligomers, bisphenol A derivatives, propylene carbonate, xylene, toluene, benzene, ethylbenzene, anisole, chlorobenzene, acetone, or a combination comprising one or more of the foregoing.

3. The process of claim 1 , further comprising pelletizing the polymerized polycarbonate prior to directing the polymerized polycarbonate to the extruder.

4. The process of claim 1 , further comprising adding a solid quencher composition.

5. The process of claim 1 , wherein the quencher composition comprises 1 to 10 ppm alkyl tosylate, based upon 100 parts of the polymerized polycarbonate and/or 1 to 10 ppm of a sulfonic acid ester, based upon 100 parts of the polymerized polycarbonate; and/or 1 to 10 ppm phosphorous acid, based upon 100 parts of the polymerized polycarbonate.

6. The process of claim 1 , wherein the quencher comprises a phosphorous acid compound, and wherein the phosphorous acid compound comprises a phosphorous acid monoester, a phosphorous acid diester, a phosphorous acid triester, a phosphinic ester, an organic phosphonite; a phosphoric ester, a phosphonic ester, or a combination comprising one or more of the foregoing.

7. The process of claim 1 , wherein the quencher is free of a phosphorous acid quencher.

8. The process of claim 1 , wherein the phenolic antioxidant comprises 2,6-di-t-butyl-p-cresol, 2,6-di-t-butyl-p-anisole, 2,6-di-t-butyl-4-ethyl phenol, 2,2′-methylenebis(6-t-butyl-p-cresol), 2,2′-methylenebis-(4-ethyl-6-t-butyl phenol), 4,4′-methylenebis(6-t-butyl-o-cresol), 4,4′-butylidenebis(6-t-butyl-m-cresol), tetrakis-[methylene-3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionate]methane, 4,4′-thiobis(6-t-butyl-m-cresol), stearyl-β-(3,5-di-t-butyl-4-hydroxyphenyl) propionate, 1,3,5-trimethyl-2,4,6-tris (3,5-di-t-butyl-4-hydroxybenzyl)benzene, 1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenyl) butane, triethylene glycol-bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate], tetrakis-[methylene-3-(3′,5′-di-t-butyl-4′-hydroxyphenyl)propionate]methane, stearyl-β-(3,5-di-t-butyl-4-hydroxyphenyl) propionate, and triethylene glycol-bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl) propionate, 3,5-di-t-butyl-4-hydroxybenzylphosphonate-diethyl ester, and bis(ethyl-3,5-di-t-butyl-4-hydroxybenzylphosphonate)calcium, or a combination comprising one or more of the foregoing.

9. The process of claim 1 , wherein the UV absorber comprises 2-(5-methyl-2-hydroxyphenyl)-2H-benzotriazole, 2-[2-hydroxy-3,5-bis(alpha, alpha dimethylbenzyl)phenyl]-2H-benzotriazole, 2-(2′-hydroxy-5′-t-octylphenyl) benzotriazole, 2,2-methylene bis [4-(1,1,3,3-tetramethylene butyl)-6-(2H-benzotriazole-2-yl) phenol], 2-hydroxy-4-octoxybenzophenone, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxy-4′-chloro benzophenone, 2,2-dihydroxy-4-methoxybenzophenone, 2,2-dihydroxy-4,4′-dimethoxybenzophenone, 2,4-diphenyl-6-(2-hydroxy-4-methoxyphenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-ethoxyphenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-propoxyphenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-butoxyphenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-hexyloxy phenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-octyloxy phenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-dodecyloxy phenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-benzyloxyphenyl)-1,3,5-triazine, 2,4-diphenyl-6-(2-hydroxy-4-(2-butoxyethoxy) phenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-methoxypheny)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-ethoxyphenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-propoxyphenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-butoxyphenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-hexyloxy phenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-octyloxy phenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-dodecyloxy phenyl)-1,3,5-triazine, 2-(4,6-diphenyl-1,3,5-triazine-2-yl)-5-(hexyl) oxy-phenol, 2,4-di-p-toluyl-6-(2-hydroxy-4-benzyloxyphenyl)-1,3,5-triazine, 2,4-di-p-toluyl-6-(2-hydroxy-4-(2-hexyloxy ethoxy) phenyl)-1,3,5-triazine, t-buthylphenyl salicylate, octylphenylsalicylate, or a combination comprising one or more of the foregoing.

10. The process of claim 1 , wherein the release agent comprises a polyhydric alcohol, a C 10-30 saturated fatty acid, a partial ester, a full ester, or a combination comprising one or more of the foregoing.

11. The process of claim 1 , wherein the flame retardant comprises a flame retardant of the formula (200)

wherein each R L independently is an alkyl group, a cycloalkyl group, or an aryl group; R M is an alkyl group or a cycloalkyl group; iv is an integer; and each vi independently is 0 or 1.

12. The process of claim 1 , further comprising
extruding polycarbonate pellets from the extruder;
coating the polycarbonate pellets with a PTFE coating layer, wherein the coating layer has a coating thickness of 0.5 to 15 micrometers to form coated polycarbonate pellets; and
melt mixing or extruding the coated polycarbonate pellets.

13. The process of claim 1 , wherein the pressure is greater than or equal to 3 bars.

14. The process of claim 1 , wherein the colorant is present in an amount of 0.00001 to 0.0002 parts by weight based on the total weight of the polymerized polycarbonate.

15. The process of claim 1 , wherein the melt polymerizing comprises forming a catalyst mixture in a mixing unit by adding a dihydroxy compound to the mixing unit, adding a carbonate compound to the mixing unit, reducing a water and an alkyl alcohol level to a reduced level of less than or equal to 450 ppm based on the total weight of the carbonate compound and/or less than or equal to 400 ppm based on the total weight of the dihydroxy compound; and adding a quaternary compound.

16. The process of claim 1 , wherein the catalyst composition comprises tetraphenyl phosphonium phenoxide.

17. The process of claim 1 , wherein the liquid carrier comprises a low boiling point solvent and a high boiling point solvent; wherein the low boiling point solvent has a low boiling point that is lower than a boiling point of the quencher and the high boiling point solvent has a high boiling point that is greater than a boiling point of the quencher.

Assignees

• Sabic Global Technologies Bv

Inventors

• Fernandez Ignacio Vic

Classifications

• C08L27/12

  containing fluorine atoms · CPC title

• C08K5/00

  Use of organic ingredients · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08G64/40 Primary

  Post-polymerisation treatment · CPC title