Method for purifying contaminated polyethylene

Patent metadata

Field	Value
Publication number	US-9803035-B2
Application number	US-201615190248-A
Country	US
Kind code	B2
Filing date	Jun 23, 2016
Priority date	Jun 30, 2015
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A method for purifying reclaimed polyethylene, such as polyethylene reclaimed from post-consumer use or post-industrial use, is disclosed. The method involves obtaining the reclaimed polyethylene and contacting it at an elevated temperature and pressure with a fluid solvent to produce an extracted reclaimed polyethylene. The extracted reclaimed polyethylene is dissolved in a solvent at an elevated temperature and pressure to produce a polyethylene solution, which is purified at an elevated temperature and pressure by contacting the polyethylene solution with solid media to produce a purer polyethylene solution. A purer polyethylene is then separated from the purer polyethylene solution.

First claim

What is claimed is:

1. A method for purifying reclaimed polyethylene comprising:
a. obtaining the reclaimed polyethylene wherein said reclaimed polyethylene is selected from the group consisting of post-consumer use polymers, post-industrial use polymers, and combinations thereof;
b. contacting the reclaimed polyethylene at a temperature from about 80° C. to about 220° C. and at a pressure from about 150 psig (1.03 MPa) to about 15,000 psig (103.42 MPa) with a first fluid solvent having a standard boiling point less than about 70° C., to produce an extracted reclaimed polyethylene;
c. dissolving the extracted reclaimed polyethylene in a solvent selected from the group consisting of the first fluid solvent, a second fluid solvent, and mixtures thereof, at a temperature from about 90° C. to about 220° C. and a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) to produce a polyethylene solution;
d. purifying said polyethylene solution at a temperature from about 90° C. to about 220° C. and at a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) by contacting said polyethylene solution with solid media to produce a purer polyethylene solution; and
e. separating a purer polyethylene from said purer polyethylene solution;

wherein said second fluid solvent has the same chemical composition as or a different chemical composition than the first fluid solvent.

2. The method of claim 1 , wherein the purer polyethylene is separated from said purer polyethylene solution at a temperature from about 0° C. to about 220° C. and a pressure from about 0 psig (0 MPa) to 2,000 psig (13.79 MPa).

3. The method of claim 1 , wherein the reclaimed polyethylene is post-consumer recycle derived polyethylene.

4. The method of claim 1 , wherein said polyethylene is a polyethylene homopolymer or a primarily polyethylene copolymer.

5. The method of claim 1 , wherein said fluid solvent has a standard boiling point less than about 0° C. and greater than about −45° C. and a standard enthalpy change of vaporization of less than about +25 kJ/mol.

6. The method of claim 1 , wherein said fluid solvent is selected from the group consisting of olefinic hydrocarbons, aliphatic hydrocarbons, and mixtures thereof.

7. The method of claim 6 , wherein said aliphatic hydrocarbon is selected from the group consisting of C 1 -C 6 aliphatic hydrocarbons and mixtures thereof.

8. The method of claim 6 , wherein said aliphatic hydrocarbons and mixtures thereof is comprised of primarily C 4 aliphatic hydrocarbons.

9. The method of claim 6 , wherein said fluid solvent consists essentially of C 4 liquefied petroleum gas.

10. The method of claim 8 , wherein said fluid solvent is n-butane, butane isomers, or mixtures thereof.

11. The method of claim 1 , wherein said temperature in steps b, c, and d is from about 110° C. to about 170° C.

12. The method of claim 1 , wherein said pressure in step b is from about 1,100 psig (7.58 MPa) to about 5,500 psig (37.92 MPa).

13. The method of claim 1 , wherein said pressure in step b is from about 150 psig (1.03 MPa) to about 1,100 psig (7.58 MPa).

14. The method of claim 1 , wherein said pressure in step c is from about 4,500 psig (31.03 MPa) to about 20,000 psig (137.90 MPa).

15. The method of claim 1 , wherein said pressure in step c is from about 5,500 psig (37.92 MPa) to about 20,000 psig (137.90 MPa).

16. The method of claim 1 , wherein said solid media is selected from the group consisting of inorganic substances, carbon-based substances, and mixtures thereof.

17. The method of claim 16 , wherein said inorganic substances are selected from the group consisting of oxides of silicon, oxides of aluminum, oxides of iron, aluminum silicates, amorphous volcanic glasses, and mixtures thereof.

18. The method of claim 16 , wherein said inorganic substances are selected from the group consisting of silica gel, diatomite, sand, quartz, alumina, perlite, fuller's earth, bentonite, and mixtures thereof.

19. The method of claim 18 , wherein said inorganic substance is reclaimed glass.

20. The method of claim 16 , wherein said carbon-based substances are selected from the group consisting of anthracite coal, carbon black, coke, activated carbon, cellulose, and mixtures thereof.

21. The method of claim 1 , wherein said contacting of the polyethylene solution with said solid media is performed in a packed bed of said solid media.

22. The method of claim 21 , where said packed bed is greater than 20 cm in length.

Assignees

• Procter & Gamble

Inventors

• Layman John Moncrief
• Gunnerson Maggie
• Schonemann Hans
• Williams Kara

Classifications

• C08J2323/06

  Polyethene · CPC title

• C08F6/00 Primary

  Post-polymerisation treatments (C08F8/00 takes precedence; of conjugated diene rubbers C08C) · CPC title

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title

• C08J11/08 Primary

  using selective solvents for polymer components · CPC title

• C08J2323/12

  Polypropene · CPC title