Treating and recylcing oilfield waste water

Patent metadata

Field	Value
Publication number	US-9802846-B2
Application number	US-201313923509-A
Country	US
Kind code	B2
Filing date	Jun 21, 2013
Priority date	Jun 21, 2013
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A process for treating oilfield waste water includes combining oilfield waste water and a biocide comprising hydrogen peroxide, the biocide being present in an amount effective to decrease a number density of bacteria in the oilfield waste water. The treated water can be reused in a subterranean environment.

First claim

What is claimed is:

1. A process for treating oilfield waste water, the process comprising:
combining oilfield waste water comprising hydrogen sulfide and iron-oxidizing bacteria and a biocide consisting of hydrogen peroxide to form treated water, the biocide being present in an amount effective to decrease a number density of bacteria in the oilfield waste water; and
reusing the treated water by disposing the treated water in a subterranean environment,
wherein the process further comprises oxidizing an organic material, an inorganic material, or a combination comprising at least one of the foregoing materials with an oxidizer which is a nitrate, a nitrite, a dichromate, or a nitrogen-chloro oxidizer, or a combination comprising at least one of the foregoing, prior to combining the biocide and the oilfield waste water;
determining an oxidation reduction potential (ORP) of the oilfield waste water; and
adjusting the amount of the biocide present in the oilfield waste water such that the ORP of the oilfield waste water is greater than or equal to 100 mV, referenced to a Ag/AgCl reference electrode.

2. The process of claim 1 , wherein the oxidizer is added to the oilfield waste water in an amount such that an oxidation reduction potential (ORP) of the oilfield waste water is greater than or equal to 100 mV, referenced to an Ag/AgCl reference electrode.

3. The process of claim 1 , further comprising determining the number density of the bacteria present in the oilfield waste water.

4. The process of claim 3 , wherein, after combining the oilfield waste water and the biocide, the number density of the bacteria present in the oilfield waste water decreases by an amount greater than or equal to 90%, based on the number of bacteria per milliliter of the oilfield waste water.

5. The process of claim 3 , wherein determining the number density of the bacteria comprises quantifying an amount of bacterial ATP in a sample of the oilfield waste water.

6. The process of claim 1 , wherein the oilfield waste water comprises produced water, flowback water, pit water, or a combination comprising at least one of the foregoing.

7. The process of claim 1 , wherein combining the biocide and the oilfield waste water occurs aboveground.

8. The method of claim 1 , wherein the oilfield waste water is not treated with biocides or oxidants other than hydrogen peroxide.

9. The method of claim 1 , further comprising heating the oilfield waste water.

10. A process for treating oilfield waste water, the process comprising:
measuring an oxidation reduction potential (ORP) of oilfield waste water, the oilfield waste water comprising hydrogen sulfide and iron-oxidizing bacteria;
combining the oilfield waste water and an oxidizer in an amount to adjust the ORP of the oilfield waste water to be greater than or equal to a first ORP value of 100 mV referenced to an Ag/AgCl reference electrode, the oxidizer comprising halogen oxidizer, nitrate, nitrite, dichromate, nitrogen-chloro oxidizer, or a combination comprising at least one of the foregoing; and
adding a biocide comprising hydrogen peroxide to the oilfield waste water having an ORP of greater than or equal to 100 mV to adjust the ORP of the oilfield waste water to be greater than or equal to a second ORP value of 600 mV, referenced to an Ag/AgCl reference electrode, to treat the oilfield waste water, the second ORP value being greater than the first ORP value.

11. The process of claim 10 , further comprising determining a number density of bacteria in the oilfield waste water.

12. The method of claim 10 , wherein the biocide consists of hydrogen peroxide.

13. The method of claim 10 , further comprising
introducing an additive to the treated water; and
disposing the treated water in a subterranean environment,
wherein the additive comprises a coagulant, a flocculant, or a combination thereof;
the coagulant comprises sodium chloride, aluminum sulfate, polyaluminum chloride, ferric sulfate, ferric chloride, aluminum chloride, sodium aluminate, polyethyleneimine, dimethylamine-epichlorohydrin copolymer, dicyandiamide-formaldehyde condensation product, cation-modified starch, tannin, a melamine formaldehyde, a resin amine, or a combination comprising at least one of the foregoing; and
the flocculant comprises copolymer of acrylamide and acrylic acid, a copolymer of acrylamide and dimethylaminoethyl acrylate, N,N-dimethylaminoethyl acrylate methyl chloride quaternary, cationic polyacrylamide, acrylic acid, acrylamide meth acrylic acid, polyethylene imine or polyamine, a dicyandiamide condensation polymer, a polymer of water soluble ethylenically unsaturated monomer or monomer blend, or a combination comprising at least one of the foregoing.

14. A process for recycling oilfield waste water, the process comprising:
combining oilfield waste water and a biocide consisting of hydrogen peroxide, the oilfield waste water comprising hydrogen sulfide and iron-oxidizing bacteria;
decreasing a number density of bacteria in the oilfield waste water to form treated water;
introducing an additive to the treated water; and
disposing the treated water in a subterranean environment,
wherein the additive comprises a coagulant, a flocculant, or a combination thereof;
the coagulant comprises sodium chloride, aluminum sulfate, polyaluminum chloride, ferric sulfate, ferric chloride, aluminum chloride, sodium aluminate, polyethyleneimine, dimethylamine-epichlorohydrin copolymer, dicyandiamide-formaldehyde condensation product, cation-modified starch, tannin, a melamine formaldehyde, a resin amine, or a combination comprising at least one of the foregoing; and
the flocculant comprises copolymer of acrylamide and acrylic acid, a copolymer of acrylamide and dimethylaminoethyl acrylate, N,N-dimethylaminoethyl acrylate methyl chloride quaternary, cationic polyacrylamide, acrylic acid, acrylamide meth acrylic acid, polyethylene imine or polyamine, a dicyandiamide condensation polymer, a polymer of water soluble ethylenically unsaturated monomer or monomer blend, or a combination comprising at least one of the foregoing, and
the process further comprising oxidizing an organic material, an inorganic material, or a combination comprising at least one of the foregoing materials with an oxidizer which is a nitrate, a nitrite, a dichromate, or a nitrogen-chloro oxidizer, or a combination comprising at least one of the foregoing, prior to combining the biocide and the oilfield waste water.

15. The process of claim 14 , further comprising contacting the oilfield waste water with an oxidizer prior to combining the oilfield waste water and the biocide.

16. The process of claim 14 , further comprising pressurizing the treated water to fracture the subterranean environment.

17. The method of claim 14 , wherein the recycled water is a hydraulic fracturing fluid comprising slickwater or a crosslink fluid; an enhanced oil recovery fluid; a completion fluid; a drilling fluid; or a combination comprising at least one of the foregoing.

Assignees

• Seth Kushal
• Lascano Jenifer C
• Hines Larry G
• Baker Hughes A Ge Co Llc

Inventors

• Seth Kushal
• Lascano Jenifer C
• Hines Larry G

Classifications

• C02F1/50

  by addition or application of a germicide or by oligodynamic treatment {(C02F1/4606, C02F1/467, C02F1/76 take precedence)} · CPC title

• C02F1/76 Primary

  with halogens or compounds of halogens {(C02F1/4674 takes precedence)} · CPC title

• C02F1/72

  by oxidation {(C02F1/4672 takes precedence)} · CPC title

• C02F9/00

  Multistage treatment of water, waste water or sewage · CPC title

• C02F2209/04

  Oxidation reduction potential [ORP] · CPC title