Methanation catalyst

Patent metadata

Field	Value
Publication number	US-9802872-B2
Application number	US-201414779941-A
Country	US
Kind code	B2
Filing date	Mar 28, 2014
Priority date	Mar 28, 2013
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

The invention relates to use of a catalyst comprising particles of nickel dispersed in a porous silica matrix for catalyzing a methanation reaction. There is also described a method for methanation of a feedstock at least comprising gases carbon monoxide and hydrogen, said method comprising contacting the feedstock with the catalyst.

First claim

The invention claimed is:

1. A method for methanation of a feedstock comprising carbon monoxide and hydrogen, said method comprising contacting the feedstock with a catalyst comprising particles of nickel dispersed in a porous silica matrix, said catalyst comprising about 20 wt % to about 63 wt % metallic nickel, and said catalyst having pores which extend continuously from an outside surface of the silica matrix to an outside surface of the nickel, wherein the active nickel surface area in said catalyst is about 50 m 2 /g to 160 m 2 /g Ni.

2. The method of claim 1 wherein the feedstock additionally comprises carbon dioxide gas.

3. The method of claim 1 wherein the feedstock additionally comprises steam.

4. The method of claim 1 wherein the feedstock comprises coal gasification effluent and/or biomass gasification effluent.

5. The method of claim 1 wherein the feedstock additionally comprises a sulfur-containing gas.

6. The method of claim 5 wherein the sulfur-containing gas comprises any one or more of hydrogen sulfide, carbonyl sulfide, sulfur dioxide or an organic thiol.

7. The method of claim 1 wherein the molar ratio of hydrogen to carbon monoxide in the feedstock is between 4:1 and about 1:1.

8. The method of claim 1 wherein the pressure of the feedstock during said contacting is between about 0.5 and about 40 bar.

9. The method of claim 1 wherein said contacting is conducted at a temperature of at least about 250° C.

10. The method of claim 1 wherein the catalyst is effective without regeneration after use in said method for at least 2000 minutes using a feedstock having at least 20 ppm of a sulfur containing gas.

11. The method of claim 1 wherein the porous silica matrix of the catalyst has pores of about 1 nm to 100 nm in diameter.

12. The method of claim 1 wherein the particles of nickel have a mean particle diameter of about 2 nm to 10 nm.

13. The method of claim 1 wherein said catalyst has a BET surface area of at least about 200 m 2 /g.

14. A method for reducing the carbon monoxide content of a gas mixture comprising carbon monoxide and hydrogen, said method comprising exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix, said catalyst comprising about 20 wt % to about 63 wt % metallic nickel, and said catalyst having pores which extend continuously from an outside surface of the silica matrix to an outside surface of the nickel, wherein the active nickel surface area in said catalyst is about 50 m 2 /g to 160 m 2 /g Ni.

15. The method of claim 14 wherein the gas mixture comprises a sulfur containing gas.

16. A method for reducing the carbon monoxide content of a gas, said method comprising adding hydrogen to said gas to form a gas mixture and exposing the gas mixture to a catalyst comprising particles of nickel dispersed in a porous silica matrix, said catalyst comprising about 20 wt % to about 63 wt % metallic nickel, and said catalyst having pores which extend continuously from an outside surface of the silica matrix to an outside surface of the nickel, wherein the active nickel surface area in said catalyst is about 50 m 2 /g to 160 m 2 /g Ni.

17. The method of claim 16 wherein the gas comprises a sulfur containing gas.

Assignees

• Agency Science Tech & Res
• Ihi Corp

Inventors

• Chen Luwei
• Tian Zhi Qun
• Borgna Armando
• Kamata Hiroyuki
• Izumi Yoshinori

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title